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1. 吉林师范大学 信息技术学院,吉林 四平 136000,E-mail: gy-ding@163.com
2. 华南理工大学 化学与化工学院,广东 广州,510641
收稿日期:2008-12-19,
修回日期:1900-01-02,
网络出版日期:2009-08-30,
纸质出版日期:2009-08-30
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王广德;丁桂英;姜文龙;欧阳新华;曾和平. 基于TPAHQZn发光色度稳定的黄色OLED[J]. 液晶与显示, 2009,24(04): 497-501
WANG Guang-de;DING Gui-ying;JIANG Wen-long;OUYANG Xin-hua;ZENG He-ping. Color Stabled Yellow Organic Light-Emitting Devices Based on (E)-2-(4-(Diphenylamino) Styryl) Quinolin-Zinc as Emitter[J]. 液晶与显示, 2009,24(04): 497-501
王广德;丁桂英;姜文龙;欧阳新华;曾和平. 基于TPAHQZn发光色度稳定的黄色OLED[J]. 液晶与显示, 2009,24(04): 497-501 DOI:
WANG Guang-de;DING Gui-ying;JIANG Wen-long;OUYANG Xin-hua;ZENG He-ping. Color Stabled Yellow Organic Light-Emitting Devices Based on (E)-2-(4-(Diphenylamino) Styryl) Quinolin-Zinc as Emitter[J]. 液晶与显示, 2009,24(04): 497-501 DOI:
采用一种既具有空穴传输特性又具有发光特性的新型荧光染料(E)-2-(4-(dipheny-lamino)styryl)quinolato-zinc (TPAHQZn)作为发光层
制备了结构为 ITO/ 4
4'
4-{N
-(2-naphthyl)-N-phenylamino}-triphenylamine (2T-NATA)(15 nm)/ (E)-2-(4-(diphenylamino)styryl)quinolato-zinc (TPAHQZn)(x nm)/9
10-bis(2-naphthyl)anthracene(ADN)(31 nm)/ tris(8-quinolinolato) aluminum(Alq
3
)((65-
x
) nm)/LiF(0.6 nm)/Al的黄色有机电致发光器件。研究了不同厚度的发光层对器件性能的影响。TPAHQZn厚度为30 nm 的器件在14 V电压下实现了黄光发射
最大发光亮度为 2 479 cd/m
2
最大电流效率为0.84 cd/A
色坐标由8 V(6.346 cd/m
2
)时的(0.502
0.449 5)到14 V(2 479 cd/m
2
)时的(0.497 9
0.453)变化不大
器件的发光颜色稳定。
Using(E)-2-(4-(diphenylamino)styryl)quinolato-zinc (TPAHQZn) as a hole-transporting emitter
a yellow OLED was fabricated with the molecular structure: indium-tin oxide(ITO)/ 4
4'
4-{N
-(2-naphthyl)-N-phenylamino}-triphenylamine (2T-NATA)(15 nm)/ (E)-2-(4-(diphenylamino)styryl)quinolato-zinc (TPAHQZn)(
x
nm)/9
10-bis(2-naphthyl)anthracene(ADN)(31 nm)/ tris(8-quinolinolato) aluminum(Alq
3
)((65-
x
) nm)/LiF(0.6 nm) /Al. By adjusting thicknesses of TPAHQZn
a yellow OLED was obtained which has the maximum luminous efficiency of 0.84 cd /A (at 10 V) and maximum luminance of 2 479 cd /m
2
(at 14 V). The device emits pure yellow light efficiently and stably
the Commission Internationale De LEclairage (CIE) coordinates slightly varied from (0.502
0.449 5) (6.346 cd/m
2
at 8 V) to (0.497 9
0.453) (2 479 cd/m
2
at 14 V).
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. Ding G Y, Jiang W L, Wang J, et al. White organic light-emitting devices based on novel (E)-2-(4-(diphenylamino) styryl)quinolato zinc as a hole-transporting emitter [J]. Semicond. Sci. Technol.,2009, 24(2):025016(1-5).
. Chen P. Stadies on white organic light emitting devices based on blue fluorescence and orange phosphorescence . Changchun:Jilin University, 2008.
. Tse S C, So S K, Yeung M Y, et al. The role of charge-transfer integral in determining and engineering the carrier mobilities of 9,10-di(2-naphthyl)anthracene compounds[J]. Chem. Phys. Lett., 2006, 422(4-6):354-357.
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. Huang J S, Yang K X, Liu S Y, et al. High-brightness organic double-quantum-well electroluminescent device [J]. Appl. Phys. Lett., 2000,77(12):1750-1752.
. 丁桂英,汪津,王广德,等. 基于rubrene掺杂剂的高亮度白色有机电致发光器件[J]. 液晶与显示 , 2008, 23(1):5-10.
. 丁桂英,姜文龙,汪津,等.利用C-545T超薄层多层结构的白光器件[J]. 液晶与显示, 2008,23(2):214-218.
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