偶氮分子掺杂对蓝相液晶选择性反射波长的影响

周路; 张丹; 郑致刚; 沈冬; 包锡峰

doi:10.3788/YJYXS20132801.0007

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偶氮分子掺杂对蓝相液晶选择性反射波长的影响

材料物理和化学 | 更新时间：2020-08-12

- 偶氮分子掺杂对蓝相液晶选择性反射波长的影响
- Influence of Selective Reflection Wavelength in Liquid Crystal Blue Phase Doped with Azo Materials
- 液晶与显示 2013年28卷第1期页码：7-14
- 作者机构：
  
  1. 华东理工大学理学院化学物理研究室上海,200237
  2. 江苏北方湖光光电有限公司工艺中心,江苏无锡,214035
- 作者简介：
- 基金信息：
  
  国家自然科学基金(No. 61108065)();上海市晨光计划(No. 12CG33)();教育基本科研业务专项(No. WM1014015)();龙腾光电有限公司新
- DOI：10.3788/YJYXS20132801.0007
  中图分类号： O753+.2
- 收稿日期：2012-11-20，
  
  修回日期：2012-12-11，
  
  纸质出版日期：2013-02-15
- 稿件说明：
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周路, 张丹, 郑致刚, 沈冬, 包锡峰. 偶氮分子掺杂对蓝相液晶选择性反射波长的影响[J]. 液晶与显示, 2013,(1): 7-14

ZHOU Lu, ZHANG Dan, ZHENG Zhi-gang, SHEN Dong, BAO Xi-feng. Influence of Selective Reflection Wavelength in Liquid Crystal Blue Phase Doped with Azo Materials[J]. , 2013,(1): 7-14
周路, 张丹, 郑致刚, 沈冬, 包锡峰. 偶氮分子掺杂对蓝相液晶选择性反射波长的影响[J]. 液晶与显示, 2013,(1): 7-14 DOI： 10.3788/YJYXS20132801.0007.

ZHOU Lu, ZHANG Dan, ZHENG Zhi-gang, SHEN Dong, BAO Xi-feng. Influence of Selective Reflection Wavelength in Liquid Crystal Blue Phase Doped with Azo Materials[J]. , 2013,(1): 7-14 DOI： 10.3788/YJYXS20132801.0007.

摘要

偶氮基团(—N=N—)在适当波长光的照射下

会发生可逆的顺反异构反应

这一反应中偶氮分子构型上的变化会影响到蓝相液晶中脆弱的晶格结构

并造成晶格参数的变化

进而影响到选择性反射波长的变化

甚至有时会造成蓝相相态的消失。文章合成并将几种偶氮化合物掺入手性向列相液晶中

再变温至BPI

对比了这几种偶氮化合物对蓝相液晶选择性反射波长的影响

从而得出更有实际使用价值的偶氮分子

在此基础上还从分子结构角度分析了产生差异的原因

为进一步的改进工作提供了方向。

Abstract

The azo (—N=N—) group can have reversible trans-cis isomerization reaction under the appropriate wavelength light irradiation. The change of the azo molecular configuration affects fragile lattice structure of the blue phase liquid crystal and leads to the change of the lattice parameters

thus the selective reflection wavelength is also changed. Sometimes the change of azo molecular configuration can make the blue phase disappeared. In this paper several azo compounds were synthesized and doped in chiral nematic phase liquid crystal

then the temperature was changed to get blue phase I. The influence of selective reflection wavelength was studied and the azo compounds suitable for application were found. The reason of the difference was also discussed and the suggestion for further improvement was given.

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references

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