蓝光材料3,3'-二甲基-9,9'-联蒽的合成及光电性能研究

姜菡雨; 徐茂梁; 胡琳琳; 张创军; 王歌扬

doi:10.3788/YJYXS20132801.0045

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蓝光材料3,3'-二甲基-9,9'-联蒽的合成及光电性能研究

材料物理和化学 | 更新时间：2020-08-12

- 蓝光材料3,3'-二甲基-9,9'-联蒽的合成及光电性能研究
- Synthesis and Optical Properties of Blue Emitting Material 3,3'-Dimethyl-9,9'-Bianthracene
- 液晶与显示 2013年28卷第1期页码：45-49
- 作者机构：
  
  西安近代化学研究所,陕西西安,710065
- 作者简介：
- 基金信息：
  
  西安市经开区科技创新项目(No. JKZD110532)()
- DOI：10.3788/YJYXS20132801.0045
  中图分类号： TN383+.1
- 收稿日期：2012-09-07，
  
  修回日期：2012-10-20，
  
  纸质出版日期：2013-02-15
- 稿件说明：
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姜菡雨, 徐茂梁, 胡琳琳, 张创军, 王歌扬. 蓝光材料3,3'-二甲基-9,9'-联蒽的合成及光电性能研究[J]. 液晶与显示, 2013,(1): 45-49

JIANG Han-yu, XU Mao-liang, HU Lin-lin, ZHANG Chuang-jun, WANG Ge-yang. Synthesis and Optical Properties of Blue Emitting Material 3,3'-Dimethyl-9,9'-Bianthracene[J]. , 2013,(1): 45-49
姜菡雨, 徐茂梁, 胡琳琳, 张创军, 王歌扬. 蓝光材料3,3'-二甲基-9,9'-联蒽的合成及光电性能研究[J]. 液晶与显示, 2013,(1): 45-49 DOI： 10.3788/YJYXS20132801.0045.

JIANG Han-yu, XU Mao-liang, HU Lin-lin, ZHANG Chuang-jun, WANG Ge-yang. Synthesis and Optical Properties of Blue Emitting Material 3,3'-Dimethyl-9,9'-Bianthracene[J]. , 2013,(1): 45-49 DOI： 10.3788/YJYXS20132801.0045.

摘要

以2-甲基蒽醌为原料

经两步反应合成了3

3'-二甲基-9

9'-联蒽

并通过核磁共振、元素分析等对其结构进行了确证和表征。该方法工艺简单

反应步骤少

收率高

绿色环保。同时探讨了不同还原剂及配料比对反应收率的影响

并利用紫外-可见光吸收光谱和发射光谱对其光学性能进行研究。研究表明

该化合物在近紫外光激发下发出明亮的蓝光

发射中心波长位于447 nm处

荧光量子效率为是9

9'-联蒽的1.18倍

是一种良好的蓝光材料。

Abstract

3'-dimethyl-9

9'-bianthracene was synthesized from 2-methyl-anthraquinone through two steps reactions

and its structure was determined by means of

H NMR spectra and elemental analysis. The synthetic pathway has more advantages such as few reaction steps

high yield

easy purification and so on. Moreover

the effects on the reaction yield by different reductants and mole ratios were also discussed and its optical properties were characterized by the absorption and photoluminescence (PL) spectra. The results indicated that the maximum emission peak of the compound is at 447 nm

which is the typical blue fluorescence and its fluorescence quantum yield is 1.18 times than that of 9

9'-bianthracene.

关键词

Keywords

references

Tang C W, Vanslyke S A. Organic electroluminescent devices [J]. Appl. Phys. Lett., 1987, 51 (12): 913-915.

马颖,韩薇,张方辉,等. 发光层混合掺杂的白色OLED器件 [J]. 液晶与显示, 2011,26 (1): 40- 43.

王振,陈双文,周翔.高效率有机蓝光和白光电致发光器件 [J]. 发光学报, 2011, 32(7):715-719.

Adachi C, Kwong R C, Djurovich P, et al. Endothermic energy transfer: A mechanism for generating very efficient high-energy phosphorescent emission in organic materials [J]. Appl. Phys. Lett., 2001, 79(13): 2082-2084.

Karatsu T, Hazuku R, Asuke M, et al. Blue electroluminescence of silyl substituted anthracene derivatives [J]. Org. Electron., 2007, (8):357-366.

Raghunath P, Reddy M A, Gouri C, et al. Electronic properties of anthracene derivatives for blue light emitting electroluminescent layers in organic light emitting diodes: A density functional theory study [J]. J. Phys. Chem. A., 2006, 110 (3): 1152-1162.

Cho I, Kim S H, Kim J H, et al. Highly efficient and stable deep-blue emitting anthracene-derived molecular glass for versatile types of non-doped OLED applications [J]. J. Mater. Chem., 2012, 22: 123-129.

Ando S, Nishida J, Fujiwara E, et al. Novel p- and n-type organic semiconductors with an anthracene unit [J]. Chem. Mater., 2005, 17(6):1261-1264.

Park H, Lee J, Kang H, et al. Highly rigid and twisted anthracene derivatives: a strategy for deep blue OLED materials with theoretical limit efficiency [J]. J. Mater. Chem., 2012, 22: 2695-2700.

Adachi C, Tsutsui T, Saito S. Blue light emitting organic electroluminescent devices [J]. Appl. Phys. Lett., 1990, 56 (9): 799-801.

Shi J, Tang C W. Anthracene derivatives for stable blue-emitting organic electroluminescence devices [J]. Appl. Phys. Lett., 2002, 80 (17): 3201-3203.

Sun J, Zhong H L, Xu E, et al. An X-shaped solution-processible oligomer having an anthracene unit as acore: A new organic light-emitting material with high thermostability and efficiency [J]. Org. Electron., 2010, 11: 74-80.

Li Jian-feng, Chang Wen-li, Tao Chun-lan, et al. Synthesis, characterization of 9,9'-bianthracene and fabrication of 9,9'-bianthracene field-effect transistors [J]. Chin. Phys. Lett., 2008, 25(12):4476-4479.

Jou J H, Wu M H, Wang C P, et al. Efficient fluorescent white organic light-emitting diodes using co-host/emitter dual-role possessed di(triphenyl-amine)-1,4-divinyl-naphthalene [J]. Org. Electron., 2007, 8: 735-742.

Shen W J, Dodda R, Wu C C, et al. Spirobifluorene-linked bisanthracene: an efficient blue emitter with pronounced thermal stability [J]. Chem. Mater., 2004, 16(5):930-934.

Bell F, Waring D H. Symmetrical dianthryls. Part III [J].J. Chem. Soc., 1949: 2689-2693.

董明东,马玲娥. 9,9'-联二蒽合成研究进展 [J]. 丹东师专学报, 1995,(3):23-26.

李建丰,常文利,欧谷平,等. 9,9'-联蒽的合成及其白色有机电致发光器件的研制 [J]. 功能材料, 2009, 6 (40): 936-939.

Kim Y H, Jeong H C, Kim S H, et al. High purity blue and high efficiency electroluminescent devices based on anthracene [J]. Adv. Funct. Mater., 2005, 15 (11): 1799-1805.

安永,徐茂梁,王子俊,等. 新型蓝光材料9,9'-联蒽衍生物的合成及其光电性能研究 [J]. 发光学报, 2011,32 (9): 890-895.

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