新型相邻长支链取代的聚酰亚胺液晶垂直取向剂的合成及其用于液晶显示元件的性能表现

袁震; 马浩源; 张迪; 武玉民; 胡葆华

doi:10.3788/YJYXS20193403.0245

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新型相邻长支链取代的聚酰亚胺液晶垂直取向剂的合成及其用于液晶显示元件的性能表现

材料与器件 | 更新时间：2020-07-05

- 新型相邻长支链取代的聚酰亚胺液晶垂直取向剂的合成及其用于液晶显示元件的性能表现
- Synthesis of a new polyimide liquid crystal vertical aligning agent substituted with adjacent long side chains and its performance in liquid crystal displays
- 液晶与显示 2019年34卷第3期页码：245-253
- 作者机构：
  
  1.青岛科技大学化工学院, 山东青岛 266000
  2.中节能万润股份有限公司, 山东烟台 264000
- 作者简介：
  
  [ "袁震(1993-), 男, 山东青岛人, 硕士研究生, 2016年于曲阜师范大学获得学士学位, 主要从事聚酰亚胺取向膜方面的研究。E-mail:cx00259860@163.com" ]
  [ "胡葆华(1971-), 男, 山东烟台人, 高级工程师, 1994年于大连理工大学获得学士学位, 主要从事聚酰亚胺、分子筛、液晶等方面的研究。E-mail:hubaohua@valiantltd.com" ]
- 基金信息：
- DOI：10.3788/YJYXS20193403.0245
  中图分类号： O753.2
- 收稿日期：2018-07-19，
  
  录用日期：2018-9-26，
  
  纸质出版日期：2019-03
- 稿件说明：
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袁震, 马浩源, 张迪, 等. 新型相邻长支链取代的聚酰亚胺液晶垂直取向剂的合成及其用于液晶显示元件的性能表现[J]. 液晶与显示, 2019,34(3):245-253.

Zhen YUAN, Hao-yuan MA, Di ZHANG, et al. Synthesis of a new polyimide liquid crystal vertical aligning agent substituted with adjacent long side chains and its performance in liquid crystal displays[J]. Chinese journal of liquid crystals and displays, 2019, 34(3): 245-253.
袁震, 马浩源, 张迪, 等. 新型相邻长支链取代的聚酰亚胺液晶垂直取向剂的合成及其用于液晶显示元件的性能表现[J]. 液晶与显示, 2019,34(3):245-253. DOI： 10.3788/YJYXS20193403.0245.

Zhen YUAN, Hao-yuan MA, Di ZHANG, et al. Synthesis of a new polyimide liquid crystal vertical aligning agent substituted with adjacent long side chains and its performance in liquid crystal displays[J]. Chinese journal of liquid crystals and displays, 2019, 34(3): 245-253. DOI： 10.3788/YJYXS20193403.0245.

摘要

报道了一类新型相邻柔性长支链聚酰亚胺液晶垂直取向剂的合成，并考察其用于液晶显示元件的性能表现。首先，以2，3，4-三氟硝基苯、4-（4-庚基环己基）-苯酚、邻苯二甲酰亚胺钾盐等原料合成了含有相邻柔性长支链结构的新型功能性对苯二胺（L-14），通过核磁共振波谱（NMR）和高压液相色质联用（HPLC-MS）对目标产物进行结构表征。用1，2，3，4-环丁烷四甲酸二酐（CBDA）、对苯二胺（PDA）和L-14制备了一类PDA与L-14不同比例的聚酰亚胺液晶垂直取向剂，并对以该聚酰亚胺膜作为液晶取向层制得的液晶显示元件开展了预倾角、液晶定向时间、陡度、对比度等性能测试。结果表明，基于该新型聚酰亚胺液晶垂直取向膜的液晶显示元件耐磨性能强、液晶定向时间短、取向性能优良、显示画面清晰。

Abstract

The synthesis of a new polyimide liquid crystal vertical alignment agent substituted with adjacent double long side chains was reported

and its performance for liquid crystal display elements was investigated. First

4-trifluoronitrobenzene

4-(4-heptylcyclohexyl)-phenol

phthalimide potassium salt and other raw materials were used to synthesize a functional diamine (L-14) substituted with adjacent double long side chains. The diamine L-14 was characterized by NMR and HPLC-MS. Then a kind of polyimide liquid crystal vertical alignment agents were prepared using 1

4-cyclobutanetetracarboxylic dianhydride (CBDA)

p-phenylenediamine (PDA) and L-14 with variant ratio of L-14/PDA. The liquid crystal display elements prepared with thus obtained polyimine film as the aligning layer were subjected to performance tests such as pretilt angle

liquid crystal aligning time

steepness

and contrast. The results show that the liquid crystal display elements based on the newly synthesized polyimide liquid crystal vertical aligning film possess strong abrasion resistance

short liquid crystal aligning time

excellent orientation performance

and clear display image.

关键词

Keywords

references

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