不同单体配比对聚合物网络及聚合物稳定胆甾相液晶器件光电性能的影响

张姗娜; 张俊; 陆红波

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不同单体配比对聚合物网络及聚合物稳定胆甾相液晶器件光电性能的影响

材料物理和化学 | 更新时间：2020-08-12

- 不同单体配比对聚合物网络及聚合物稳定胆甾相液晶器件光电性能的影响
- Influence of different monomer ratio on polymer network and photoelectric performance of polymer stabilized cholesteric liquid crystal
- 液晶与显示 2014年29卷第4期页码：504-507
- 作者机构：
  
  合肥工业大学光电技术研究院, 安徽合肥 230009
- 作者简介：
- 基金信息：
  
  国家自然科学基金（No.61107014）();国家高技术研究发展计划（863计划）（No.2012AA011901）();科技部973计划前研专项（No.2012CB
- DOI：
  中图分类号： O753+.2
- 收稿日期：2013-10-11，
  
  修回日期：2013-11-15，
  
  网络出版日期：2013-11-25，
  
  纸质出版日期：2014-08-05
- 稿件说明：
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张姗娜, 张俊, 陆红波. 不同单体配比对聚合物网络及聚合物稳定胆甾相液晶器件光电性能的影响[J]. 液晶与显示, 2014,29(4): 504-507

ZHANG Shan-na, ZHANG-Jun, LU Hong-bo. Influence of different monomer ratio on polymer network and photoelectric performance of polymer stabilized cholesteric liquid crystal[J]. , 2014,29(4): 504-507
张姗娜, 张俊, 陆红波. 不同单体配比对聚合物网络及聚合物稳定胆甾相液晶器件光电性能的影响[J]. 液晶与显示, 2014,29(4): 504-507 DOI：

ZHANG Shan-na, ZHANG-Jun, LU Hong-bo. Influence of different monomer ratio on polymer network and photoelectric performance of polymer stabilized cholesteric liquid crystal[J]. , 2014,29(4): 504-507 DOI：

摘要

为了调节聚合物网络与液晶分子之间的相互作用，从而改善聚合物稳定胆甾相液晶（PSCLC）的光电性能，本文采用紫外光聚合诱导相分离法（PIPS）制备了聚合物稳定胆甾相液晶，通过控制2种单体RM257与BAB6的比例来改善器件性能。随着RM257含量的减少，聚合物网络由取向排列的纤维状结构向疏松不规整的交联状结构转变，形成的聚合物网络对液晶分子的锚定作用减弱，聚合物稳定胆甾相液晶的饱和电压降低，关闭时间增大。当RM257与BAB6质量比为1：4时，聚合物稳定胆甾相液晶器件具有较好的对比度。

Abstract

The interaction force between polymer network and liquid crystal molecules was adjusted by controlling two monomer ratio

the photoelectric performance of the PSCLC was also improved by the method. Polymer stabilized cholesteric liquid crystal was prepared by the method of UV polymerization induced phase separation (PIPS). As the concentration of RM257 decreased

the saturated voltage reduced and the field-off response times of PSCLC increased with the polymer network changing from fiber-like to crosslink-like. When the proportion of RM257 and BAB6 is 1:4

the contrast reach maximum.

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references

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