芳基取代蒽衍生物的合成及发光性能研究

吕宏飞; 张惠; 杨杰; 吴绵园; 李猛; 徐虹; 白雪峰

doi:10.3788/YJYXS20163112.1105

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芳基取代蒽衍生物的合成及发光性能研究

材料与器件 | 更新时间：2020-07-07

- 芳基取代蒽衍生物的合成及发光性能研究
- Synthesis and properties of anthracene derivatives using as electroluminescent materials in OLEDs
- 液晶与显示 2016年31卷第12期页码：1105-1111
- 作者机构：
  
  黑龙江省科学院石油化学研究院, 黑龙江哈尔滨 150040
- 作者简介：
  
  [ "吕宏飞(1975-), 男, 吉林榆树人, 博士, 研究员, 主要从事有机电致发光材料合成及表征工作。E-mail:maillhf@163.com" ]
  白雪峰(1965-), 男, 内蒙古赤峰人, 博士, 研究员, 主要从事有机电致发光材料制备及工业催化领域研究工作。E-mail:tommybai@126.com; maillhf@163.com
- 基金信息：
  
  黑龙江省哈尔滨市科技攻关项目(2011AA4AG066);Supported by Harbin Programs for Science and Technology Development(2011AA4AG066)
- DOI：10.3788/YJYXS20163112.1105
  中图分类号： TN383.1
- 收稿日期：2016-06-22，
  
  录用日期：2016-9-12，
  
  纸质出版日期：2016-12-05
- 稿件说明：
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吕宏飞, 张惠, 杨杰, 等. 芳基取代蒽衍生物的合成及发光性能研究[J]. 液晶与显示, 2016,31(12):1105-1111.

Hong-fei LV, Hui ZHANG, Jie YANG, et al. Synthesis and properties of anthracene derivatives using as electroluminescent materials in OLEDs[J]. Chinese journal of liquid crystals and displays, 2016, 31(12): 1105-1111.
吕宏飞, 张惠, 杨杰, 等. 芳基取代蒽衍生物的合成及发光性能研究[J]. 液晶与显示, 2016,31(12):1105-1111. DOI： 10.3788/YJYXS20163112.1105.

Hong-fei LV, Hui ZHANG, Jie YANG, et al. Synthesis and properties of anthracene derivatives using as electroluminescent materials in OLEDs[J]. Chinese journal of liquid crystals and displays, 2016, 31(12): 1105-1111. DOI： 10.3788/YJYXS20163112.1105.

摘要

为提高有机电致发光材料热稳定性和发光效率，设计合成了新型萘基蒽类蓝光材料。以9-溴-10-（2-萘基）蒽为原料，分别同4-（1-萘基）苯硼酸和4-（2-萘基）苯硼酸在四（三苯基膦）钯催化下进行Suzuki偶联，合成10-（2-萘基）-9-（4-（1-萘基）苯基）蒽（NPNA-1）和10-（2-萘基）-9-（4-（2-萘基）苯基）蒽（NPNA-2）。采用红外、核磁对其结构进行表征，通过TG、DSC分析对其热稳定性进行研究，采用紫外和荧光光谱对其光谱性能进行表征。在波长378 nm波长光激发下，二者均显现出了强发光性能，NAPA-1的

max

为424 nm，NAPA-2的

max

为428 nm，均为优秀的蓝光材料。

Abstract

9-(4-(naphthalen-1-yl) phenyl)-10-(naphthalen-2-yl) anthracene (NAPA-1) and 9-(naphthalen-2-yl)-10-(4-(naphthalen-2-yl) phenyl) anthracene (NAPA-2) are synthesized starting from 9-bromo-10-(naphthalen-2-yl) anthracene

4-(naphthalene-1-yl) phenylboronic acid and 4-(naphthalen-2-yl) phenylboronic acid by Suzuki coupling reaction. Structures of the target compounds are characterized by IR

NMR. Results of TG and DSC analysis show the compounds have good thermal stability. The PL spectra of NAPA-1 and NAPA-2 in solution were found to exhibit excellent blue emission with the peak maxima at

max

=424 nm

428 nm respectively.NAPA-1 and NAPA-2 have excellent light emitting performance and could be used as materials for organic light emitting diodes (OLEDs).

关键词

Keywords

references

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