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暨南大学 理工学院,广东 广州,510632
收稿日期:2010-11-09,
修回日期:2010-11-29,
网络出版日期:2011-04-06,
纸质出版日期:2011-04-06
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侯林涛, 王平, 王标, 梁振锴, 刘彭义, 吴冰, 张秀菊. 高效叠层有机电致发光器件[J]. 液晶与显示, 2011,26(2): 142-146
HOU Lin-tao, WANG Ping, WANG Biao, LIANG Zhen-kai, LIU Peng-yi, WU Bing, ZHANG Xiu-ju. High Efficiency Tandem Organic Light-Emitting Diodes with Effective Charge Generation Layer[J]. , 2011,26(2): 142-146
侯林涛, 王平, 王标, 梁振锴, 刘彭义, 吴冰, 张秀菊. 高效叠层有机电致发光器件[J]. 液晶与显示, 2011,26(2): 142-146 DOI: 10.3788/YJYXS20112602.0142.
HOU Lin-tao, WANG Ping, WANG Biao, LIANG Zhen-kai, LIU Peng-yi, WU Bing, ZHANG Xiu-ju. High Efficiency Tandem Organic Light-Emitting Diodes with Effective Charge Generation Layer[J]. , 2011,26(2): 142-146 DOI: 10.3788/YJYXS20112602.0142.
采用Cs
2
CO
3
∶ Alq
3
/MoO
3
作电荷产生层
制备出高效双单元串联型叠层有机发光器件。双单元叠层有机发光器件发光性能受电荷产生层MoO
3
的厚度影响很大。当MoO
3
厚度为30 nm时
叠层器件表现出最好的器件性能
最大电流效率达到14.5 cd/A。在相当宽的低电流密度范围内
30 nm MoO
3
叠层器件的电流效率是对比单层器件电流效率的2倍以上|但高电流密度下
叠层器件电流效率下降较快。叠层发光器件性能的提高与中间电荷产生层向上下两个发光单元有效的电子、空穴注入有关。
By employing cesium carbonate doped tris-(8-hydroxyquinoline) aluminum/MoO
3
as the effective charge generation layer (CGL)
high efficiency two-unit series connected tandem organic light-emitting diodes were fabricated. It is found the performance of the two-unit tandem devices can be controlled by the thickness of the MoO
3
layer. The 30 nm-thick MoO
3
CGL tandem device exhibits the best device performance with the current efficiency of 14.5 cd/A
which is above 2.0 times than that of the control device over a wide range of current densities. Its suggested that the connecting layer broke down under a high current density
leading to the decrease of current efficiency. The improvement of tandem device performance is attributed to the efficient electron and hole injection from charge generation layer to two adjacent emission units.
Tang C W, Vanslyke S A. Organic electroluminescent diodes [J]. Appl. Phys. Lett., 1987, 51(12): 913-195.[2] Reineke S, Lindner F, Schwartz G, et al. White organic light-emitting diodes with fluorescent tube efficiency [J]. Nature, 2009, 459:234-239.[3] Ho M H, Chen T M, Yeh P C, et al. Highly efficient p-i-n white organic light emitting devices with tandem structure [J]. Appl. Phys. Lett., 2007, 91(23):233507(1-3).[4] Hamwi S, Meyer J, Krger M, et al. The role of transition metal oxides in charge-generation layers for stacked organic light-emitting diodes [J]. Adv. tanct. Mater., 2010,20(11):1762-1766.[5] Yook K S, Jeon S O, Min S Y, et al. Highly efficient p-i-n and tandem organic light-emitting devices using an air-stable and low temperature-evaporable metal azide as an n-dopant [J]. Adv. Funct. Mater., 2010, 20(11):1797-1802. [6] Wang Q, Ding J Q, Zhang Z Q, et al. A high-performance tandem white organic light-emitting diode combining highly effective white-units and their interconnection layer [J]. J. Appl. Phys., 2009, 105(7):076101(1-3).[7] Cho T Y, Lin C L, Wu C C, Microcavity two-unit tandem organic light-emitting devices having a high efficiency [J]. Appl. Phys. Lett., 2006, 88(11):111106(1-3). [8] Tsutsui T, Terai M. Electric field-assisted bipolar charge spouting in organic thin-film diodes [J]. Appl. Phys. Lett., 2004, 84(3):440-442.[9] Hou L T, Wang P, Liu P Y, et al. Novel electron injection layer by co-evaporating tris (8-hydroxyquinoline) aluminum doped cesium carbonate in organic light emitting diodes[J]. Chin. J. Lumin., 2010, 31(5):655-660.[10] Chang C C, Hwang S W, Chen C H, et al. High-efficiency organic electroluminescent device with multiple emitting units [J]. Jpn. J. Appl. Phys., 2004, 43:6418-6422.[11] Krger M, Hamwi S, Meyer J, et al. P-type doping of organic wide band gap materials by transition metal oxides:A case-study on molybdenum trioxide[J]. Org. Electron, 2009, 10(5):932-938.[12] [JP2]Wang F X, Xiong T, Qiao X F, et al. Origin of improvement in device performance via the modification role of cesium[JP] hydroxide doped tris(8-hydroxyquinoline) aluminum interfacial layer on ITO cathode in inverted bottom-emission organic light-emitting diodes [J]. Org. Electron, 2009, 10(2):266-274.[13] 侯林涛,刘彭义,张靖磊, 等. MoO3作空穴注入层的有机电致发光器件 [J].[HTK]发光学报, [HTSS]2010, 31(3):326-330.
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