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氢键组装的超分子液晶的研究进展
Progress in intermolecular hydrogen bond-assembled supramolecular liquid crystals
- 液晶与显示 2019年34卷第11期 页码：1037-1054
- 作者机构：
1.桂林理工大学 化学与生物工程学院, 广西 桂林 541004
2.北部湾大学 石油与化工学院, 广西 钦州 535011
- 作者简介：
[ "孔翔飞(1975-), 男, 河南南阳人, 副教授, 硕士生导师, 2011年于北京交通大学获得博士学位, 主要从事液晶材料的合成和应用, 特别是在苯并菲类盘状液晶的合成及应用在有机发光和光伏领域, 积累了丰富的经验; 还从事具有美容等效果的先导化合物的合成与应用研究。E-mail:xiangfei.kong@glut.edu.cn" ]
[ "王桂霞(1976-), 女, 河北沧洲人, 副教授, 硕士生导师, 2010年于中国科学院理化技术研究所获得博士学位, 主要从事有机功能材料和水溶性高分子材料的合成和应用方面的研究。E-mail:2010033@glut.edu.cn" ]
[ "梁金禄(1978-), 男, 广西桂平人, 高级工程师, 硕士生导师, 2011于中国民航大学获得硕士学位, 主要从事石油与天然气工程、油气储运工程、油气管道及化工管道安全方面的研究。E-mail:ljinlu@163.com" ]
- 基金信息：国家自然科学基金项目(11364013);广西基金面上项目(2018JJA110038);桂林理工大学博士启动基金项目;Supported by National Natural Science Foundation of China(11364013);Guangxi Fund Project(2018JJA110038);Guilin University of Technology Doctor Startup Fund Project
DOI：10.3788/YJYXS20193411.1037
中图分类号： O62收稿日期：2019-05-14，
录用日期：2019-9-3，
纸质出版日期：2019-11-05
- 稿件说明：
移动端阅览
孔翔飞, 李俊, 俞建文, 等. 氢键组装的超分子液晶的研究进展[J]. 液晶与显示, 2019,34(11):1037-1054.
Xiang-fei KONG, Jun LI, Jian-wen YU, et al. Progress in intermolecular hydrogen bond-assembled supramolecular liquid crystals[J]. Chinese journal of liquid crystals and displays, 2019, 34(11): 1037-1054.
孔翔飞, 李俊, 俞建文, 等. 氢键组装的超分子液晶的研究进展[J]. 液晶与显示, 2019,34(11):1037-1054. DOI： 10.3788/YJYXS20193411.1037.
Xiang-fei KONG, Jun LI, Jian-wen YU, et al. Progress in intermolecular hydrogen bond-assembled supramolecular liquid crystals[J]. Chinese journal of liquid crystals and displays, 2019, 34(11): 1037-1054. DOI： 10.3788/YJYXS20193411.1037.
摘要
介绍了近十几年来典型的氢键组装的超分子液晶材料的组装方法和分子结构，对比其光电性能和自组装特点，并对其在光电器件方面的应用进行展望。这类材料依据氢键组装的方式和分子结构主要分为两大类：结构封闭型和结构开放型。与后者相比，前者具有易于结构修饰和易于精确调控性能的特点。但两者内部的分子结构变化时，组装的超分子液晶材料的性能均受到显著影响。分子间氢键作用组装的超分子液晶材料具有高度有序性和可精确调控性，因此作为新型材料在有机光电器件和纳米器件等领域具有广阔的应用前景。
Abstract
In this paper
the typical hydrogen bond-assembled supramolecular liquid crystal materials are summarized over the past decade. Their preparation methods and molecular structures are presented
and their photoelectric properties and self-assembly characteristics are compared
as well as their applications in optoelectronic devices are prospected. According to the kinds of hydrogen bonds and the molecular structures
these materials are mainly divided into two categories:closed-type and open-type structures. Compared with the latter
the former has the characteristics of easy structural modification and precise structure control. However
the properties of all these assembled supramolecular liquid crystal materials are significantly affected by the changes of their internal molecular structure. These materials assembled by intermolecular hydrogen bonding are highly ordered and their molecular structures are precisely controllable. As a novel material
it has broad application prospects in the field of organic photoelectronic devices and nanodevices.
关键词
Keywords
references
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