High-performance nanofiltration membranes derived from liquid crystals

Yi-zhou ZHANG; Xun-da FENG

doi:10.37188/YJYXS20203507.0776

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High-performance nanofiltration membranes derived from liquid crystals

New Concept Applications | 更新时间：2020-07-13

- High-performance nanofiltration membranes derived from liquid crystals
- Chinese Journal of Liquid Crystals and Displays Vol. 35, Issue 7, Pages: 776-783(2020)
- 作者机构：
  
  1.宾夕法尼亚大学化学工程与生物工程系, 宾夕法尼亚州费城 19104
  2.东华大学先进低维材料中心, 上海 201620
- 作者简介：
- 基金信息：
  
  Start-up Fund for High-Level Talents, Donghua University(285-07-005710)
- DOI：10.37188/YJYXS20203507.0776
  CLC： O753.2
- Received：10 April 2020，
  
  Revised：11 May 2020，
  
  Accepted：11 May 2020，
  
  Published：05 July 2020
- 稿件说明：
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Yi-zhou ZHANG, Xun-da FENG. High-performance nanofiltration membranes derived from liquid crystals[J]. Chinese journal of liquid crystals and displays, 2020, 35(7): 776-783.
DOI：

Yi-zhou ZHANG, Xun-da FENG. High-performance nanofiltration membranes derived from liquid crystals[J]. Chinese journal of liquid crystals and displays, 2020, 35(7): 776-783. DOI： 10.37188/YJYXS20203507.0776.

摘要

纳滤膜是一种高效的膜分离技术，在整个膜工业领域占据重要地位。研发拥有高度有序水通道结构的纳滤膜，可以针对特定的分离应用，利用既定的纳米结构性质实现需要的分离效果。然而，传统的纳滤膜的性能受限于膜材料、制膜方法，无法精确构建水通道。利用液晶自组装的有序结构来制备高效的聚合物纳滤膜是一种行之有效的策略。各种不同的液晶相态可以用作精确调节纳米结构的模板，并通过灵活地改变其结构及形态，为下一代纳滤膜的研发提供了一种高度可控的制作平台。目前，基于液晶自组装的分离膜的分离尺度在1~2 nm的范围内。我们从两个方面评述了实现制备基于液晶材料的高性能纳滤膜的基本条件。从不同液晶相态的设计原理开始，首先讨论了不同纳米结构在实际传递作用中的固有性质。随后，对近期以薄膜复合膜的形式制作的液晶纳滤膜的报道进行了总结，分析了这些薄膜的性能局限性，为适应更广泛的分离引用，对目前液晶材料的设计理念提出了合理的改进措施。

Abstract

Nanofiltration membranes are a class of promising platform that is critical for selective small molecule separations. The development of nanofiltration membranes with an array of well-defined water channels motivates an opportunity to tailor the solute transport based on the precisely programmed nanostructured-properties. To date

however

the study of state-of-art nanofiltration materials has been slow to advance in constructing controlled water-channel architectures. Supramolecular assemblies derived from liquid crystalline mesophases offer a highly tunable system to fabricate nanostructured templates with the desired morphology following an inherent periodicity. These structurally ordered templates

in turn

can be tailored independently to target applications demanding higher permeability or specific solute selectivity. In this review

we highlight the development of liquid crystal-based materials from two fundamental aspects that will allow the realization of the next-generation nanofiltration membranes. Starting from the materials design principle that governs the creation of myriad nanostructures

we discuss the structural factors that define the intrinsic transport performance of different liquid crystal mesophases. Then we summarize the recent advances in the fabrication of liquid crystal nanofiltration membranes as thin-film composites

analyze their current limitation

and emphasize the potential approaches to revolutionize the current membrane design strategy. We envision these paradigm-altering approaches can support the development of liquid crystalline materials towards a more extensive range of membrane applications.

关键词

Keywords

references

P RODGERS , J WILDE . Nanoscience and Technology:A Collection of Reviews from Nature Journals , : Singapore World Scientific , 2010 . 337 - 346 .

CADOTTE J E, PETERSEN R J. Thin-film Composite Reverse-osmosis Membranes: Origin, Development, and Recent Advances[M]//Turbak A F edi., Synthetic Membranes. USA: ACS Publications, 1981: 305-326.

V T DO , C Y TANG , M REINHARD , 等 . Effects of chlorine exposure conditions on physiochemical properties and performance of a polyamide membrane-mechanisms and implications . Environmental Science & Technology , 2012 . 46 ( 24 ): 13184 - 13192 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=338c23343257610a06a83680334ba2d5 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=338c23343257610a06a83680334ba2d5 .

V T DO , C Y TANG , M REINHARD , 等 . Effects of hypochlorous acid exposure on the rejection of salt, polyethylene glycols, boron and arsenic (Ⅴ) by nanofiltration and reverse osmosis membranes . Water Research , 2012 . 46 ( 16 ): 5217 - 5223 . DOI: 10.1016/j.watres.2012.06.044 http://doi.org/10.1016/j.watres.2012.06.044 .

B VAN DER BRUGGEN , M MÄNTTÄRI , M NYSTRÖM . Drawbacks of applying nanofiltration and how to avoid them:a review . Separation and Purification Technology , 2008 . 63 ( 2 ): 251 - 263 . DOI: 10.1016/j.seppur.2008.05.010 http://doi.org/10.1016/j.seppur.2008.05.010 .

D L GIN , J E BARA , R D NOBLE , 等 . Polymerized lyotropic liquid crystal assemblies for membrane applications . Macromolecular Rapid Communications , 2008 . 29 ( 5 ): 367 - 389 . DOI: 10.1002/marc.200700707 http://doi.org/10.1002/marc.200700707 .

D L GIN , W Q GU , B A PINDZOLA , 等 . Polymerized lyotropic liquid crystal assemblies for materials applications . Accounts of Chemical Research , 2001 . 34 ( 12 ): 973 - 980 . DOI: 10.1021/ar000140d http://doi.org/10.1021/ar000140d .

T HUMPLIK , J LEE , S C O'HERN , 等 . Nanostructured materials for water desalination . Nanotechnology , 2011 . 22 ( 29 ): 292001 DOI: 10.1088/0957-4484/22/29/292001 http://doi.org/10.1088/0957-4484/22/29/292001 .

T KATO , J UCHIDA , T ICHIKAWA , 等 . Functional liquid crystals towards the next generation of materials . Angewandte Chemie International Edition , 2018 . 57 ( 16 ): 4355 - 4371 . DOI: 10.1002/anie.201711163 http://doi.org/10.1002/anie.201711163 .

D L GIN , X LU , P R NEMADE , 等 . Recent advances in the design of polymerizable lyotropic liquid-crystal assemblies for heterogeneous catalysis and selective separations . Advanced Functional Materials , 2006 . 16 ( 7 ): 865 - 878 . DOI: 10.1002/adfm.200500280 http://doi.org/10.1002/adfm.200500280 .

J ABRAHAM , K S VASU , C D WILLIAMS , 等 . Tunable sieving of ions using graphene oxide membranes . Nature Nanotechnology , 2017 . 12 ( 16 ): 546 - 550 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=1a02ec101eeaee3adfaae884e5b59782 http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=1a02ec101eeaee3adfaae884e5b59782 .

H NADA , T SAKAMOTO , M HENMI , 等 . Transport mechanisms of water molecules and ions in sub-nano channels of nanostructured water treatment liquid-crystalline membranes:a molecular dynamics simulation study . Environmental Science:Water Research & Technology , 2020 . 6 ( 3 ): 604 - 611 .

B RADHA , A ESFANDIAR , F C WANG , 等 . Molecular transport through capillaries made with atomic-scale precision . Nature , 2016 . 538 ( 7624 ): 222 - 225 . DOI: 10.1038/nature19363 http://doi.org/10.1038/nature19363 .

G HUMMER , J C RASAIAH , J P NOWORYTA . Water conduction through the hydrophobic channel of a carbon nanotube . Nature , 2001 . 414 ( 6860 ): 188 - 190 . DOI: 10.1038/35102535 http://doi.org/10.1038/35102535 .

B CORRY . Designing carbon nanotube membranes for efficient water desalination . The Journal of Physical Chemistry B , 2008 . 112 ( 5 ): 1427 - 1434 . DOI: 10.1021/jp709845u http://doi.org/10.1021/jp709845u .

M HENMI , K NAKATSUJI , T ICHIKAWA , 等 . Self-organized liquid-crystalline nanostructured membranes for water treatment:selective permeation of ions . Advanced Materials , 2012 . 24 ( 17 ): 2238 - 2241 . DOI: 10.1002/adma.201200108 http://doi.org/10.1002/adma.201200108 .

A J C SEMIÃO , A I SCHÄFER . Removal of adsorbing estrogenic micropollutants by nanofiltration membranes. Part A-experimental evidence . Journal of Membrane Science , 2013 . 431 244 - 256 . DOI: 10.1016/j.memsci.2012.11.080 http://doi.org/10.1016/j.memsci.2012.11.080 .

J R WERBER , C O OSUJI , M ELIMELECH . Materials for next-generation desalination and water purification membranes . Nature Reviews Materials , 2016 . 1 ( 5 ): 16018 DOI: 10.1038/natrevmats.2016.18 http://doi.org/10.1038/natrevmats.2016.18 .

Y Z ZHANG , J L SARGENT , B W BOUDOURIS , 等 . Nanoporous membranes generated from self-assembled block polymer precursors: Quo vadis ? . Journal of Applied Polymer Science , 2015 . 132 ( 21 ): 41683 http://d.old.wanfangdata.com.cn/NSTLQK/NSTL_QKJJ0234229692/ http://d.old.wanfangdata.com.cn/NSTLQK/NSTL_QKJJ0234229692/ .

M J ZHOU , P R NEMADE , X Y LU , 等 . New type of membrane material for water desalination based on a cross-linked bicontinuous cubic lyotropic liquid crystal assembly . Journal of the American Chemical Society , 2007 . 129 ( 31 ): 9574 - 9575 . DOI: 10.1021/ja073067w http://doi.org/10.1021/ja073067w .

L LI , L SCHULTE , L D CLAUSEN , 等 . Gyroid nanoporous membranes with tunable permeability . ACS Nano , 2011 . 5 ( 10 ): 7754 - 7766 . DOI: 10.1021/nn200610r http://doi.org/10.1021/nn200610r .

E S HATAKEYAMA , B R WIESENAUER , C J GABRIEL , 等 . Nanoporous, bicontinuous cubic lyotropic liquid crystal networks via polymerizable gemini ammonium surfactants . Chemistry of Materials , 2010 . 22 ( 16 ): 4525 - 4527 . DOI: 10.1021/cm1013027 http://doi.org/10.1021/cm1013027 .

G P SORENSON , K L COPPAGE , M K MAHANTHAPPA . Unusually stable aqueous lyotropic gyroid phases from gemini dicarboxylate surfactants . Journal of the American Chemical Society , 2011 . 133 ( 38 ): 14928 - 14931 . DOI: 10.1021/ja2063555 http://doi.org/10.1021/ja2063555 .

C V KULKARNI , T Y TANG , A M SEDDON , 等 . Engineering bicontinuous cubic structures at the nanoscale-the role of chain splay . Soft Matter , 2010 . 6 ( 14 ): 3191 - 3194 . DOI: 10.1039/c0sm00068j http://doi.org/10.1039/c0sm00068j .

B A PINDZOLA , J Z JIN , D L GIN . Cross-linked normal hexagonal and bicontinuous cubic assemblies via polymerizable gemini amphiphiles . Journal of the American Chemical Society , 2003 . 125 ( 10 ): 2940 - 2949 . DOI: 10.1021/ja0208106 http://doi.org/10.1021/ja0208106 .

G C SHEARMAN , B J KHOO , M L MOTHERWELL , 等 . Calculations of and evidence for chain packing stress in inverse lyotropic bicontinuous cubic phases . Langmuir , 2007 . 23 ( 13 ): 7276 - 7285 . DOI: 10.1021/la700355a http://doi.org/10.1021/la700355a .

E S HATAKEYAMA , C J GABRIEL , B R WIESENAUER , 等 . Water filtration performance of a lyotropic liquid crystal polymer membrane with uniform, sub-1-nm pores . Journal of Membrane Science , 2011 . 366 ( 1-2 ): 62 - 72 . DOI: 10.1016/j.memsci.2010.09.028 http://doi.org/10.1016/j.memsci.2010.09.028 .

B M CARTER , B R WIESENAUER , E S HATAKEYAMA , 等 . Glycerol-based bicontinuous cubic lyotropic liquid crystal monomer system for the fabrication of thin-film membranes with uniform nanopores . Chemistry of Materials , 2012 . 24 ( 21 ): 4005 - 4007 . DOI: 10.1021/cm302027s http://doi.org/10.1021/cm302027s .

T SAKAMOTO , T OGAWA , H NADA , 等 . Development of nanostructured water treatment membranes based on thermotropic liquid crystals:molecular design of sub-nanoporous materials . Advanced Science , 2018 . 5 ( 1 ): 1700405 DOI: 10.1002/advs.201700405 http://doi.org/10.1002/advs.201700405 .

B A PINDZOLA , B P HOAG , D L GIN . Polymerization of a phosphonium diene amphiphile in the regular hexagonal phase with retention of mesostructure . Journal of the American Chemical Society , 2001 . 123 ( 19 ): 4617 - 4618 . DOI: 10.1021/ja0058583 http://doi.org/10.1021/ja0058583 .

H K LEE , H LEE , Y H KO , 等 . Synthesis of a nanoporous polymer with hexagonal channels from supramolecular discotic liquid crystals . Angewandte Chemie International Edition , 2001 . 40 ( 14 ): 2669 - 2671 . DOI: 10.1002/1521-3773(20010716)40:14<2669::AID-ANIE2669>3.0.CO;2-Q http://doi.org/10.1002/1521-3773(20010716)40:14<2669::AID-ANIE2669>3.0.CO;2-Q .

H DENG , D L GIN , R C SMITH . Polymerizable lyotropic liquid crystals containing transition-metal and lanthanide ions:architectural control and introduction of new properties into nanostructured polymers . Journal of the American Chemical Society , 1998 . 120 ( 14 ): 3522 - 3523 . DOI: 10.1021/ja9743654 http://doi.org/10.1021/ja9743654 .

M GUPTA , Y SUZUKI , T SAKAMOTO , 等 . Polymerizable photocleavable columnar liquid crystals for nanoporous water treatment membranes . ACS Macro Letters , 2019 . 8 ( 10 ): 1303 - 1308 . DOI: 10.1021/acsmacrolett.9b00513 http://doi.org/10.1021/acsmacrolett.9b00513 .

K YANO , Y ITOH , F ARAOKA , 等 . Nematic-to-columnar mesophase transition by in situ supramolecular polymerization . Science , 2019 . 363 ( 6423 ): 161 - 165 . DOI: 10.1126/science.aan1019 http://doi.org/10.1126/science.aan1019 .

D SAHOO , M R IMAM , M PETERCA , 等 . Hierarchical self-organization of chiral columns from chiral supramolecular spheres . Journal of the American Chemical Society , 2018 . 140 ( 41 ): 13478 - 13487 . DOI: 10.1021/jacs.8b09174 http://doi.org/10.1021/jacs.8b09174 .

G M BÖGELS , J A M LUGGER , O J G M GOOR , 等 . Size-selective binding of sodium and potassium ions in nanoporous thin films of polymerized liquid crystals . Advanced Functional Materials , 2016 . 26 ( 44 ): 8023 - 8030 . DOI: 10.1002/adfm.201603408 http://doi.org/10.1002/adfm.201603408 .

G M BÖGELS , H P C VAN KURINGEN , I K SHISHMANOVA , 等 . Selective absorption of hydrophobic cations in nanostructured porous materials from crosslinked hydrogen-bonded columnar liquid crystals . Advanced Materials Interfaces , 2015 . 2 ( 7 ): 1500022 DOI: 10.1002/admi.201500022 http://doi.org/10.1002/admi.201500022 .

S BHATTACHARJEE , J A M LUGGER , R P SIJBESMA . Tailoring pore size and chemical interior of near 1 nm sized pores in a nanoporous polymer based on a discotic liquid crystal . Macromolecules , 2017 . 50 ( 7 ): 2777 - 2783 . DOI: 10.1021/acs.macromol.7b00013 http://doi.org/10.1021/acs.macromol.7b00013 .

X D FENG , K KAWABATA , G KAUFMAN , 等 . Highly selective vertically aligned nanopores in sustainably derived polymer membranes by molecular templating . ACS Nano , 2017 . 11 ( 4 ): 3911 - 3921 . DOI: 10.1021/acsnano.7b00304 http://doi.org/10.1021/acsnano.7b00304 .

B J COSCIA , J YELK , M A GLASER , 等 . Understanding the nanoscale structure of inverted hexagonal phase lyotropic liquid crystal polymer membranes . The Journal of Physical ChemistryB , 2018 . 123 ( 1 ): 289 - 309 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=4e4a2a3c9dfc6cc5be12dfffab60267b http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=4e4a2a3c9dfc6cc5be12dfffab60267b .

M ZHOU , T J KIDD , R D NOBLE , 等 . Supported lyotropic liquid-crystal polymer membranes:Promising materials for molecular-size-selective aqueous nanofiltration . Advanced Materials , 2005 . 17 ( 15 ): 1850 - 1853 . DOI: 10.1002/adma.200500444 http://doi.org/10.1002/adma.200500444 .

X D FENG , M E TOUSLEY , M G COWAN , 等 . Scalable fabrication of polymer membranes with vertically aligned 1 nm pores by magnetic field directed self-assembly . ACS Nano , 2014 . 8 ( 12 ): 11977 - 11986 . DOI: 10.1021/nn505037b http://doi.org/10.1021/nn505037b .

X D FENG , K KAWABATA , M G COWAN , 等 . Single crystal texture by directed molecular self-assembly along dual axes . Nature Materials , 2019 . 18 ( 11 ): 1235 - 1243 . DOI: 10.1038/s41563-019-0389-1 http://doi.org/10.1038/s41563-019-0389-1 .

M E TOUSLEY , X D FENG , M ELIMELECH , 等 . Aligned nanostructured polymers by magnetic-field-directed self-assembly of a polymerizable lyotropic mesophase . ACS Applied Materials & Interfaces , 2014 . 6 ( 22 ): 19710 - 19717 . http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=971f13cabcb53081337acee8f99ef1cb http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=971f13cabcb53081337acee8f99ef1cb .

X D FENG , S NEJATI , M G COWAN , 等 . Thin polymer films with continuous vertically aligned 1 nm pores fabricated by soft confinement . ACS Nano , 2016 . 10 ( 1 ): 150 - 158 . DOI: 10.1021/acsnano.5b06130 http://doi.org/10.1021/acsnano.5b06130 .

J A M LUGGER , D J MULDER , S BHATTACHARJEE , 等 . Homeotropic self-alignment of discotic liquid crystals for nanoporous polymer films . ACS Nano , 2018 . 12 ( 7 ): 6714 - 6724 . DOI: 10.1021/acsnano.8b01822 http://doi.org/10.1021/acsnano.8b01822 .

X D FENG , Q IMRAN , Y Z ZHANG , 等 . Precise nanofiltration in a fouling-resistant self-assembled membrane with water-continuous transport pathways . Science Advances , 2019 . 5 ( 8 ): eaav9308 DOI: 10.1126/sciadv.aav9308 http://doi.org/10.1126/sciadv.aav9308 .

陈清 , 韩庆 . 石墨烯膜在水处理中的应用 . 应用化学 , 2018 . 35 ( 3 ): 299 - 306 . http://d.old.wanfangdata.com.cn/Periodical/yyhx201803006 http://d.old.wanfangdata.com.cn/Periodical/yyhx201803006 .

Q CHEN , Q HAN . Application of graphene membrane in water treatment . Chinese Journal of Applied Chemistry , 2018 . 35 ( 3 ): 299 - 306 . http://d.old.wanfangdata.com.cn/Periodical/yyhx201803006 http://d.old.wanfangdata.com.cn/Periodical/yyhx201803006 .

彭继华 , 郭贵宝 . 四甲基氢氧化铵改性聚偏氟乙烯一步接枝聚苯乙烯磺酸油水分离膜的制备及性能 . 应用化学 , 2019 . 36 ( 8 ): 909 - 916 . http://d.old.wanfangdata.com.cn/Periodical/yyhx201908007 http://d.old.wanfangdata.com.cn/Periodical/yyhx201908007 .

J H PENG , G B GUO . Preparation and properties of oil/water separation membranes synthesized via one-step grafting poly(styrene sulfonic acid) onto poly(vinylidene fluoride) modified by tetramethylammonium hydroxide . Chinese Journal of Applied Chemistry , 2019 . 36 ( 8 ): 909 - 916 . http://d.old.wanfangdata.com.cn/Periodical/yyhx201908007 http://d.old.wanfangdata.com.cn/Periodical/yyhx201908007 .

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