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陕西科技大学 电气与信息工程学院,陕西 西安,710021
收稿日期:2011-02-21,
修回日期:2011-04-08,
网络出版日期:2011-08-20,
纸质出版日期:2011-08-20
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丁磊, 张方辉, 马颖. 一种新型双空穴注入层微腔OLED[J]. 液晶与显示, 2011,26(4): 496-500
DING Lei, ZHANG Fang-hui, MA Ying. Novel Microcavity OLEDs with Double Hole Injection Layer[J]. , 2011,26(4): 496-500
丁磊, 张方辉, 马颖. 一种新型双空穴注入层微腔OLED[J]. 液晶与显示, 2011,26(4): 496-500 DOI: 10.3788/YJYXS20112604.0496.
DING Lei, ZHANG Fang-hui, MA Ying. Novel Microcavity OLEDs with Double Hole Injection Layer[J]. , 2011,26(4): 496-500 DOI: 10.3788/YJYXS20112604.0496.
一种新型有机电致发光二极管的阳极结构
在玻璃衬底上以半透明的Al膜为出光面
通过在空穴注入层(HAT-CN)和空穴传输层(NPB)中间插入三氧化钼(MoO
3
)层
制备了底发射微腔OLEDs。所制备的器件结构为Glass/Al(15 nm)/HAT-CN(10 nm)/ MoO
3
(
x
nm)/NPB(30 nm)/Alq
3
(70 nm)/LiF(1 nm)/Al(150 nm)。通过电流密度-电压-亮度性能说明该结构有利于降低驱动电压和增强器件亮度。器件的最高亮度可以达到14 390 cd/m
2
起亮电压为3.4 V左右。设计的空穴型器件证明了该器件结构具有很好的空穴注入和传输特性。研究了光谱窄化和峰值偏移的微腔效应。
A novel anode structure of organic light-emitting diodes was fabricated by inserting a molybdenum trioxide (MoO
3
) layer into the interface of hole injection layer(HIL) 1
4
5
8
9
11-hexaazatriphenylene-hexacarbonitrile (HAT-CN) and hole transport layer 4
4'-bis biphenyl (NPB). The microcavity OLED with a 150 nm-thick Al top cathode and a transparent Al bottom anode on a glass substrate was fabricated. It has the configuration of Glass/Al(15 nm)/HAT-CN(10 nm)/MoO
3
(
x
nm)/NPB(30 nm)/Alq
3
(70 nm)/LiF (1 nm)/Al(150 nm).The current density-voltage-luminance(
J-V-L)
performances shows that this structure is beneficial to the reduction of the driving voltage and the enhancement of the luminance. The highest luminance of the device is reached to 14 390 cd/m
2
at 13 V
with a turn-on voltage of 3.4 V. "Hole only"devices were fabricated to verify the enhancement of hole injection and transport properties of this structure. The optical characteristics of the microcavity
such as narrowed and peak shift
were examined.
Zou Y, Deng Z B. Reduction of driving voltage in organic light-emitting diodes with molybdenum trioxide in CuPc/NPB interface [J]. J. Lumin., 2010, 130(6):959-962.[2] Meyer J, Winkler T, Hamwi S, et al. Transparent inverted organic light-emitting diodes with a tungsten oxide buffer layer [J]. Advanced Materials, 2008, 20(20):3839-3843.[3] Wang Z B, Helander M G, Qiu J, et al. Direct hole injection in to 4, 4-N, N-dicarbazole-biphenyl: A simple pathway to achieve efficient organic light emitting diodes [J]. J. Appl. Phys.,2010, 108(2):024510(1-4).[4] Park S M, Kim Y H, Hak Y, et al. Insertion of an organic interlayer for hole current enhancement in inverted organic light emitting devices [J]. Appl. Phys. Lett., 2010, 97(6):063308(1-3).[5] 熊志勇,李宏建,王俊西,等.可弯曲式微腔有机电致发光器件的光学特性 [J]. 发光学报, 2009,30(3):337-343.[6] 张春玉,陆景彬,秦莉,等.微腔有机电致发光白光器件设计及制作 [J]. 发光学报, 2009,30(5):596-600.[7] 王洪杰,张春玉.激子位置不同微腔有机电致发光器件性能模拟 [J]. 发光学报, 2010,31(2):167-170.[8] Matsuo J, Katsumata H, Minami E, et al. O2 cluster ion-assisted deposition for tin-doped indium oxide films [J]. Methods Phys. Res. B, 2000, 161-163:952-957.[9] 刘丁涵,张方辉,牟强,等. DCJTB掺杂浓度对OLED器件性能的影响[J]. 液晶与显示, 2010,25(5):672-677.[10] 蒋谦,张方辉. 2,5,8,11-tetra-terbutylperylene作为辅助掺杂剂的红色有机电致发光二极管[J]. 液晶与显示, 2010, 25(5):666-671.[11] Han S, Huang C J, Lu Z H. Color tunable metal-cavity organic light-emitting diodes with fullerene layer[J]. J. Appl. Phys., 2005,97(9):093102(1-3).[12] Yokoya H. Physics and device application of optical microcavities [J]. Science, 1992, 256(5053):66-70.[13] Jordan R H, Rothberg L J, Dodabalapur A, et al. Efficiency enhancement of microcavity organic light emitting diodes [J]. Appl. Phys. Lett., 1997, 69(14):116858(1-3).
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