HU Jun-tao, DENG Ya-fei, MEI Wen-juan etc. Effects of transparent Ag/MoO<sub>3</sub>/Ag stack as anode on the performance of green organic light-Emitting diodes[J]. , 2016,31(1): 74-79
HU Jun-tao, DENG Ya-fei, MEI Wen-juan etc. Effects of transparent Ag/MoO<sub>3</sub>/Ag stack as anode on the performance of green organic light-Emitting diodes[J]. , 2016,31(1): 74-79 DOI: 10.3788/YJYXS20163101.0074.
Effects of transparent Ag/MoO3/Ag stack as anode on the performance of green organic light-Emitting diodes
/Ag is introduced to fabricate organic light-emitting devices (OLEDs) as a anode instead for ITO. Effects of different structures of the anode on transmittance
brightness
spectrum of OLEDs are researched in this paper. A series of devices is fabricated by the means of vacuum evaporating with the structure of Ag/MoO
3
/Ag/MoO
3
(10 nm)/NPB(40 nm)/Alq
3
(60 nm)/LiF(1 nm)/Al(150 nm). Current density-voltage characteristic
brightness-voltage characteristic
spectrogram characteristic of the devices are analyzed. It is found that brightness of the device which is applied Ag/MoO
3
/Ag 20/20/10(nm) as the anode reaches the maximum of 18421 cd/m
2
and the best current efficiency of 2.45 cd/A with the operating voltage of 11 V. Because of microcavity effect
the center wavelength of EL spectra is blue-shifted and the full width at half maximum becomes narrower. But considering its electrode transmittance is only 17% at 530 nm
the OLED device is actually brighter than the ITO electrode device by the conversion. They can be used as anodes for top-emitting and transparent flexible OLED because of the simplicity of the production.
关键词
Keywords
references
陈金鑫,黄孝文.OLED梦幻显示器-材料与器件[M].北京:人民邮电出版社,2011. CHEN J X, HUANG X W. The Fantastic Oled Display-Materials and Devices[M]. Beijing:People Post Press, 2011. (in Chinese)
ZHAO Y B, CHEN J S. Poly (3, 4-ethylenedioxythiophene):poly (styrenesulfonate)/MoO3 composite layer for efficient and stable hole injection in organic semiconductors[J]. Journal of Applied Physics, 2012, 111(4):043716.
吴晓晓,李福山,吴薇,等.基于石墨烯/PEDOT:PSS叠层薄膜的柔性OLED器件[J].发光学报,2014,35(4):486-490. WU X X, LI F S, WU W, et al. Flexible organic light emitting diodes based on double-layered graphene/PEDOT:PSS conductive film[J]. Chinese Journal of Luminescence, 2014, 35(4):486-490. (in Chinese)
JUN Y L. C60 modification of al anode for efficient hole injection in organic light-emitting diodes[J]. Molecular Crystals and Liquid Crystals, 2009, 499(1):333-339.
LEI P H, HSU C M, FAN Y S. Flexible organic light-emitting diodes on a polyestersulfone (PES) substrate using Al-doped ZnO anode grown by dual-plasma-enhanced metalorganic deposition system[J]. Organic Electronics, 2013, 14(1):236-249.
LI Y Z, WANG Z L, LUO H, et al. Highly efficient phosphorescent organic light-emitting diode with a nanometer-thick Ni silicide/polycrystalline p-Si composite anode[J]. Optics Express, 2010, 18(15):15942-15947.
ZHANG H M, CHOY W C H. Indium tin oxide modified by au and vanadium pentoxide as an efficient anode for organic light-emitting devices[J]. IEEE Transactions on Electron Devices, 2008, 55(9):2517-2520.
LEE S M, CHOI C S, CHOI K C, et al. Low resistive transparent and flexible ZnO/Ag/ZnO/Ag/WO3 electrode for organic light-emitting diodes[J]. Organic Electronics, 2012, 13(9):1654-1659.
ZHANG H M, CHOY W C H. Transparent Al/WO3/Au film as anode for high efficiency organic light-emitting diodes[J]. Organic Electronics, 2008, 9(6):964-967.
TIAN B L. Investigation of MoO3 as an electron injection contact and as a charge transport material in transparent organic light emitting devices[D]. Ontario:University of Waterloo, 2011.
LENG J, YU Z N, XUE W, et al. Influence of Ag thickness on structural, optical, and electrical properties of ZnS/Ag/ZnS multilayers prepared by ion beam assisted deposition[J]. Journal of Applied Physics, 2010, 108(7):073109.
NGUYEN D T, VEDRAINE S, CATTIN L, et al. Effect of the thickness of the MoO3 layers on optical properties of MoO3/Ag/MoO3 multilayer structures[J]. Journal of Applied Physics, 2012, 112(6):063505.
陶海华,姚宁,杜晨霞,等.有机电致发光的光学微腔效应[J].光学与光电技术,2004,2(2):61-64. TAO H H, YAO N, DU C X, et al. Microcavity effects of organic electroluminescence[J]. Optic & Optoelectronic Technology, 2004, 2(2):61-64. (in Chinese)
ASLAN K, MALYN S N, ZHANG Y X, et al. Conversion of just-continuous metallic films to large particulate substrates for metal-enhanced fluorescence[J]. Journal of Applied Physics, 2008, 103(8):084307.
LIU S H, LIU W B, YU J, et al. Silver/germanium/silver:An effective transparent electrode for flexible organic light-emitting devices[J]. Journal of Materials Chemistry C, 2014, 2(5):835-840.
席俭飞,张方辉,马颖,等.钙铝合金作为阴极对OLED器件性能的影响[J].液晶与显示,2010,25(3):355-359. XI J F, ZHANG F H, MA Y, et al. Effects of Ca:Al alloy as cathode on the performance of organic light-emitting devices[J]. Chinese Journal of Liquid Crystals and Displays, 2010, 25(3):355-359. (in Chinese)
DODABALAPUR A, ROTHBERG L J, JORDAN R H, et al. Physics and applications of organic microcavity light emitting diodes[J]. Journal of Applied Physics, 1996, 80(12):6954-6964.
LIN C L, LIN H W, WU C C. Examining microcavity organic light-emitting devices having two metal mirrors[J]. Journal of Applied Letters, 2005, 87(2):021101.
HO Y H, CHEN K Y, LIU S W, et al. Transparent and conductive metallic electrodes fabricated by using nanosphere lithography[J]. Organic Electronics, 2011, 12(6):961-965.