聚合物稳定蓝相液晶用单体研究进展

李江伟; 别国军; 高嫒嫒; 杜渭松; 安忠维; 高潮; 李建; 胡明刚

doi:10.3788/YJYXS20163103.0249

您当前的位置：

首页 >

文章列表页 >

聚合物稳定蓝相液晶用单体研究进展

材料与器件 | 更新时间：2020-08-12

- 聚合物稳定蓝相液晶用单体研究进展
- Advances on monomers used in polymer stabilized blue phase liquid crystal
- 液晶与显示 2016年31卷第3期页码：249-257
- 作者机构：
  
  西安近代化学研究所,陕西西安,710065
- 作者简介：
- 基金信息：
  
  2014年西安市科技企业小巨人资助项目(No.CX1416)()
- DOI：10.3788/YJYXS20163103.0249
  中图分类号： O69
- 收稿日期：2015-07-21，
  
  修回日期：2015-11-30，
  
  纸质出版日期：2016-03-05
- 稿件说明：
移动端阅览
李江伟, 别国军, 高嫒嫒等. 聚合物稳定蓝相液晶用单体研究进展[J]. 液晶与显示, 2016,31(3): 249-257

LI Jiang-wei, BIE Guo-jun, GAO Ai-ai etc. Advances on monomers used in polymer stabilized blue phase liquid crystal[J]. , 2016,31(3): 249-257
李江伟, 别国军, 高嫒嫒等. 聚合物稳定蓝相液晶用单体研究进展[J]. 液晶与显示, 2016,31(3): 249-257 DOI： 10.3788/YJYXS20163103.0249.

LI Jiang-wei, BIE Guo-jun, GAO Ai-ai etc. Advances on monomers used in polymer stabilized blue phase liquid crystal[J]. , 2016,31(3): 249-257 DOI： 10.3788/YJYXS20163103.0249.

摘要

聚合物稳定蓝相液晶(PS-BPLC)由于其具有相对宽的温域

亚毫秒的灰度响应速率

并且无需取向层等特点在平面显示和光学方面引起越来越多的关注。本文简要回顾了目前应用在聚合稳定蓝相液晶方面的聚合物单体的发展情况

主要从单体结构

单体的浓度

交联剂的使用这3个方面研究了这些因素对聚合物稳定蓝相的性能影响。其中对单体结构的影响进行了更为详细的讨论

包括特殊基团如氟原子、手性中心的引入

端烯的甲基化等因素对聚合物稳定蓝相液晶在驱动电压、迟滞效应和响应时间等性能的影响。并在此基础上

对聚合物稳定蓝相液晶所用单体的结构设计提出新的构想。

Abstract

Polymer stabilized blue phase liquid crystals (PS-BPLC) have attracted a considerable amount of attention because of their application to information display and photonic technology. PS-BPLC exhibit several attractive features

such as reasonably wide temperature range

sub-millisecond gray-to-gray response time

no need for alignment layer

and optically isotropic voltage-off state. After reviewing recent progress in monomers stabilizing blue phases

we describe their electro-optical performance. Molecular structure of monomers

the concentration of monomers

use of cross-linker and their influence on PS-BPLC were the main topics of this review. A more detailed discussion was emphasized on the influence of varied structure in the monomers including the introduction of fluorine atoms

chiral center and methylation of end-alkene. Furthermore

some advanced concepts in material design for PS-BPLC were presented.

关键词

Keywords

references

REINITZER F. Contributions to the knowledge of cholesterol[J]. Liquid Crystals, 1989, 1(5):7-18.

LU S Y, CHIEN L C. Electrically switched color with polymer-stabilized blue-phase liquid crystals[J]. Optics Letters, 2010, 35(4):562-564.

KIKUCHIH, YOKOTA M, HISAKADO Y, et al. Polymer-stabilized liquid crystal blue phases[J]. Nature Materials, 2002, 1(1):64-68.

GERBERP R. Electro-optical effects of a small-pitch blue-phase system[J]. Molecular Crystals and Liquid Crystals, 1985, 116(3/4):197-206.

HEPPKE G, KITZEROW H S, KRUMREY M. Electric field induced variation of the refractive index in cholesteric blue phases[J]. Molecular Crystals and Liquid Crystals Letters, 1985, 2(1/2):59-65.

PORSCH F, STEGEMEYER H, HILTROP K. Electric field-induced birefringence in liquid-crystalline blue phases[J]. Zeitschrift fr Naturforschung A, 1984, 39(5):475-480.

KITZEROWH S, SCHMID H, RANFT A, et al. Observation of blue phases in chiral networks[J]. Liquid Crystals, 1993, 14(3):911-916.

CASTLES F, DAY F V, MORRIS S M, et al. Blue-phase templated fabrication of three-dimensional nanostructures for photonic applications[J]. Nature Materials, 2012, 11(7):599-603.

李宁,郑成武,张兴,等.稳定蓝相液晶的研究进展[J].功能材料,2012,43(S1):33-38,42. LI N, ZHENG C W, ZHANG X, et al. Review on development of stabilized blue-phase liquid crystals[J]. Journal of Functional Materials, 2012, 43(S1):33-38, 42. (in Chinese)

YAN J, CHENG H C, GAUZA S, et al. Extended Kerr effect of polymer-stabilized blue-phase liquid crystals[J]. Applied Physics Letters, 2010, 96(7):071105.

CHEN Y, WU S T. Electric field-induced monodomain blue phase liquid crystals[J]. Applied Physics Letters, 2013, 102(17):171110.

CHEN Y, YAN J, SCHADT M, et al. Diluter effects on polymer-stabilized blue phase liquid crystals[J]. Journal of Display Technology, 2013, 9(7):592-597.

CHOI H, HIGUCHI H, OGAWA Y, et al. Polymer-stabilized supercooled blue phase[J]. Applied Physics Letters, 2012, 101(13):131904.

YAN J, WU S T, CHENG K L, et al. A full-color reflective display using polymer-stabilized blue phase liquid crystal[J]. Applied Physics Letters, 2013, 102(8):081102.

YAN J, LUO Z Y, WU S T, et al. Low voltage and high contrast blue phase liquid crystal with red-shifted Bragg reflection[J]. Applied Physics Letters, 2013, 102(1):011113.

YAN J, CHEN Y, WU S T, et al. Figure of merit of polymer-stabilized blue phase liquid crystals[J]. Journal of Display Technology, 2013, 1(9):24-29.

CHEN H S, NI S Y, LIN Y H, et al. An experimental investigation of electrically induced-birefringence of Kerr effect in polymer-stabilized blue phase liquid crystals resulting from orientations of liquid crystals[J]. Applied Physics Letters, 2012, 101(9):093501.

CHEN Y, YAN J, SUN J, et al. A microsecond-response polymer-stabilized blue phase liquid crystal[J]. Applied Physics Letters, 2011, 99(20):201105.

SUN J, XIANYU H Q, CHEN Y, et al. Submillisecond-response polymer network liquid crystal phase modulators at 1.06-m wavelength[J]. Applied Physics Letters, 2011, 99(2):021106.

KIKUCHI H. Liquid crystalline blue phases[M]//KATO T. Liquid Crystalline Functional Assemblies and Their Supramolecular Structures. Berlin Heidelberg:Springer, 2008, 128:99-117.

CHEN Y, WU S T. Recent advances on polymer-stabilized blue phase liquid crystal materials and devices[J]. Applied Polymer, 2014, 131(13), doi:10.1002/app.40556.

YAN J, RAO L H, JIAO M Z, et al. Polymer-stabilized optically isotropic liquid crystals for next-generation display and photonics applications[J]. Journal of Materials Chemistry, 2011, 21(22):7870-7877.

OO T N, MIZUNUMA T, NAGANO Y, et al. Effects of monomer/liquid crystal compositions on electro-optical properties of polymer-stabilized blue phase liquid crystal[J]. Optical Material Express, 2011, 1(8):1502-1510.

NORDENDORF G, HOISCHEN A, SCHMIDTKE J, et al. Polymer-stabilized blue phases:promising mesophases for a new generation of liquid crystal displays[J]. Polymers for Advanced Technologies, 2014, 25(11):1195-1207.

NORDENDORF G, LORENZ A, HOISCHEN A, et al. Hysteresis and memory factor of the Kerr effect in blue phases[J]. Journal of Applied Physics, 2013, 114(17):173104.

IWATA T, SUZUKI K, AMAYA N, et al. Control of cross-linking polymerization kinetics and polymer aggregated structure in polymer-stabilized liquid crystalline blue phases[J]. Macromolecules, 2009, 42(6):2002-2008.

IWATA T, SUZUKI K, HIGUCHI H, et al. A method for enlarging the Kerr constant of polymer-stabilised blue phases[J]. Liquid Crystals, 2009, 36(9):947-951.

HUSSAIN Z, DANNER D, MASUTANI A, et al. Investigation of reactive acrylic monomers for their effect on the temperature range and operating voltage of polymer-stabilised optically isotropic liquid crystal blue phases[J]. Liquid Crystals, 2012, 39(11):1345-1357.

PARK N H, PARK H R, NAYEK P, et al. P.73:withdrawn:P.74:polymer stabilized double twist cylinders of blue phase liquid crystal for reduced hysteresis and operating voltage[J]. SID Symposium Digest of Technical Papers, 2013, 44(1):1270-1272.

SUN J, XIANYU H Q, CHEN Y, et al. Submillisecond-response polymer network liquid crystal phase modulators at 1.06-m wavelength[J]. Applied Physics Letters, 2011, 99(2):021106.

SUN J, WU S T. Recent advances in polymer network liquid crystal spatial light modulators[J]. Journal of Polymer Science Part B:Polymer Physics, 2014, 52(3), doi:10.1002/polb.23391.

CHEN Y, YAN J, SUN J, et al. A microsecond-response polymer-stabilized blue phase liquid crystal[J]. Applied Physics Letters, 2011, 99(20):201105.

YAN J, WU S T. Effect of polymer concentration and composition on blue phase liquid crystals[J]. Journal of Display Technology, 2011, 7(9):490-493.

HSIEHP J, CHEN H M P. Hysteresis-free polymer-stabilised blue phase liquid crystals comprising low surface tension monomers[J]. Liquid Crystals, 2015, 42(2):216-261.

CHOI S W, YAMAMOTO S I, HASEBA Y, et al. Optically isotropic-nanostructured liquid crystal composite with high Kerr constant[J]. Applied Physics Letters, 2008, 92(4):043119.

ZHU J L, NI S B, CHEN C P, et al. The Influence of polymer system on polymer-stabilised blue phase liquid crystals[J]. Liquid Crystals, 2014, 41(6):891-896.

ZHU J L, NI S B, SONG Y, et al. Improved Kerr constant and response time of polymer-stabilized blue phase liquid crystal with a reactive diluent[J]. Applied Physics Letters, 2013, 102(7):071104.

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

蓝相液晶网络聚合物及其应用进展

光定域化蓝相软晶格结构的光学应用

聚合物薄膜晶体管制备条件对其性能影响分析