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北京京东方显示技术有限公司, 北京 100176, China
[ "吴祖谋(1991-), 男, 河南信阳人, 硕士, 2016年于北京航空航天大学获得硕士学位, 主要从事TFT-LCD工艺研究。E-mail:wuzumou@163.com" ]
收稿日期:2020-09-23,
修回日期:2020-12-18,
纸质出版日期:2021-04
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吴祖谋, 白金超, 丁向前, 等. 阵列基板铜工艺不良研究[J]. 液晶与显示, 2021,36(4):560-565.
Zu-mou WU, Jin-chao BAI, Xiang-qian DING, et al. Cu defects in array process[J]. Chinese journal of liquid crystals and displays, 2021, 36(4): 560-565.
吴祖谋, 白金超, 丁向前, 等. 阵列基板铜工艺不良研究[J]. 液晶与显示, 2021,36(4):560-565. DOI: 10.37188/CJLCD.2020-0253.
Zu-mou WU, Jin-chao BAI, Xiang-qian DING, et al. Cu defects in array process[J]. Chinese journal of liquid crystals and displays, 2021, 36(4): 560-565. DOI: 10.37188/CJLCD.2020-0253.
本文结合产品开发过程中遇到的铜相关不良现象进行研究,提出了有效的改善措施。结果表明,在第一次氮化硅刻蚀中的后灰化工序有高含量的氧气,会使过孔内部铜发生氧化而发黑。使用氢等离子体处理,可以将氧化铜还原成铜,在生产线光学设备测量时过孔反射出金属白色。在氧化铟锡刻蚀过程中,高温退火会造成裸露的铜发生严重氧化,需要去掉退火步骤或者更改设计来规避。在第二次氮化硅刻蚀步骤中,高含量的氧会氧化过孔处的铜,造成过孔连接异常,降低刻蚀步骤中氧气含量可以解决该不良。
The mechanism of defects on Cu process along with the development of new product is studied in this paper
and improvement methods are proposed. The results show that the high flow of O
2
used in post ashing corrodes the Cu in PVX1 (The First passivation Layer) etch
and makes the Cu hole blackened. After adding the H
2
treatment step
CuO can be reduced to Cu
and the hole appears metallic white color during CD (Critical Dimension) measurement. During 1ITO (The First Indium Tin Oxides Layer) etch process
high temperature annealing results in the occurrence of serious oxidation of exposed SD Cu. Skipping anneal or changing mask design can avoid the defect. In the VIA etch step
high content of O
2
oxidizes the Cu
resulting in the break of conduction between gate and SD through the hole which leads to the occurrence of vertical line Mura. Reducing the content of O
2
of VIA etch can solve the problem.
白 金超 , 李 小龙 , 韩 皓 , 等 . 4-Mask工艺Cu腐蚀分析及改善研究 . 液晶与显示 , 2019 . 34 ( 2 ): 125 - 129 . http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20193402.0125 http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20193402.0125 .
J C BAI , X L LI , H HAN , 等 . Research of Cu corrosion in 4-Mask process . Chinese Journal of Liquid Crystals and Displays , 2019 . 34 ( 2 ): 125 - 129 . http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20193402.0125 http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20193402.0125 .
Y J WANG , Q Y SHEN , J W WANG , 等 . Resolving bump issue on copper surface in GI hole of TFT-LCDs . SID Symposium Digest of Technical Papers , 2019 . 50 ( 1 ): 1495 - 1498 . DOI: 10.1002/sdtp.13225 http://doi.org/10.1002/sdtp.13225 .
刘 丹 , 秦 刚 , 王 任远 , 等 . 阵列基板栅极制程的Cu腐蚀研究 . 液晶与显示 , 2018 . 33 ( 9 ): 717 - 724 . http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20183309.0717 http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20183309.0717 .
D LIU , G QIN , R Y WANG , 等 . Cu corrosion of array substrate in gate process . Chinese Journal of Liquid Crystals and Displays , 2018 . 33 ( 9 ): 717 - 724 . http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20183309.0717 http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20183309.0717 .
X X ZHANG , X Q DING , Y Z SONG , 等 . Mechanism analysis of defects on the organic film process . SID Symposium Digest of Technical Papers , 2019 . 50 ( 1 ): 1474 - 1476 . DOI: 10.1002/sdtp.13219 http://doi.org/10.1002/sdtp.13219 .
安 晖 , 操 彬彬 , 栗 芳芳 , 等 . ITO退火工艺对HADS型TFT-LCD透过率的影响 . 液晶与显示 , 2019 . 34 ( 5 ): 482 - 488 . http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20193405.0482 http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20193405.0482 .
H AN , B B CAO , F F LI , 等 . Influence of ITO anneal on the transmittance property of HADS TFT-LCD . Chinese Journal of Liquid Crystals and Displays , 2019 . 34 ( 5 ): 482 - 488 . http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20193405.0482 http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20193405.0482 .
白 金超 , 王 玉堂 , 郭 总杰 , 等 . TFT-LCD过孔接触电阻研究 . 液晶与显示 , 2015 . 30 ( 3 ): 432 - 436 . http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20153003.0432 http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20153003.0432 .
J C BAI , Y T WANG , Z J GUO , 等 . Via hole contact resistance in TFT-LCD . Chinese Journal of Liquid Crystals and Displays , 2015 . 30 ( 3 ): 432 - 436 . http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20153003.0432 http://cjlcd.lightpublishing.cn/thesisDetails#10.3788/YJYXS20153003.0432 .
马 群刚 . TFT-LCD原理与设计 , : 北京 电子工业出版社 , 2011 .
Q G MA . TFT-LCD Principle and Design , : Beijing Publishing House of Electronics Industry , 2011 .
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