主、侧链修饰对异靛蓝基共轭聚合物结构及电学性能的影响

田丰收; 邱龙臻; 陈俊辉; 张国兵

doi:10.3788/YJYXS20193407.0627

您当前的位置：

首页 >

文章列表页 >

主、侧链修饰对异靛蓝基共轭聚合物结构及电学性能的影响

材料与器件 | 更新时间：2020-07-05

- 主、侧链修饰对异靛蓝基共轭聚合物结构及电学性能的影响
- Effects of modification of main and side chains on the structure and electrical properties of isoindigo-based conjugated polymers
- 液晶与显示 2019年34卷第7期页码：627-633
- 作者机构：
  
  特种显示技术国家工程实验室, 现代显示技术省部共建国家重点实验室培育基地, 合肥工业大学光电技术研究院, 安徽合肥 230009
- 作者简介：
  
  [ "田丰收(1992-), 男, 黑龙江伊春人, 硕士研究生, 2014年于合肥工业大学大学获得学士学位, 主要从事有机半导体材料力学与电学性质研究。E-mail:18656377565@163.com" ]
  [ "邱龙臻(1980-), 男, 福建宁化人, 研究员, 博士生导师, 2006年于中国科学技术大学获得博士学位, 主要从事高分子材料设计合成、高分子薄膜制备和凝聚态结构调控及有机光电子器件等方面的研究。E-mail:lzqiu@hfut.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51573036);国家自然科学基金(51703047);National Natural Science Foundation of China(51573036);National Natural Science Foundation of China(51703047)
- DOI：10.3788/YJYXS20193407.0627
  中图分类号： TB34
- 收稿日期：2019-03-01，
  
  录用日期：2019-4-4，
  
  纸质出版日期：2019-07-05
- 稿件说明：
移动端阅览
田丰收, 邱龙臻, 陈俊辉, 等. 主、侧链修饰对异靛蓝基共轭聚合物结构及电学性能的影响[J]. 液晶与显示, 2019,34(7):627-633.

Feng-shou TIAN, Long-zhen QIU, Jun-hui CHEN, et al. Effects of modification of main and side chains on the structure and electrical properties of isoindigo-based conjugated polymers[J]. Chinese journal of liquid crystals and displays, 2019, 34(7): 627-633.
田丰收, 邱龙臻, 陈俊辉, 等. 主、侧链修饰对异靛蓝基共轭聚合物结构及电学性能的影响[J]. 液晶与显示, 2019,34(7):627-633. DOI： 10.3788/YJYXS20193407.0627.

Feng-shou TIAN, Long-zhen QIU, Jun-hui CHEN, et al. Effects of modification of main and side chains on the structure and electrical properties of isoindigo-based conjugated polymers[J]. Chinese journal of liquid crystals and displays, 2019, 34(7): 627-633. DOI： 10.3788/YJYXS20193407.0627.

摘要

研究了基于异靛蓝及其衍生物的给-受体共轭聚合物主、侧链修饰对电学性能的影响。采用掠入射X射线衍射、原子力显微镜和4200半导体参数测试仪对聚合物结构与形貌以及电学性能进行了表征。实验结果表明，烷基侧链的加入会增大空间位阻，使得分子堆积从较为有序的edge-on结构变得混乱无序，导致结晶性和电学性能的下降。平均空穴迁移率从0.05 cm

·V

-1

·s

-1

下降至2.11×10

-3

·V

-1

·s

-1

。但当主链用苯并二呋喃二酮（BIBDF）这一强吸电子的长共轭单元替代异靛蓝单元之后，由于主链平面性的提高，引起分子堆积变好，结晶性和电学性能显著提高，并不影响溶液加工性且该聚合物显示出良好的双极型传输特性。空气中电子与空穴平均迁移率可以达到0.29 cm

·V

-1

·s

-1

和0.49 cm

·V

-1

·s

-1

。

Abstract

The effects of main and side chain modification of donor-acceptor conjugated polymers based on isoindigo and its derivatives on electrical properties were studied. The structure

morphology and electrical properties of the polymers were characterized by glancing angle X-ray diffraction

atomic force microscopy and Keithley 4200-SCS. The experimental results show that the addition of alkyl side chains can increase the steric hindrance and change the molecular stacking from the ordered edge-on structure to disordered

resulting in the decrease of crystallinity and electrical properties. The average hole mobility decreased from 0.05 cm

·V

-1

·s

-1

to 2.11×10

-3

·V

-1

·s

-1

. However

when the long conjugated unit of benzofuradiadione (BIBDF) is used to replace the isoindigo unit in the main chain

the molecular stacking

crystallinity and electrical properties of the main chain are improved significantly due to the improvement of the planarity of the main chain

which don't affect the solution processability

and the polymer shows good bipolar transmission characteristics. The average mobility of electron and hole can reach to 0.29 cm

·V

-1

·s

-1

and 0.49 cm

·V

-1

·s

-1

关键词

Keywords

references

庞博, 葛丰, 邱龙臻.聚3-己基噻吩-b-聚十六烷氧基联烯嵌段聚合物的制备及其场效应性能[J].发光学报, 2016, 37(6):669-675.

PANG B, GE F, QIU L Z. Synthesis and field effect transistor performance of poly(3-hexylthiophene)- b -poly (hexadecyloxylallene) blockpolymer[J]. Chinese Journal of Luminescence , 2016, 37(6): 669-675. (in Chinese)

MEIJER E J, DE LEEUW D M, SETAYESH S, et al . Erratum: Corrigendum: Solution-processed ambipolar organic field-effect transistors and inverters[J]. Nature Materials , 2003, 2(12): 834-834.

薛战, 田丰收, 王庆贺, 等.氧敏感性供体-受体共轭聚合物薄膜晶体管[J].发光学报, 2018, 39(8):1136-1142.

XUE Z, TIAN F S, WANG Q H, et al . Oxygen sensing characteristics of donor-acceptor conjugated polymer transistors of organic semiconductor film[J]. Chinese Journal of Luminescence , 2018, 39(8): 1136-1142. (in Chinese)

PARK G E, SHIN J, LEE D H, et al . Effect of branched alkyl side chains on the performance of thin-film transistors and photovoltaic cells fabricated with isoindigo-based conjugated polymers[J]. Journal of Polymer Science Part A-Polymer Chemistry , 2015, 53(10): 1226-1234.

SHIN J, PARK G E, LEE D H, et al . Bis(thienothiophenyl) diketopyrrolopyrrole-based conjugated polymers with various branched alkyl side chains and their applications in thin-film transistors and polymer solar cells[J]. ACS Applied Materials & Interfaces , 2015, 7(5): 3280-3288.

WANG B, ZHANG J, TAM H L, et al . Impact of alkyl side chains on the photovoltaic and charge mobility properties of naphthodithiophene-benzothiadiazole copolymers[J]. Polymer Chemistry , 2014, 5(3): 836-843.

GRIMSDALE A C, CHAN K L, MARTIN R E, et al . Synthesis of light-emitting conjugated polymers for applications in electroluminescent devices[J]. Chemical Reviews , 2009, 109(3): 897-1091.

SONAR P, SINGH S P, LI Y N, et al . A low-bandgap diketopyrrolopyrrole-benzothiadiazole-based copolymer for high-mobility ambipolar organic thin-film transistors[J]. Advanced Materials , 2010, 22(47): 5409-5413.

ZHAN X W, FACCHETTI A, BARLOW S, et al . Rylene and related diimides for organic electronics[J]. Advanced Materials , 2011, 23(2): 268-284.

ZHAO Y, GUO Y L, LIU Y Q. Recent advances in n-type and ambipolar organic field-effect transistors[J]. Advanced Materials , 2013, 25(38): 5372-5391.

LEI T, DOU J H, PEI J. Influence of alkyl chain branching positions on the hole mobilities of polymer thin-film transistors[J]. Advanced Materials , 2012, 24(48): 6457-6461.

MEI J G, KIM D H, AYZNER A L, et al . Siloxane-terminated solubilizing side chains: bringing conjugated polymer backbones closer and boosting hole mobilities in thin-film transistors[J]. Journal of the American Chemical Society , 2011, 133(50): 20130-20133.

BABELA, JENEKHE S A. Alkyl chain length dependence of the field-effect carrier mobility in regioregular poly(3-alkylthiophene)s[J]. Synthetic Metals , 2005, 148(2): 169-173.

OSAKA I, ZHANG R, SAUVÉ G, et al . High-lamellar ordering and amorphous-like pi-network in short-chain thiazolothiazole-thiophene copolymers lead to high mobilities[J]. Journal of the American Chemical Society , 2015, 131(7): 2521-2529.

LEI T, DOU H J, CAO Y X, et al . A BDOPV-based donor-acceptor polymer for high-performance n-type and oxygen-doped ambipolar field-effect transistors[J]. Advanced Materials , 2013, 25(45): 6589-6593.

YAN Z Q, SUN B, LI Y N. Novel stable (3E, 7E)-3, 7-bis(2-oxoindolin-3-ylidene)benzo[1, 2-b: 4, 5-b']difuran-2, 6(3H, 7H)-dione based donor-acceptor polymer semiconductors for n-type organic thin film transistors[J] . Chemical Communications , 2013, 49(36): 3790-3792.

LEI T, DOU H J, MA J Z, et al . Chlorination as a useful method to modulate conjugated polymers: balanced and ambient-stable ambipolar high-performance field-effect transistors and inverters based on chlorinated isoindigo polymers[J]. Chemical Science , 2013, 4(6): 2447-2452.

ZHANG G B, LI P, TANG L X, et al . A bis(2-oxoindolin-3-ylidene)-benzodifuran-dione containing copolymer for high-mobility ambipolar transistors[J]. Chemical Communications , 2014, 50(24): 3180-3183.

LEI T, CAO Y, FAN Y L, et al . High-performance air-stable organic field-effect transistors: isoindigo-based conjugated polymers[J]. Journal of the American Chemical Society , 2011, 133(16): 6099-6101.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

暂无数据