Active matrix liquid crystal display (AM-LCD) has strict requirements on the liquid crystal properties
which greatly promoted the development of fluorinated liquid crystals. This paper reviews the progress in synthesis and application of fluorine containing liquid crystal materials in recent years
and focuses on the effects of different location of fluorine atom on the performance of the parent molecule in liquid crystal compound and the corresponding synthesis method. In combination with the liquid crystal phase transition temperature
dielectric anisotropy
birefringence and viscosity data
the key position of fluorine substituted in liquid crystal molecules were illustrated.It can significantly improve the performance of liquid crystal. The paper introduced the synthetic methods about terminal group fluorinated liquid crystals
benzene laterally fluorinated liquid crystals and the central bridge bond fluorinated liquid crystals.
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Detlef P, Kazuaki T. Optimization of liquid crystal for television[J].Journal of the Society for Information Display, 2005, 13(8):693-702.[2] 吴诗聪. 液晶材料与应用[J]. 现代显示, 1995(2):25-31. Wu S C. Materials and application of liquid crystal[J].Advanced Display, 1995(2):25-31.(in Chinese)[3] 李银华. 亲电氟化剂的研究进展[J]. 化学试剂, 2001, 23(30): 143-146. Li Y H. Research progress of dear electric fluorinating agent[J].Chemical Reagents, 2001, 23(30): 143-146. (in Chinese)[4] 杨燕, 刘骞峰. 氟化剂的研究进展[J]. 中国科技信息, 2010(21):144-146. Yang Y, Liu Q F. Research progress of fluorinating agent[J].China Science and Technology Information, 2010(21):144-146. (in Chinese)[5] 李建, 安忠维, 马方生. 二氟甲基醚类液晶[J]. 化学通报, 2005, 68(140):409-418. Li J, An Z W, Ma F S. Difluoromethyl ether liquid crystal[J].Chemistry, 2005, 68(140):409-418. (in Chinese)[6] 孟凡宝, 廉娇, 高永梅. 含氟液晶研究进展[J]. 化学进展, 2008, 20(4): 499-508. Meng F B, Lian J, Gao Y M. Advances in fluorinated liquid crystals[J].Progress in Chemistry, 2008, 20(4): 499-508. (in Chinese)[7] 孙冲, 秦川. 新型TFT含氟液晶的合成[D]. 上海:华东理工大学, 2009. Sun C, Qin C. Synthesis of novel TFT fluorinated liquid crystals[D].Shanghai:East China University of Science and Technology, 2009. (in Chinese)[8] 魏强, 曹晖, 朱思泉, 等. 一类含氟希夫碱液晶的合成及中间相性能[J]. 北京科技大学学报, 2008, 30(3):287-292. Wei Q, Cao H, Zhu S Q, et al.Synthesis and mesomorphic properties of fluorinated Schiff base liquid crystals[J].Journal of Beijing University of Science and Technology, 2008, 30(3):287-292. (in Chinese)[9] 陈新兵, 安忠维, 刘建群, 等. 1-(反式-4-烷基环己基)-苯基-2-含氟苯基取代乙炔类液晶的合成与性能[J]. 精细化工, 2005, 22(11):801-803. Chen X B, An Z W, Liu J Q, et al. Synthesis and properties of 1-(trans -4-alkylcyclohexyl) -phenyl -2-aryl acetylene containing fluoro terminal group[J].Fine Chemicals, 2005, 22(11):801-803. (in Chinese)[10] 黄梅, 陈建华, 陶晓春, 等. 含氟反式环己基联苯液晶的合成[J]. 液晶与显示, 2007, 22(2): 124-128. Huang M, Chen J H, Tao X C, et al.Synthesis of fluorinated trans cyclohexyl biphenyl liquid crystals[J].Chinese Journal of Liquid Crystal and Displays, 2007, 22(2): 124-128. (in Chinese)[11] 杜渭松 安忠维. 含氟反式-1, 4-二芳基环己烷类液晶化合物的合成[J]. 精细化工, 2003, 20(5):261-264. Du W S, An Z W. Synthesis of fluorinated trans -1, 4-diphenylcyclohexane liquid crystal compounds[J].Fine Chemicals, 2003, 20(5):261-264. (in Chinese)[12] 李衡峰, 闻建勋. 含氟极性端基取代的四氟二苯炔类液晶的合成与相变性质[J]. 中南大学学报, 2007, 38(1): 9-13. Li H F, Wen J X.Synthesis and mesomorphic properties of tetrafluorotolane-based liquid crystals with fluorinated polar end-groups[J].Journal Central South University of Technology, 2007, 38(1): 9-13.(in Chinese)[13] 侯光明, 唐洪, 徐寿颐. 合成侧向含氟酯类液晶的新方法[J]. 精细化工, 2004, 21(8):561-563. Hou G M, Tang H, Xu S Y. Synthesis of laterally fluorinated ester liquid crystal[J].Fine Chemicals, 2004, 21(8):561-563. (in Chinese)[14] 张芳苗, 韩光华, 尚洪勇, 等. 含氟联苯乙炔类液晶的合成[J]. 液晶与显示, 2010, 25(4):510-516. Zhang F M, Han G H, Shang H Y, et al. Synthesis of fluorinated biphenyl acetylene liquid crystals[J].Chinese Journal of Liquid Crystal and Displays, 2010, 25(4):510-516. (in Chinese)[15] 孙亮, 张志勇, 游红军, 等. 含氟联苯乙炔液晶化合物的合成及其低温性能[J]. 液晶与显示, 2010, 25(6):784-791. Sun L, Zhang Z Y, You H J, et al. Synthesis and low-temperature properties of lateral difluoro-diphenyltolane compounds[J].Chinese Journal of Liquid Crystal and Displays, 2010, 25(6):784-791. (in Chinese)[16] 朱生勃, 刘骞峰. 乙撑基桥键类含氟液晶的合成及性能研究[D]. 西安:西安建筑科技大学, 2009. Zhu S B, Liu Q F.Synthesis and properties of liquid crystals containing ethylene bridge and fluorines[D].XiAn:Xian University of Architecture & Technology, 2009. (in Chinese)[17] 李文博, 姜炜, 陈新兵, 等. 含氟液晶材料的发展趋势[J]. 浙江化工, 2010, 41(8):1-7. Li W B, Jiang W, Chen X B, et al.Tendency of the fluorinated liquid crystal materials[J].Zhejiang Chemical Industry, 2010, 41(8):1-7.(in Chinese)