新型高HTP值液晶用手性添加剂的合成及性质测定

王健; 贠国良; 张兴; 华瑞茂

doi:10.3788/YJYXS20142902.0189

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新型高HTP值液晶用手性添加剂的合成及性质测定

材料物理和化学 | 更新时间：2020-08-12

- 新型高HTP值液晶用手性添加剂的合成及性质测定
- Synthesis and application of high HTP values chiral additives in LCD
- 液晶与显示 2014年29卷第2期页码：189-194
- 作者机构：
  
  1. 石家庄诚志永华显示材料有限公司,河北石家庄,050091
  2. 河北省平板显示材料工程技术研究中心,河北石家庄,050091
  3. 清华大学化学系北京,100084
- 作者简介：
- 基金信息：
  
  2013年河北省科技计划项目（No.13211202D）()
- DOI：10.3788/YJYXS20142902.0189
  中图分类号： TP394.1;TH691.9
- 收稿日期：2013-08-05，
  
  修回日期：2014-01-08，
  
  纸质出版日期：2014-03-05
- 稿件说明：
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王健, 贠国良, 张兴, 华瑞茂. 新型高HTP值液晶用手性添加剂的合成及性质测定[J]. 液晶与显示, 2014,29(2): 189-194

WANG Jian, YUN Guo-liang, ZHANG Xing, HUA Rui-mao. Synthesis and application of high HTP values chiral additives in LCD[J]. , 2014,29(2): 189-194
王健, 贠国良, 张兴, 华瑞茂. 新型高HTP值液晶用手性添加剂的合成及性质测定[J]. 液晶与显示, 2014,29(2): 189-194 DOI： 10.3788/YJYXS20142902.0189.

WANG Jian, YUN Guo-liang, ZHANG Xing, HUA Rui-mao. Synthesis and application of high HTP values chiral additives in LCD[J]. , 2014,29(2): 189-194 DOI： 10.3788/YJYXS20142902.0189.

摘要

以环戊基环己酮和手性联萘二酚为基础原料经过还原、取代等一系列反应制备了一种新型高HTP值液晶用手性添加剂。其具有较大的HTP值以及良好的光稳定性和化学稳定性。此外，还具备TFT液晶显示用手性添加剂的一些其他要求，如较高的电压保持率，与主体液晶材料良好的相溶性，不易被吸附剂（硅胶或氧化铝）所吸附，螺距

有小的温度相依性等。特别是其HTP值达到了101

-1

，与其他手性剂相比，用量会更少，可以大大降低其对混晶品质的影响，并且其合成方法简单，中间体及终产物易于纯化，使其在高端TFT混晶中的应用成为可能。

Abstract

High HTP values chiral additives in LCD was synthesized based on 4-cyclopentylcyclohexa-none and chiral of 1

1'-Binaphthyl-2

2'-diol by reduction reaction

substitution reaction

and a series of reactions. It has large HTP values

good light stability and chemical stability. In addition

it also has other requirements of TFT-LCD chiral additive

such as higher voltage holding ratio

good compatibility with the main liquid crystal material

uneasiness to be absorbed by adsorbent (silica gel or alumina)

limited temperature dependence of the pitch

etc. Especially its HTP value reaches 101

-1

.When compared with other chiral agents

less dosage will be needed in making LCD devices

which can greatly reduce the negative influences of the additives on the quality of mixed crystal. The synthesis method is simple

the purifications of the intermediates and the final product are easy. These advantages make it possible for the high HTP chiral additives to be applied in the high-end TFT mixed crystals.

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references

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