液晶高分子聚对苯二甲酰对苯二胺自组装及应用研究进展

谢春杰; 杨诗煊; 何然; 刘健柠; 郭朝霞; 庹新林

doi:10.37188/CJLCD.2021-0316

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液晶高分子聚对苯二甲酰对苯二胺自组装及应用研究进展

结构与功能应用 | 更新时间：2022-02-28

- 液晶高分子聚对苯二甲酰对苯二胺自组装及应用研究进展
- Research on the self-assembly and application of liquid crystal polymer poly (p-phenylene terephtalamide)
- 液晶与显示 2022年37卷第2期页码：129-137
- 作者机构：
  
  清华大学化学工程系高分子研究所, 北京 100084
- 作者简介：
  
  [ "谢春杰(1991-), 男, 山东济南人, 博士后, 2021年于清华大学获得博士学位, 主要从事对位芳纶纳米纤维的制备及自组装研究。E-mail: xiechunjie2010@163.com" ]
  [ "庹新林(1973-), 男, 湖北十堰人, 博士, 副研究员, 2002年于清华大学获得博士学位, 主要从事高性能高分子材料的设计、合成、工业化生产技术及应用研究。E-mail: tuoxl@tsinghua.edu.cn" ]
- 基金信息：
  
  国家自然科学基金(52073154);山东省重点研发计划（重大科技创新工程）项目(2019TSLH0109);清华大学（化工系）-黄河三角洲京博化工研究院有限公司高性能高分子材料联合研究中心基金;中国博士后科学基金(2021M701831);清华大学“水木学者”计划
- DOI：10.37188/CJLCD.2021-0316
  中图分类号： O753.2;TQ427.26
- 收稿日期：2021-11-30，
  
  修回日期：2021-12-20，
  
  纸质出版日期：2022-02
- 稿件说明：
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谢春杰, 杨诗煊, 何然, 等. 液晶高分子聚对苯二甲酰对苯二胺自组装及应用研究进展[J]. 液晶与显示, 2022,37(2):129-137.

Chun-jie XIE, Shi-xuan YANG, Ran HE, et al. Research on the self-assembly and application of liquid crystal polymer poly (p-phenylene terephtalamide)[J]. Chinese journal of liquid crystals and displays, 2022, 37(2): 129-137.
谢春杰, 杨诗煊, 何然, 等. 液晶高分子聚对苯二甲酰对苯二胺自组装及应用研究进展[J]. 液晶与显示, 2022,37(2):129-137. DOI： 10.37188/CJLCD.2021-0316.

Chun-jie XIE, Shi-xuan YANG, Ran HE, et al. Research on the self-assembly and application of liquid crystal polymer poly (p-phenylene terephtalamide)[J]. Chinese journal of liquid crystals and displays, 2022, 37(2): 129-137. DOI： 10.37188/CJLCD.2021-0316.

摘要

聚对苯二甲酰对苯二胺（PPTA）是一种溶致液晶高分子，其取向结构构成的纤维材料力学性能优异，在众多领域有不可或缺的应用价值。但是PPTA不熔难溶的特点使其加工性差，严重限制了PPTA应用的扩展。将PPTA自组装成纳米纤维，并进一步将纳米纤维组装成宏观材料是解决PPTA加工难题的一个有效策略。本文对近年来PPTA的自组装方法进行了简要综述，重点介绍了以单体为起点，通过原位自组装结合其他自组装方法制备出不同形态、功能及应用的宏观材料多级自组装策略。这一多级自组装策略实现了对液晶高分子PPTA的加工，丰富了其产物种类，并有望应用于其他液晶高分子的自组装中。

Abstract

Poly (

-phenylene terephtalamide) (PPTA) is a kind of lyotropic liquid crystal polymer. Fiber material consisted of oriented PPTA molecules has excellent mechanical strength and is necessary in many important areas. However

the poor processability of PPTA due to its non-melting and insoluble characteristics seriously limits the expansion of PPTA application. Self-assembly of PPTA into nanofibers and further processing the nanofibers into macroscopic materials is an effective strategy to solve the problem of PPTA processing. This paper briefly reviews the self-assembly methods of PPTA in recent years

and mainly introduced the fabrication of different kinds of macroscopic materials from monomers through the combination of in-situ self-assembly and other self-assembly methods. This multi-level self-assembly strategy realizes the processing of liquid crystal polymer PPTA

enrich the product variety

and is expected to be applied to the self-assembly of other liquid crystal polymers.

关键词

Keywords

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