氮(氧)化物荧光粉的合成与发光性能

武文杰; 阿木古楞; 刘文全; 朝克夫; 特古斯

doi:10.3788/YJYXS20173209.0663

您当前的位置：

首页 >

文章列表页 >

氮(氧)化物荧光粉的合成与发光性能

材料科学 | 更新时间：2020-07-07

- 氮(氧)化物荧光粉的合成与发光性能
- Synthesis and luminescence of nitride and oxynitride luminescent materials
- 液晶与显示 2017年32卷第9期页码：663-676
- 作者机构：
  
  1.内蒙古师范大学物理与电子信息学院, 内蒙古呼和浩特 010022
  2.内蒙古自治区功能材料物理与化学重点实验室, 内蒙古呼和浩特 010022
  3.锡林郭勒职业技术学院, 内蒙古锡林浩特 026000
- 作者简介：
  
  [ "武文杰(1992-), 男, 山西忻州人, 硕士研究生在读, 2015年获得学士学位, 现在为内蒙古师范大学在读硕士研究生。E-mail:786278714@qq.com" ]
  [ "朝克夫(1979-), 男, 内蒙古锡林郭勒人, 博士, 副教授, 主要从事的研究方向为发光量子点材料的合成制备以及应用, 稀土掺杂发光材料的合成与特性研究, 纳米复合材料的合成与性质研究以及白光LED封装应用研究。E-mail: phyerick@imnu.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(51262022);2015年度内蒙古自治区科技计划;2016年度内蒙古自治区科技创新引导奖励基金;内蒙古自治区研究生科研创新项目;内蒙古师范大学研究生科研基金创新项目;National Natural Science Foundation of China(51262022);Science and Technology Plan of the Inner Mongolia Autonomous Region in 2015;Science and Technology Innovation Guidance Award Fund of the Inner Mongolia Autonomous Region in 2016;Research Project of Graduate Students in the Inner Mongolia Autonomous Region;Innovative Project of Research Fund for Graduate Students of Inner Mongolia Normal University
- DOI：10.3788/YJYXS20173209.0663
  中图分类号： O482.31
- 收稿日期：2017-05-01，
  
  录用日期：2017-6-2，
  
  纸质出版日期：2017-09-05
- 稿件说明：
移动端阅览
武文杰, 阿木古楞, 刘文全, 等. 氮(氧)化物荧光粉的合成与发光性能[J]. 液晶与显示, 2017,32(9):663-676.

Wen-jie WU, Amugulen, Wen-quan LIU, et al. Synthesis and luminescence of nitride and oxynitride luminescent materials[J]. Chinese journal of liquid crystals and displays, 2017, 32(9): 663-676.
武文杰, 阿木古楞, 刘文全, 等. 氮(氧)化物荧光粉的合成与发光性能[J]. 液晶与显示, 2017,32(9):663-676. DOI： 10.3788/YJYXS20173209.0663.

Wen-jie WU, Amugulen, Wen-quan LIU, et al. Synthesis and luminescence of nitride and oxynitride luminescent materials[J]. Chinese journal of liquid crystals and displays, 2017, 32(9): 663-676. DOI： 10.3788/YJYXS20173209.0663.

摘要

为了制备高性能的白光LED，发光性能好的荧光粉是必不可少的。氮（氧）化物荧光粉有着发光效率高、可进行光谱剪裁、绿色环保、热稳定性好的优点，可以成为制备白光LED的主要的荧光粉材料。本文综述了近几年来在氮（氧）化物荧光粉的晶体结构特征、制备方法，发光性质及其在高亮度、高显色白光LED封装应用的最新进展，并指出该领域研究过程中存在的问题：（1）含有不同非金属成份的氮（氧）化物新基质很少，（2）关于计算荧光粉晶体场变化的理论研究很少，（3）目前单一基质白光发射荧光粉的发射普遍存在红色发射成分缺乏或不足、显色指数不高等问题。对该领域的发展趋势做出了展望，希望推动新型高效白光LED用发光材料的研究，继而提高白光LED研究应用水平。

Abstract

In recent years

white light-emitting diodes are emerging as an indispensable solid state lighting source for the next generation lighting industry and display systems because of its high efficiency

energy saving

environmental protection and long service life. In order to prepare high performance white light LED

phosphors with good luminescent properties are essential. And nitride and oxynitride luminescent material become important candidate materials for white LED because of their excellent properties

such as high luminous efficiency

excellent spectral cutting

green environmental protection

high thermal stability

and so on. In this review

the crystal structure

the preparation methods and the photoluminescence properties of nitride and oxynitride based phosphors as well as applications of WLEDs were summarized. In addition

challenges of nitride and oxynitride based phosphors are discussed:(1) The nitride and oxynitride luminescent material that contains different nonmetallic components is rare.(2) The theories for calculating crystal field changes of phosphors are rare.(3) The emission of single base white light emitting phosphor generally exists in the absence or deficiency of the red emitting component and the low color rendering index. The work we did aims to promote the development of nitride and oxynitride luminescent material.

关键词

Keywords

references

孙晓园, 王玉晓, 祁金刚, 等.M 2 Eu x Ln 1- x AlO 5 (M=Ca, Sr, Ba, Ln=La, Gd, Lu)红色荧光粉发光性质的研究[J].发光学报, 2016, 37(2):138-143.

SUN X Y, WANG Y X, QI J G, et al. Photoluminescence properties of M 2 Eu x Ln 1- x AlO 5 (M=Ca, Sr, Ba, Ln=La, Gd, Lu)red phosphor[J]. Chinese Journal of Luminescence, 2016, 37(2):138-143. (in Chinese)

肖华, 吕毅军, 徐云鑫, 等.传统白光LED与远程荧光粉白光LED的发光性能比较[J].发光学报, 2014, 35(1):66-72.

XIAO H, Lü Y J, XU Y X, et al. The difference of luminous performance between traditional phosphor packaging LED and remote phosphor LED[J]. Chinese Journal of Luminescence, 2014, 35(1):66-72. (in Chinese)

罗洋, 江建青, 侯得健, 等.共沉淀法制备暖白光LED用Na 2 TiF 6 :Mn 4+ 红色荧光粉及其发光性能研究[J].发光学报, 2015, 36(12):1402-1408.

LUO Y, JIANG J Q, HOU D J, et al. Co-precipitation synthesis and luminescence properties of Na 2 TiF 6 :Mn 4+ Red phosphors for warm white light emitting diodes[J]. Chinese Journal of Luminescence, 2015, 36(12):1402-1408. (in Chinese)

黄波, 童玉珍, 李成明, 等.基于荧光玻璃的高效LED白光技术[J].发光学报, 2016, 37(6):637-643.

HUANG B, TONG Y Z, LI C M, et al. High-efficiency technology of LED white light based on phosphor glass[J]. Chinese Journal of Luminescence, 2016, 37(6):637-643. (in Chinese)

叶信宇, 罗洋, 刘松彬, 等.LiGd(W y Mo 1- y ) 2 O 8- x /2 F x :Eu 3+ 红色荧光粉的制备和发光特性[J].发光学报, 2016, 37(10):1203-1212.

YE X Y, LUO Y, LIU S B, et al. Synthesis and luminescence properties of LiGd(W y Mo 1- y ) 2 O 8- x /2 F x :Eu 3+ Red phosphors[J]. Chinese Journal of Luminescence, 2016, 37(10):1203-1212. (in Chinese)

孙晓园, 张家骅, 张霞, 等.新一代白光LED照明用一种适于近紫外光激发的单一白光荧光粉[J].发光学报, 2005, 26(3):404-406.

SUN X Y, ZHANG J H, ZHANG X, et al. A single white phosphor suitable for near ultraviolet excitation applied to new generation white LED lighting[J]. Chinese Journal of Luminescence, 2005, 26(3):404-406. (in Chinese)

谢飞燕, 董志月, 刁贵强, 等.一种新型的白光LED用绿色荧光粉Ca 8 MgLu(PO 4 ) 7 :Tb 3+ [J].发光学报, 2015, 36(10):1132-1136.

XIE F Y, DONG Z Y, DIAO G Q, et al. A novel green phosphor Ca 8 MgLu(PO 4 ) 7 :Tb 3+ for near ultraviolet white light-emitting diodes[J]. Chinese Journal of Luminescence, 2015, 36(10):1132-1136. (in Chinese)

吴疆, 张萍, 蒋春东, 等.橙红色荧光粉Ca 3 Y 2 Si 3 O 12 :Sm 3+ 的制备及发光特性[J].发光学报, 2014, 35(7):772-776.

WU J, ZHANG P, JIANG C D, et al. Preparation and luminescence properties of reddish-orange phosphors Ca 3 Y 2 Si 3 O 12 :Sm 3+ [J]. Chinese Journal of Luminescence, 2014, 35(7):772-776. (in Chinese)

李慧娟, 邵起越, 董岩, 等.白光LED用YAG:Ce 3+ 荧光粉的温度猝灭性质[J].发光学报, 2008, 29(6):984-988.

LI HJ, SHAO Q Y, DONG Y, et al. The thermal quenching of YAG:Ce 3+ phosphors for White LED application[J]. Chinese Journal of Luminescence, 2008, 29(6):984-988. (in Chinese)

孔丽, 甘树才, 洪广言, 等.Pr 3+ 或Sm 3+ 掺杂YAG:Ce 3+ 的发光特性及其荧光寿命[J].发光学报, 2007, 28(3):393-396.

KONG L, GAN SC, HONG G Y, et al. Luminescence properties of YAG:Ce 3+ Co-doped with Pr 3+ or Sm 3+ [J]. Chinese Journal of Luminescence, 2007, 28(3):393-396. (in Chinese)

马林, 胡建国, 万国江, 等.YAG:Ce发光材料合成的助熔剂研究[J].发光学报, 2006, 27(3):348-352.

MA L, HU J G, WAN G J, et al. Effect of Flux on YAG:Ce phosphors prepared by solid-state reactions[J]. Chinese Journal of Luminescence, 2006, 27(3):348-352. (in Chinese)

XIE R J, HINTZEN H T. Optical properties of (oxy)nitride materials:a review[J]. Journal of the American Ceramic Society, 2013, 96(3):665-687.

XIE R J, HIROSAKI N. Silicon-based oxynitride and nitride phosphors for white LEDs-a review[J]. Science and Technology of Advanced Materials, 2007, 8(7/8):588-600.

LI Y Q, HIROSAKI N, XIE R J, et al. Photoluminescence properties of rare earth doped α-Si 3 N 4 [J]. Journal of Luminescence, 2010, 130(7):1147-1153.

YIN L J, XU X, YU W, et al. Synthesis of Eu 2+ -Doped AlN phosphors by carbothermal reduction[J]. Journal of the American Ceramic Society, 2010, 93(6):1702-1707.

XIE R J, HIROSAKI N, SAKUMA K, et al. Eu 2+ -doped Ca-α-SiAlON:A yellow phosphor for white light-emitting diodes[J]. Applied Physics Letters, 2004, 84(26):5404-5406.

LI Y Q, VAN STEEN J E J, VAN KREVEL J W H, et al. Luminescence properties of red-emitting M 2 Si 5 N 8 :Eu 2+ (M=Ca, Sr, Ba) LED conversion phosphors[J]. Journal of Alloys and Compounds, 2006, 417(1/2):273-279.

VAN KREVEL J W H, VAN RUTTEN J W T, MANDAL H, et al. Luminescence properties of terbium-, cerium-, or europium-doped α -sialon materials[J]. Journal of Solid State Chemistry, 2002, 165(1):19-24.

XIE R J, MITOMO M, UHEDA K, et al. Preparation and luminescence spectra of calcium-and rare-earth (R=Eu, Tb, and Pr)-codoped α-sialon ceramics[J]. Journal of the American Ceramic Society, 2002, 85(5):1229-1234.

SCHLIEPER D C T, MILIUS W, SCHNICK W. Nitrido-silicate. Ⅱ[1]. Hochtemperatur-synthesen and kristallstrukturen von Sr 2 Si 5 N 8 und Ba 2 Si 5 N 8 [J]. Zeitschrift für Anorganische and Allgemeine Chemie, 1995, 621(8):1380-1384.

PIAO X Q, HORIKAWA T, HANZAWA H, et al. Characterization and luminescence properties of Sr 2 Si 5 N 8 :Eu 2+ phosphor for white light-emitting-diode illumination[J]. Applied Physics Letters, 2006, 88(16):161908.

VAN KREVEL J W H, HINTZEN H T, METSELAAR R, et al. Long wavelength Ce 3+ emission in Y-Si-O-N materials[J]. Journal of Alloys and Compounds, 1998, 268(1/2):272-277.

YANG H C, LI C Y, PANG R, et al. Blue-to-orange tunable luminescence from europium doped yttrium-silicon-oxide-nitride phosphors[J]. Chinese Physics Letters, 2008, 25(9):3444-3447.

LI J W, WATANABE T, SAKAMOTO N, et al. Synthesis of a multinary nitride, Eu-doped CaAlSiN 3 , from alloy at low temperatures[J]. Chemistry of Materials, 2008, 20(6):2095-2105.

ZEUNER M, SCHMIDT P J, SCHNICK W. One-pot synthesis of single-source precursors for nanocrystalline LED phosphors M 2 Si 5 N 8 :Eu 2+ (M=Sr, Ba)[J]. Chemistry of Materials, 2009, 21(12):2467-2473.

HIROSAKI N, XIE R J, KIMOTO K, et al. Characterization and properties of green-emitting β-SiAlON:Eu 2+ powder phosphors for white light-emitting diodes[J]. Applied Physics Letters, 2005, 86(21):211905.

UHEDA K, HIROSAKI N, YAMAMOTO Y, et al. Luminescence properties of a red phosphor, CaAlSiN 3 :Eu 2+ , for white light-emitting diodes[J]. Electrochemical and Solid-State Letters, 2006, 9(4):H22-H25.

HÖPPE H A, STADLER F, OECKLER O, et al. Ca[Si 2 O 2 N 2 ]-a novel layer silicate[J] . Angewandte Chemie International Edition, 2004, 43(41):5540-5542.

SUEHIRO T, HIROSAKI N, XIE R J, et al. Blue-emitting LaSi 3 N 5 :Ce 3+ fine powder phosphor for UV-converting white light-emitting diodes[J]. Applied Physics Letters, 2009, 95(5):051903.

SUEHIRO T, ONUMA H, HIROSAKI N, et al. Powder synthesis of Y-α-SiAlON and its potential as a phosphor host[J]. The Journal of Physical Chemistry C, 2010, 114(2):1337-1342.

CHEN L, XUE S C, CHEN X L, et al. Formation of the amorphous phase in the carbothermal reduction and nitridation route to SrSi 2 O 2 N 2 :Eu 2+ :a new understanding of the catalytic effect of carbon in the synthesis of Sr 2 Si 5 N 8 :Eu 2+ for white LEDs[J]. RSC Advances, 2014, 4(83):44317-44321.

YURDAKUL H, CEYLANTEKIN R, TURAN S. A novel approach on the synthesis of β-SiAlON:Eu 2+ phosphors from kaolin through carbothermal reduction and nitridation (CRN)route[J]. Advances in Applied Ceramics, 2014, 113(4):214-222.

WANG Q, GE Y Y, CHEN Y, et al. SHS of Eu 2+ -doped β-SiAlON phosphors:Impacts of N 2 pressure and Si particle size[J]. Ceramics International, 2017, 43(5):4456-4461.

CHUNG S L, HUANG S C. Synthesis of CaAlSiN 3 :Eu 2+ phosphor via the self-propagating high temperature synthesis method and its optical properties[J]. Advanced Materials Research, 2014, 904:33-35.

SOHN K S, KWAK J H, JUNG Y S, et al. Luminescence of Sr 2 SiO 4- x N 2 x /3 :Eu 2+ phosphors prepared by spark plasma sintering[J]. Journal of the Electrochemical Society, 2008, 155(2):J58-J61.

SHI Z Q, YANG W L, BAI S J, et al. Preparation of Eu 2+ -doped AlN phosphors by plasma activated sintering[J]. Ceramics International, 2011, 37(6):2051-2054.

SONG X F, FU R L, AGATHOPOULOS S, et al. Luminescence and energy-transfer mechanism in SrSi 2 O 2 N 2 :Ce 3+ , Eu 2+ phosphors for white LEDs[J]. Journal of the Electrochemical Society, 2010, 157(2):J34-J38.

贺香红, 周健, 连宁, 等.白光LED用新型红色荧光粉的组成与发光性能的关系[J].硅酸盐通报, 2009, 28(4):741-750.

HE X H, ZHOU J, LIAN N, et al. Dependence of photoluminescence performance on composition of novel red-emitting phosphors for white LEDs application[J]. Bulletin of the Chinese Ceramic Society, 2009, 28(4):741-750. (in Chinese)

赵昕冉, 傅仁利, 宋秀峰, 等.白光LED用硅基氮(氧)化物荧光转换材料的研究进展[J].硅酸盐通报, 2009, 28(5):965-972.

ZHAO X R, FU R L, SONG X F, et al. Research progress in silicon-based (oxy) Nitride phosphors for White LED[J]. Bulletin of the Chinese Ceramic Society, 2009, 28(5):965-972. (in Chinese)

耿秀娟, 陈永杰, 田彦文, 等.白光LED用新型硅基氮化物红色荧光粉研究进展[J].化工新型材料, 2010, 38(11):15-17.

GENG X J, CHEN Y J, TIAN Y W, et al. Progress on silicon nitride red emitting phosphor used for white-LED[J]. New Chemical Materials, 2010, 38(11):15-17. (in Chinese)

VAN KREVEL J W H, VAN RUTTEN J W T, MANDAL H, et al. Luminescence properties of terbium-, cerium-, or europium-doped α-sialon materials[J]. Journal of Solid State Chemistry, 2002, 165(1):19-24.

XIE R J, HIROSAKI N, SAKUMA K, et al. Eu 2+ -doped Ca- α -SiAlON:A yellow phosphor for white light-emitting diodes[J]. Applied Physics Letters, 2004, 84(26):5404-5406.

XIE R J, HIROSAKI N, MITOMO M, et al. Photoluminescence of cerium-doped α-SiAlON materials[J]. Journal of the American Ceramic Society, 2004, 87(7):1368-1370.

TAKAHASHI K, HIROSAKI N, XIE R J, et al. Luminescence properties of blue La 1- x Ce x Al(Si 6- z Al z ) (N 10- z O z ) ( z ~1) oxynitride phosphors and their application in white light-emitting diode[J]. Applied Physics Letters, 2007, 91(9):091923.

XIE R J, HIROSAKI N, YAMAMOTO Y, et al. Fluorescence of Eu 2+ in strontium oxonitridoaluminosilicates (SiAlONS)[J]. Journal of the C eramic Society of Japan, 2005, 113(7):462-465.

HIROSAKI N, XIE R J, INOUE K, et al. Blue-emitting AlN:Eu 2+ nitride phosphor for field emission displays[J]. Applied Physics Letters, 2007, 91(6):061101.

WANG X M, WANG C H, WU M M, et al. O/N ordering in the structure of Ca 3 Si 2 O 4 N 2 and the luminescence properties of the Ce 3+ doped material[J]. Journal of Materials Chemistry, 2012, 22(8):3388.

PUCHER F J, MARCHUK A, SCHMIDT P J, et al. Luminescent nitridophosphates CaP 2 N 4 :Eu 2+ , SrP 2 N 4 :Eu 2+ , BaP 2 N 4 :Eu 2+ , and BaSr 2 P 6 N 12 :Eu 2+ [J]. Chemistry, 2015, 21(17):6443-6448.

YAMADA S, EMOTO H, IBUKIYAMA M, et al. Properties of SiAlON powder phosphors for white LEDs[J]. Journal of the European Ceramic Society, 2012, 32(7):1355-1358.

张学杰, 刘如熹.广色域背光源用绿色荧光粉β-SiAlON:Eu 2+ 的研究进展[J].中国稀土学报, 2016, 34(6):667-674.

ZHANG X J, LIU R S. Recent progress of green phosphor β-SiAlON:Eu 2+ used for wide-color gamut displays[J]. Journal of the Chinese Society of Rare Earths, 2016, 34(6):667-674. (in Chinese)

XIE R J, HIROSAKI N, MITOMO M, et al. Strong green emission from α-SiAlON activated by divalent ytterbium under blue light irradiation[J]. The Journal of Physical Chemistry B, 2005, 109(19):9490-9494.

LI Y Q, DELSING A C A, DE WITH G, et al. Luminescence properties of Eu 2+ -activated alkaline-earth silicon-oxynitride MSi 2 O 2-δ N 2+2/3δ (M=Ca, Sr, Ba):a promising class of novel LED conversion phosphors[J]. Chemistry of Materials, 2005, 17(12):3242-3248.

YIN L J, XU X, HAO L Y, et al. Synthesis and photoluminescence of Eu 2+ -Mg 2+ co-doped γ-AlON phosphors[J]. Materials Letters, 2009, 63(17):1511-1513.

YANG X F, SONG H L, YANG L X, et al. Reaction mechanism of SrSi 2 O 2 N 2 :Eu 2+ phosphor prepared by a direct silicon nitridation method[J]. Journal of the American Ceramic Society, 2011, 94(1):164-171.

DUAN C J, WANG X J, OTTEN W M, et al. Preparation, electronic structure, and photoluminescence properties of Eu 2+ -and Ce 3+ /Li + -activated alkaline earth silicon Nitride MSiN 2 (M=Sr, Ba)[J]. Chemistry of Materials, 2008, 20(4):1597-1605.

LI Y Q, HIROSAKI N, XIE R J, et al. Yellow-orange-emitting CaAlSiN 3 :Ce 3+ phosphor:Structure, photoluminescence, and application in white LEDs[J]. Chemistry of Materials, 2008, 20(21):6704-6714.

WAN J Q, LIU Q, LIU G H, et al. Y 2 Si 4 N 6 C:Ce 3+ carbidonitride green-yellow phosphors:Novel synthesis, photoluminescence properties, and applications[J]. Journal of Materials Chemistry C, 2017, 5(24):6061-6070.

XIE R J, HIROSAKI N, MITOMO M, et al. Wavelength-tunable and thermally stable Li-α-SiAlON:Eu 2+ oxynitride phosphors for white light-emitting diodes[J]. Applied Physics Letters, 2006, 89(24):241103.

ZHANG L L, ZHANG J H, ZHANG X, et al. New yellow-emitting nitride phosphor SrAlSi 4 N 7 :Ce 3+ and important role of excessive AlN in material synthesis[J]. ACS Applied Materials & Interfaces, 2013, 5(24):12839-12846.

MARCHUK A, WENDL S, IMAMOVIC N, et al. Nontypical luminescence properties and structural relation of Ba 3 P 5 N 10 X:Eu 2+ (X=Cl, I):Nitridophosphate halides with zeolite-like structure[J]. Chemistry of Materials, 2015, 27(18):6432-6441.

KIM H S, MACHIDA K I, HORIKAWA T, et al. Luminescence properties of CaAlSiN 3 :Eu 2+ phosphor prepared by direct-nitriding method using fine metal hydride powders[J]. Journal of Alloys and Compounds, 2015, 633:97-103.

林海凤, 王海波, 张瑞西, 等.白光LED用氮化物及氮氧化物红色荧光粉的研究现状[J].材料导报, 2010, 24(21):10-13.

LIN H F, WANG H B, ZHANG R X, et al. Present research situation of the nitride and oxynitride red phosphors for white-LED[J]. Materials Review, 2010, 24(21):10-13. (in Chinese)

LI J F, ZHANG H R, WANG P, et al. Luminescence properties of high-quality Ca 2 Si 5 N 8 :Eu 2+ phosphor:CaH 2 -raw material[J]. ECS Journal of Solid State Science and Technology, 2013, 2(9):R165-R168.

PIAO X Q, MACHIDA K I, HORIKAWA T, et al. Preparation of CaAlSiN 3 :Eu 2+ phosphors by the self-propagating high-temperature synthesis and their luminescent properties[J] . Chemistry of Materials, 2007, 19(18):4592-4599.

LI S X, PENG X, LIU X J, et al. Photoluminescence of CaAlSiN 3 :Eu 2+ -based fine red-emitting phosphors synthesized by carbothermal reduction and nitridation method[J]. Optical Materials, 2014, 38:242-247.

LI Y Q, DE WITH G, HINTZEN H T. The effect of replacement of Sr by Ca on the structural and luminescence properties of the red-emitting Sr 2 Si 5 N 8 :Eu 2+ LED conversion phosphor[J]. Journal of Solid State Chemistry, 2008, 181(3):515-524.

WANG T, XIANG Q C, XIA Z G, et al. Evolution of structure and photoluminescence by cation cosubstitution in Eu 2+ -doped (Ca 1- x Li x )(Al 1- x Si 1+ x )N 3 solid solutions[J]. Inorganic Chemistry, 2016, 55(6):2929-2933.

HUANG W Y, YOSHIMURA F, UEDA K, et al. Domination of second-sphere shrinkage effect to improve photoluminescence of red nitride phosphors[J]. Inorganic Chemistry, 2014, 53(24):12822-12831.

刘文全, 朝克夫, 武文杰, 等.CaAlSiN 3 :Eu 2+ 红色荧光粉的常压氮化制备及发光性能[J].物理学报, 2016, 65(20):207801.

LIU W Q, CHAO K F, WU W J, et al. CaAlSiN 3 :Eu 2+ red phosphors synthesized by atmospheric nitrogen and their luminescence properties[J]. Acta Physica Sinica, 2016, 65(20):207801.(in Chinese)

PUST P, WEILER V, HECHT C, et al. Narrow-band red-emitting Sr[LiAl 3 N 4 ]:Eu 2+ as a next-generation LED-phosphor material[J]. Nature Materials, 2014, 13(9):891-896.

DING J Y, WU Q S, LI Y Y, et al. αM 3 B 2 N 4 (M=Ca, Sr):Eu 3+ :A nitride-based red phosphor with a sharp emission line and broad excitation band used for WLED[J]. The Journal of Physical Chemistry C, 2017, 121(18):10102-10111.

PONCÉ S, JIA Y C, GIANTOMASSI M, et al. Understanding thermal quenching of photoluminescence in oxynitride phosphors from first principles[J]. The Journal of Physical Chemistry C, 2016, 120(7):4040-4047.

JANG S, IM J, BANG B K, et al. First-principles calculation of metal-doped CaAlSiN 3 :Material design for new phosphors[J]. RSC Advances, 2015, 5(49):39319-39323.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

LED用KZn₄（BO₃）₃：Eu³⁺荧光粉的合成与发光性能研究

白光LED用Sr₃(PO₄)₂ ∶ Tb³⁺,Li⁺ 荧光粉的制备工艺及发光性能

新型Ba₂ZnS₃ : Cu荧光粉的合成及其发光性能

共沉淀法制备PDP用红色荧光粉 (Y, Gd)BO₃ : Eu³⁺的正交实验研究