反应温度对亲核试剂引发点击化学制备聚合物分散液晶电光性能的影响

毛远洪; 邵磊山; 李静静; 钟向宏; 肖树萌; 王莹; 石志清; 汪映寒

doi:10.3788/YJYXS20173212.0968

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反应温度对亲核试剂引发点击化学制备聚合物分散液晶电光性能的影响

材料科学 | 更新时间：2020-07-07

- 反应温度对亲核试剂引发点击化学制备聚合物分散液晶电光性能的影响
- Effects of reaction temperature on electro-optical properties of polymer-dispersed liquid crystal films fabricated by nucleophile-initiated thiol-ene click reaction
- 液晶与显示 2017年32卷第12期页码：968-972
- 作者机构：
  
  1.中国石油化工股份有限公司茂名分公司, 广东茂名 525000
  2.四川大学高分子科学与工程学院, 四川成都 610065
- 作者简介：
  
  [ "毛远洪(1971-), 男, 广东茂名人, 硕士研究生, 主要从事高分子材料方面的研究。E-mail:maoyh.mmsh@sinopec.com" ]
  [ "汪映寒(1964-), 男, 四川成都人, 教授, 主要从事高分子材料方面的研究。E-mail:wang_yh@scu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51173115);Supported by National Natural Science Foundation of China(51173115)
- DOI：10.3788/YJYXS20173212.0968
  中图分类号： TP394.1;TH691.9
- 收稿日期：2017-08-21，
  
  录用日期：2017-9-25，
  
  纸质出版日期：2017-12-05
- 稿件说明：
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毛远洪, 邵磊山, 李静静, 等. 反应温度对亲核试剂引发点击化学制备聚合物分散液晶电光性能的影响[J]. 液晶与显示, 2017,32(12):968-972.

Yuan-hong MAO, Lei-shan SHAO, Jing-jing LI, et al. Effects of reaction temperature on electro-optical properties of polymer-dispersed liquid crystal films fabricated by nucleophile-initiated thiol-ene click reaction[J]. Chinese journal of liquid crystals and displays, 2017, 32(12): 968-972.
毛远洪, 邵磊山, 李静静, 等. 反应温度对亲核试剂引发点击化学制备聚合物分散液晶电光性能的影响[J]. 液晶与显示, 2017,32(12):968-972. DOI： 10.3788/YJYXS20173212.0968.

Yuan-hong MAO, Lei-shan SHAO, Jing-jing LI, et al. Effects of reaction temperature on electro-optical properties of polymer-dispersed liquid crystal films fabricated by nucleophile-initiated thiol-ene click reaction[J]. Chinese journal of liquid crystals and displays, 2017, 32(12): 968-972. DOI： 10.3788/YJYXS20173212.0968.

摘要

光聚合诱导相分离法是应用最广泛的制备聚合物分散液晶（PDLC）膜的方法。为了提高PDLC的对比度（CR），通常在PDLC膜中引入二色性染料。然而，目前商业化的染料掺杂PDLC膜还很少，因为光聚合诱导相分离法使用的紫外光会使染料分解；另外，染料会吸收紫外光导致预聚物的聚合速率变慢。亲核试剂引发点击化学反应是最近合成化学的研究热点，可在无紫外光的条件下发生。因此，用亲核试剂引发点击化学反应制备PDLC膜，有望克服传统光聚合诱导相分离法的缺点。本论文，采用亲核试剂引发巯基-烯烃点击化学反应制备PDLC膜，并研究了反应温度对PDLC电光性能的影响。结果表明，温度的改变导致液晶微滴的尺寸发生变化，进而对PDLC的电光性能产生影响。温度升高使得开态透过率（

）变小，阈值电压（

）和饱和电压（

sat

）升高。

Abstract

Photo-polymerization-induced phase separation is a most widely used method to fabricate polymer dispersed liquid crystal (PDLC) films. Meanwhile

dichroic dye is usually introduced into PDLC films to enhance the contrast ratio. However

until now

commercial dye-doped PDLC films are still very few

because UV-light can make dye decompose in the process of photo-polymerization-induced phase separation and dye absorbs UV-light causing the polymerization rate of the prepolymer to slow down. Recently

nucleophile-initiated click reaction

which can be processed without UV-light

is a research hotspot in synthetic chemistry. Thus

fabricating PDLC films via click reaction initiated by nucleophile may hopefully overcome the shortcomings of traditional photo-polymerization-induced phase separation method. In our work

PDLC films were prepared via thiol-ene click reaction initiated by nucleophile. The influences of reaction temperature on electro-optical properties of PDLC were investigated. It was found that reaction temperature influenced the electro-optical properties of PDLC films by changing the droplets size of liquid crystal. With the increase of reaction temperature

ON state transmittance (

) decreases

while threshold voltage (

) and saturation voltage (

sat

) increases.

关键词

Keywords

references

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