High sensitivity organic transistor nitrogen dioxide sensor based on three component conjugated polymer

Guan-long WANG; Xiao-hong WANG; Long-zhen QIU

doi:10.37188/CJLCD.2022-0101

您当前的位置：

首页 >

文章列表页 >

High sensitivity organic transistor nitrogen dioxide sensor based on three component conjugated polymer

Device Physics and Device Preparation | 更新时间：2022-07-25

- High sensitivity organic transistor nitrogen dioxide sensor based on three component conjugated polymer
- Chinese Journal of Liquid Crystals and Displays Vol. 37, Issue 7, Pages: 797-805(2022)
- 作者机构：
  
  合肥工业大学光电技术研究院特种显示技术国家工程实验室，测量理论与精密仪器安徽省重点实验室，安徽合肥 230009
- 作者简介：
- 基金信息：
  
  Fundamental Research Funds for the Central Universities of China(PA2021GDSK0098)
- DOI：10.37188/CJLCD.2022-0101
  CLC： TN321⁺.5
- Received：30 March 2022，
  
  Revised：21 April 2022，
  
  Published：05 July 2022
- 稿件说明：
移动端阅览
Guan-long WANG, Xiao-hong WANG, Long-zhen QIU. High sensitivity organic transistor nitrogen dioxide sensor based on three component conjugated polymer[J]. Chinese journal of liquid crystals and displays, 2022, 37(7): 797-805.
DOI：

Guan-long WANG, Xiao-hong WANG, Long-zhen QIU. High sensitivity organic transistor nitrogen dioxide sensor based on three component conjugated polymer[J]. Chinese journal of liquid crystals and displays, 2022, 37(7): 797-805. DOI： 10.37188/CJLCD.2022-0101.

摘要

研究了基于联噻吩-氮杂异靛蓝-双（2-氧代二氢-7-氮杂吲哚-3-亚基）苯并二呋喃二酮的三组分给体-受体共轭聚合物（BTNIDNBIBDF-50）薄膜对二氧化氮气体传感特性。通过控制半导体浓度调控半导体薄膜表面形貌，研究其对二氧化氮气体灵敏度的影响。聚合物半导体BTNIDNBIBDF-50的浓度为2 mg/mL时对NO

气体表现出最优的传感性能，对体积分数为10×10

-6

气体的灵敏度为121.44%。实验结果表明：三组分共轭聚合物BTNIDNBIBDF-50呈现双极型半导体特性，降低聚合物半导体浓度会使薄膜表面出现明显的孔洞结构，提高传感器对NO

气体的灵敏度。但过多的孔洞又会使气体解吸附速率的变化大于吸附速率变化，导致传感器灵敏度降低。

Abstract

A three-component donor-acceptor conjugated polymer （BTNIDNBIBDF-50） film based on dithiophene-aza-isoindigo-bis（2-oxodihydro-7-azaindol-3-ylidene）benzodifurandione was investigated for the sensing characteristics of nitrogen dioxide gas. The effect of semiconductor concentration on the sensitivity of nitrogen dioxide was studied by controlling the morphology of semiconductor film. The polymer semiconductor BTNIDNBIBDF-50 showed the best sensing performance for NO

gas at a concentration of 2 mg/mL， and the sensitivity for NO

gas at 10×10

-6

（volum fraction） was 121.44%. The experimental results show that bipolar semiconductor polymer BTNIDNBIBDF-50 shows ambipolar charge transport characteristics. Reducing the concentration of the polymer semiconductor will lead to obvious holes on the surface of the film and improve the sensitivity of the sensor to NO

gas. However， the excessive porosity can cause the change in gas desorption rate to be greater than the change in adsorption rate， leading to the decrease of sensor sensitivity.

关键词

Keywords

references

ZHENG C Z ， XIANG L Y ， JIN W L ， et al . A flexible self‐powered sensing element with integrated organic thermoelectric generator ［J］. Advanced Materials Technologies ， 2019 ， 4 （ 8 ）： 1900247 . doi: 10.1002/admt.201900247 http://dx.doi.org/10.1002/admt.201900247

ZHUANG X M ， ZHANG D Y ， WANG X L ， et al . Biocompatible and degradable gelatin dielectric based low-operating voltage organic transistors for ultra-high sensitivity NH 3 detection ［J］. Applied Physics Letters ， 2018 ， 113 （ 26 ）： 263301 . doi: 10.1063/1.5054026 http://dx.doi.org/10.1063/1.5054026

ZHANG C C ， CHEN P L ， HU W P . Organic field-effect transistor-based gas sensors ［J］. Chemical Society Reviews ， 2015 ， 44 （ 8 ）： 2087 - 2107 . doi: 10.1039/c4cs00326h http://dx.doi.org/10.1039/c4cs00326h

WU M G ， HOU S H ， YU X G ， et al . Recent progress in chemical gas sensors based on organic thin film transistors ［J］. Journal of Materials Chemistry C ， 2020 ， 8 （ 39 ）： 13482 - 13500 . doi: 10.1039/d0tc03132a http://dx.doi.org/10.1039/d0tc03132a

FAN H D ， HAN S J ， SONG Z H ， et al . Organic field-effect transistor gas sensor based on GO/PMMA hybrid dielectric for the enhancement of sensitivity and selectivity to ammonia ［J］. Organic Electronics ， 2019 ， 67 ： 247 - 252 . doi: 10.1016/j.orgel.2019.01.038 http://dx.doi.org/10.1016/j.orgel.2019.01.038

JEONG S H ， LEE J Y ， LIM B ， et al . Diketopyrrolopyrrole-based conjugated polymer for printed organic field-effect transistors and gas sensors ［J］. Dyes and Pigments ， 2017 ， 140 ： 244 - 249 . doi: 10.1016/j.dyepig.2017.01.054 http://dx.doi.org/10.1016/j.dyepig.2017.01.054

XIE Q ， WANG L ， ZHU Y Y ， et al . Highly sensitive NO 2 sensors based on organic field effect transistors with Al 2 O 3 /PMMA bilayer dielectrics by sol-spin coating ［J］. Organic Electronics ， 2019 ， 74 ： 69 - 76 . doi: 10.1016/j.orgel.2019.06.054 http://dx.doi.org/10.1016/j.orgel.2019.06.054

SONG R X ， ZHOU X ， WANG Z ， et al . High selective gas sensors based on surface modified polymer transistor ［J］. Organic Electronics ， 2021 ， 91 ： 106083 . doi: 10.1016/j.orgel.2021.106083 http://dx.doi.org/10.1016/j.orgel.2021.106083

TRUL A A ， SIZOV A S ， CHEKUSOVA V P ， et al . Organosilicon dimer of BTBT as a perspective semiconductor material for toxic gas detection with monolayer organic field-effect transistors ［J］. Journal of Materials Chemistry C ， 2018 ， 6 （ 36 ）： 9649 - 9659 . doi: 10.1039/c8tc02447b http://dx.doi.org/10.1039/c8tc02447b

YANG Z C ， HAN S J ， LIU Y F ， et al . Investigation of the atmosphere influence on device characteristics and NO 2 sensing performance of organic field-effect transistors consisting of polymer bulk heterojunction ［J］. Organic Electronics ， 2018 ， 62 ： 114 - 120 . doi: 10.1016/j.orgel.2018.07.023 http://dx.doi.org/10.1016/j.orgel.2018.07.023

LU J J ， LIU D P ， ZHOU J C ， et al . Porous organic field-effect transistors for enhanced chemical sensing performances ［J］. Advanced Functional Materials ， 2017 ， 27 （ 20 ）： 1700018 . doi: 10.1002/adfm.201700018 http://dx.doi.org/10.1002/adfm.201700018

ZHOU X ， WANG Z ， SONG R X ， et al . High performance gas sensors with dual response based on organic ambipolar transistors ［J］. Journal of Materials Chemistry C ， 2021 ， 9 （ 5 ）： 1584 - 1592 . doi: 10.1039/d0tc04843g http://dx.doi.org/10.1039/d0tc04843g

DU Y C ， YAO H B ， GALUSKA L ， et al . Side-chain engineering to optimize the charge transport properties of isoindigo-based random terpolymers for high-performance organic field-effect transistors ［J］. Macromolecules ， 2019 ， 52 （ 12 ）： 4765 - 4775 . doi: 10.1021/acs.macromol.9b00474 http://dx.doi.org/10.1021/acs.macromol.9b00474

KIM K H ， PARK S ， YU H ， et al . Determining optimal crystallinity of diketopyrrolopyrrole-based terpolymers for highly efficient polymer solar cells and transistors ［J］. Chemistry of Materials ， 2014 ， 26 （ 24 ）： 6963 - 6970 . doi: 10.1021/cm502991d http://dx.doi.org/10.1021/cm502991d

KHIM D ， CHEON Y R ， XU Y ， et al . Facile route to control the ambipolar transport in semiconducting polymers ［J］. Chemistry of Materials ， 2016 ， 28 （ 7 ）： 2287 - 2294 . doi: 10.1021/acs.chemmater.6b00298 http://dx.doi.org/10.1021/acs.chemmater.6b00298

NAIR V S ， SUN J B ， QI P L ， et al . Conjugated random donor-acceptor copolymers of ［1］benzothieno［3， 2- b ］benzothiophene and diketopyrrolopyrrole units for high performance polymeric semiconductor applications ［J］. Macromolecules ， 2016 ， 49 （ 17 ）： 6334 - 6342 . doi: 10.1021/acs.macromol.6b00954 http://dx.doi.org/10.1021/acs.macromol.6b00954

JUNG J W ， LIU F ， RUSSELL T P ， et al . Semi-crystalline random conjugated copolymers with panchromatic absorption for highly efficient polymer solar cells ［J］. Energy & Environmental Science ， 2013 ， 6 （ 11 ）： 3301 - 3307 . doi: 10.1039/c3ee40689j http://dx.doi.org/10.1039/c3ee40689j

杜玉昌 . 三组分给受体共轭聚合物结构与性能关系研究［D］. 合肥：合肥工业大学， 2019 .

DU Y C . Study on the structure-property relationship of donor-acceptor terpolymers ［D］. Hefei ： Hefei University of Technology ， 2019 . （in Chinese）

KIM Y ， LEE S ， SONG J G ， et al . 2D transition metal dichalcogenide heterostructures for p‐ and n‐type photovoltaic self‐powered gas sensor ［J］. Advanced Functional Materials ， 2020 ， 30 （ 43 ）： 2003360 . doi: 10.1002/adfm.202003360 http://dx.doi.org/10.1002/adfm.202003360

MENG Q ， ZHANG F J ， ZANG Y P ， et al . Solution-sheared ultrathin films for highly-sensitive ammonia detection using organic thin-film transistors ［J］. Journal of Materials Chemistry C ， 2014 ， 2 （ 7 ）： 1264 - 1269 . doi: 10.1039/c3tc31762e http://dx.doi.org/10.1039/c3tc31762e

LV A F ， WANG M ， WANG Y D ， et al . Investigation into the sensing process of high-performance H 2 S sensors based on polymer transistors ［J］. Chemistry ， 2016 ， 22 （ 11 ）： 3654 - 3659 . doi: 10.1002/chem.201504196 http://dx.doi.org/10.1002/chem.201504196

Views

304

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Transparent organic memory based on quantum dots floating gate

Impact of plasma treatment of dielectric layer on synaptic performance of organic thin film transistors

Parameters extraction method for organic thin film transistor model

Research of copper phthalocyanine thin film transistor by heterogeneous induced growth

Related Author

QIU Long-zhen

WANG Xiao-hong

WANG Guan-long

ZHANG Guo-cheng

LI Bo-wen

XING Jun-jie

MA Chao

QIN Shi-xian

Related Institution

National Engineering Lab of Special Display Technology， Anhui Province Key Laboratory of Measuring Theory and Precision Instrument， Academy of Opto-Electronic Technology， Hefei University of Technology

Research Center for Microelectronics Technology， Fujian University of Technology

Research Center for Microelectronics Technology, Fujian University of Technology

Institute of Optoelectronic Display, National & Local United Engineering Lab of Flat Panel Display Technology, Fuzhou University

Institute of Optoelectronics Technology, Beijing Jiaotong University

AI问答

Address：No.3888 Dong Nanhu Road, Changchun, Jilin, China 130033 Postal code：130033
Tel：0431-86176059 Email：yjxs@ciomp.ac.cn
Technical support is provided by Beijing Founder electronics co., LTD 吉ICP备11002662号-17 京公网安备11010802024621
It is recommended to read the content of this site in Chrome&IE9+. Please switch to extreme mode in browser 360.
Cookies We use cookies to help provide and enhance our service and tailor content. By continuing, you agree to the use of cookies.

⁰