基于液晶有序结构的高性能纳滤膜的制备

张亦周; 冯训达

doi:10.37188/YJYXS20203507.0776

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基于液晶有序结构的高性能纳滤膜的制备

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- 基于液晶有序结构的高性能纳滤膜的制备
- High-performance nanofiltration membranes derived from liquid crystals
- 液晶与显示 2020年35卷第7期页码：776-783
- 作者机构：
  
  1.宾夕法尼亚大学化学工程与生物工程系, 宾夕法尼亚州费城 19104
  2.东华大学先进低维材料中心, 上海 201620
- 作者简介：
  
  [ "张亦周(1991-), 男, 江苏南通人, 博士后, 2018年于美国圣母大学获得博士学位, 主要从事基于自组装液晶材料为媒介的分离和纯化等应用的研究。E-mail:yizhouz@seas.upenn.edu" ]
  [ "冯训达(1983-), 男, 广西北海人, 博士, 研究员, 2013年于德国哥廷根大学获得博士学位, 主要从事液晶等软物质材料的结构、动态、应用的研究。E-mail:xunda.feng@dhu.edu.cn" ]
- 基金信息：
  
  东华大学高层次人才引进计划(285-07-005710)
- DOI：10.37188/YJYXS20203507.0776
  中图分类号： O753.2
- 收稿日期：2020-04-10，
  
  修回日期：2020-05-11，
  
  录用日期：2020-5-11，
  
  纸质出版日期：2020-07-05
- 稿件说明：
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张亦周, 冯训达. 基于液晶有序结构的高性能纳滤膜的制备[J]. 液晶与显示, 2020,35(7):776-783.

Yi-zhou ZHANG, Xun-da FENG. High-performance nanofiltration membranes derived from liquid crystals[J]. Chinese journal of liquid crystals and displays, 2020, 35(7): 776-783.
张亦周, 冯训达. 基于液晶有序结构的高性能纳滤膜的制备[J]. 液晶与显示, 2020,35(7):776-783. DOI： 10.37188/YJYXS20203507.0776.

Yi-zhou ZHANG, Xun-da FENG. High-performance nanofiltration membranes derived from liquid crystals[J]. Chinese journal of liquid crystals and displays, 2020, 35(7): 776-783. DOI： 10.37188/YJYXS20203507.0776.

摘要

纳滤膜是一种高效的膜分离技术，在整个膜工业领域占据重要地位。研发拥有高度有序水通道结构的纳滤膜，可以针对特定的分离应用，利用既定的纳米结构性质实现需要的分离效果。然而，传统的纳滤膜的性能受限于膜材料、制膜方法，无法精确构建水通道。利用液晶自组装的有序结构来制备高效的聚合物纳滤膜是一种行之有效的策略。各种不同的液晶相态可以用作精确调节纳米结构的模板，并通过灵活地改变其结构及形态，为下一代纳滤膜的研发提供了一种高度可控的制作平台。目前，基于液晶自组装的分离膜的分离尺度在1~2 nm的范围内。我们从两个方面评述了实现制备基于液晶材料的高性能纳滤膜的基本条件。从不同液晶相态的设计原理开始，首先讨论了不同纳米结构在实际传递作用中的固有性质。随后，对近期以薄膜复合膜的形式制作的液晶纳滤膜的报道进行了总结，分析了这些薄膜的性能局限性，为适应更广泛的分离引用，对目前液晶材料的设计理念提出了合理的改进措施。

Abstract

Nanofiltration membranes are a class of promising platform that is critical for selective small molecule separations. The development of nanofiltration membranes with an array of well-defined water channels motivates an opportunity to tailor the solute transport based on the precisely programmed nanostructured-properties. To date

however

the study of state-of-art nanofiltration materials has been slow to advance in constructing controlled water-channel architectures. Supramolecular assemblies derived from liquid crystalline mesophases offer a highly tunable system to fabricate nanostructured templates with the desired morphology following an inherent periodicity. These structurally ordered templates

in turn

can be tailored independently to target applications demanding higher permeability or specific solute selectivity. In this review

we highlight the development of liquid crystal-based materials from two fundamental aspects that will allow the realization of the next-generation nanofiltration membranes. Starting from the materials design principle that governs the creation of myriad nanostructures

we discuss the structural factors that define the intrinsic transport performance of different liquid crystal mesophases. Then we summarize the recent advances in the fabrication of liquid crystal nanofiltration membranes as thin-film composites

analyze their current limitation

and emphasize the potential approaches to revolutionize the current membrane design strategy. We envision these paradigm-altering approaches can support the development of liquid crystalline materials towards a more extensive range of membrane applications.

关键词

Keywords

references

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