HU Jun-tao, CHENG Qun, YU Cheng-dong etc. Impact of Bphen doping Cs<sub>2</sub>CO<sub>3</sub> as electron transport layer on the performance of OLEDs[J]. , 2015,30(6): 943-948
HU Jun-tao, CHENG Qun, YU Cheng-dong etc. Impact of Bphen doping Cs<sub>2</sub>CO<sub>3</sub> as electron transport layer on the performance of OLEDs[J]. , 2015,30(6): 943-948 DOI: 10.3788/YJYXS20153006.0943.
Impact of Bphen doping Cs2CO3 as electron transport layer on the performance of OLEDs
In order to improve the balance of carrier injection
a high electron mobility material Bphen and Bphen:Cs
2
CO
3
are introduced in OLED devices respectively based on the structure of ITO/MoO
3
/NPB/Alq
3
/Cs
2
CO
3
/Al. The experiments study the effect of Bphen and Bphen doping Cs
2
CO
3
on the OLED devices of luminescence brightness
current density and efficiency by changing the thickness of Bphen and the volume concentration of Cs
2
CO
3
doped in Bphen. Experimental results show that Bphen or Bphen:Cs
2
CO
3
used as electron transport layer both can improve electronic injection and the performance of devices. Compared with the devices without Bphen
adding 25 nm thickness Bphen as electron transport layer can improve the device of electron injection
which increase the maximum current efficiency by 112%.Adding 5 nm thickness Bphen:Cs
2
CO
3
(15% volume concentration doped) as electron transport layer can reduce the electron injection barrier
which increase the maximum current efficiency by 27%. However
changing the doping layer thickness has little impact on the device's electron injection. This method can be used in cathode decorate of OLED devices and play a certain role in promoting the devices' performance.
关键词
Keywords
references
Hfle S, Do H, Mankel E, et al. Molybdenum oxide anode buffer layers for solution processed, blue phosphorescent small molecule organic light emitting diodes[J]. Organic Electronics, 2013, 14(7):1820-1824.
QuB, Gao Z, Yang H S, et al. Calcium chloride electron injection/extraction layers in organic electronic devices[J]. Applied Physics Letters, 2014, 104(4):043305.
席俭飞,张方辉,马颖,等.钙铝合金作为阴极对OLED器件性能的影响[J].液晶与显示, 2010,25(3):356-359. Xi J F, Zhang F H, Ma Y, et al. Effects of Ca:Al alloy as cathode on the performance of organic light-emitting devices[J]. Chinese Journal of Liquid Crystals and Displays,010, 25(3):356-359. (in Chinese)
陈金鑫,黄孝文. OLED梦幻显示器--材料与器件[M].北京:人民邮电出版社,2011. Chen J X, Huang X W. Fantastic OLED Display-Materials and Devices[M]. Peking:Posts and Telecom Press, 2011. (in Chinese)
Wei H X, Ou Q D, Zhang Z, et al. The role of cesium fluoride as an n-type dopant on electron transport layer in organic light-emitting diodes[J]. Organic Electronics, 2013, 14(3):839-844.
Deng Y H, Li Y Q, Ou Q D, et al. The doping effect of cesium-based compounds on carrier transport and operational stability in organic light-emitting diodes[J]. Organic Electronics, 2014, 15(6):1215-1221.
Huh D H, Kim G W, Kim G H, et al. High hole mobility hole transport material for organic light-emitting devices[J]. Synthetic Metals, 2013, 180:79-84.
Khan M A, Xu W, Wei F X, et al. Highly efficient organic electroluminescent diodes realized by efficientcharge balance with optimized electron and hole transport layers[J]. Solid State Communications, 2007, 144(7/8):343-346.
Chou D W, Chen K L, Huang C J, et al. Efficient small-molecule organic solar cells incorporating a doped buffer layer[J]. Thin Solid Films, 2013, 536:235-239.
Park J W, Lim J T, Oh J S, et al. Electron-injecting properties of Rb2CO3-doped Alq3 thin films in organic light-emitting diodes[J]. Journal of Vacuum Science & Technology A, 2013, 31(3):031101.
Hong J W, Kim C H, Han H S, et al. Dependence of the efficiency improvement of organic light-emitting diodes on the thickness of the Cs2CO3 electron-injection layer[J]. Journal of the Korean Physical Society, 2012, 60(10):1611-1615.
Liu W B, Liu S H, Yu J, et al. Efficient inverted organic light-emitting devices with self or intentionally Ag-doped interlayer modified cathode[J]. Applied Physics Letters, 2014, 104(9):093305.