Reduced harmful blue light attenuator based on self-assembly of metal nanoparticles

ZHU Qing; LIU Gen; GOU Han-guang; SHI Guang-hua; LAI Wei-en

doi:10.37188/CJLCD.2022-0168

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Reduced harmful blue light attenuator based on self-assembly of metal nanoparticles

Device Physics and Device Preparation | 更新时间：2022-12-07

- Reduced harmful blue light attenuator based on self-assembly of metal nanoparticles
- Chinese Journal of Liquid Crystals and Displays Vol. 37, Issue 9, Pages: 1158-1164(2022)
- 作者机构：
  
  1.合肥工业大学光电技术研究院仪器科学与光电工程学院特种显示技术国家工程实验室测量理论与精密仪器安徽省重点实验室，安徽合肥 230009
  2.中国电子科技集团第13研究所，河北石家庄 050051
- 作者简介：
- 基金信息：
  
  Anhui Provincial Natural Science Foundation(1908085MF200);Fundamental Research Funds for the Central Universities of China(PA2021GDSK0098)
- DOI：10.37188/CJLCD.2022-0168
  CLC： TN29
- Received：16 May 2022，
  
  Revised：23 May 2022，
  
  Published：05 September 2022
- 稿件说明：
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ZHU Qing, LIU Gen, GOU Han-guang, et al. Reduced harmful blue light attenuator based on self-assembly of metal nanoparticles[J]. Chinese journal of liquid crystals and displays, 2022, 37(9): 1158-1164.
DOI：

ZHU Qing, LIU Gen, GOU Han-guang, et al. Reduced harmful blue light attenuator based on self-assembly of metal nanoparticles[J]. Chinese journal of liquid crystals and displays, 2022, 37(9): 1158-1164. DOI： 10.37188/CJLCD.2022-0168.

摘要

为了减少LED等照明方式中有害蓝光成分对人眼带来的危害，提出了一种基于金属纳米颗粒自组装的局域表面等离子体共振效应的减有害蓝光衰减器。通过合成制备了银包金纳米颗粒（Au@Ag NPs）和银纳米颗粒（Ag NPs），使用自组装的方法在石英玻璃上制备了纳米颗粒单层膜，并通过退火进行后处理改变颗粒形貌和分布。使用扫描电子显微镜（SEM）图像对不同样品纳米颗粒的形貌以及排布方式进行分析，对样品进行紫外可见光透射光谱测试，并借助于时域有限差分法对透射情况进行模拟，分析影响透射峰值的因素。结果表明，自组装方法制备的样品对不同波段的光传输有选择性的衰减，并且在退火后衰减峰值发生了蓝移。最后，展示了不同样品在白光LED下的实际透光效果，其中退火Ag NPs样品在416 nm有害蓝光波段处，可将透射减至24.5%，有效地衰减了有害蓝光，具有优异的蓝光防护效果。

Abstract

In order to reduce the harmful blue light component of LEDs and other illumination modalities to human eyes， we propose a reduced harmful blue light attenuator based on the local surface plasmon resonance effect of self-assembled metal nanoparticles. The silver-covered gold nanoparticles （Au@Ag NPs） and silver nanoparticles （Ag NPs） were prepared by synthesis. Nanoparticle monolayers film were prepared on quartz glass using the self-assembly method， and the particle morphology film and distribution were changed by post-treatment through annealing. The scanning electron microscopy （SEM） images were used to analyze the morphology of nanoparticles of different samples as well as the arrangement pattern. The samples were subjected to UV-Vis transmission spectroscopy and the transmission was simulated with the help of time-domain finite difference method to analyze the factors affecting the transmission peaks. The results show that the samples prepared by the self-assembly method have selective attenuation of light transmission at different wavelengths and the attenuation peaks are blue-shifted after annealing. Finally， this paper shows the actual light transmission effects of different samples under white LEDs， in which the annealed Ag NPs sample can reduce the transmission to 24.5% at the 416 nm harmful blue light band， which significantly and effectively attenuates the harmful blue light and has excellent blue light protection effect.

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references

MORGAN PATTISON P ， HANSEN M ， TSAO J Y . LED lighting efficacy： status and directions ［J］. Comptes Rendus Physique ， 2018 ， 19 （ 3 ）： 134 - 145 . doi: 10.1016/j.crhy.2017.10.013 http://dx.doi.org/10.1016/j.crhy.2017.10.013

曹慧，郑喜凤，汪洋，等 . 超高清超高分辨率大尺寸LED显示器［J］. 液晶与显示， 2021 ， 36 （ 4 ）： 566 - 574 ． doi: 10.37188/CJLCD.2020-0346 http://dx.doi.org/10.37188/CJLCD.2020-0346

CAO H ， ZHENG X F ， WANG Y ， et al . Ultra high definition ultra-high resolution large size LED display ［J］. Chinese Journal of Liquid Crystals and Displays ， 2021 ， 36 （ 4 ）： 566 - 574 . （in Chinese） . doi: 10.37188/CJLCD.2020-0346 http://dx.doi.org/10.37188/CJLCD.2020-0346

DU F ， ZHUANG W D ， LIU R H ， et al . Synthesis， structure and luminescent properties of yellow phosphor La 3 Si 6 N 11 ∶ Ce 3+ for high power white-LEDs ［J］. Journal of Rare Earths ， 2017 ， 35 （ 11 ）： 1059 - 1064 . doi: 10.1016/j.jre.2017.05.010 http://dx.doi.org/10.1016/j.jre.2017.05.010

武文杰，阿木古楞，刘文全，等 . 氮（氧）化物荧光粉的合成与发光性能［J］. 液晶与显示， 2017 ， 32 （ 9 ）： 663 - 676 ． doi: 10.3788/yjyxs20173209.0663 http://dx.doi.org/10.3788/yjyxs20173209.0663

WU W J ， AMUGULEN ， LIU W Q ， et al . Synthesis and luminescence of nitride and oxynitride luminescent materials ［J］. Chinese Journal of Liquid Crystals and Displays ， 2017 ， 32 （ 9 ）： 663 - 676 . （in Chinese） . doi: 10.3788/yjyxs20173209.0663 http://dx.doi.org/10.3788/yjyxs20173209.0663

OUYANG X L ， YANG J ， HONG Z X ， et al . Mechanisms of blue light-induced eye hazard and protective measures： a review ［J］. Biomedicine & Pharmacotherapy ， 2020 ， 130 ： 110577 . doi: 10.1016/j.biopha.2020.110577 http://dx.doi.org/10.1016/j.biopha.2020.110577

TOSINI G ， FERGUSON I ， TSUBOTA K . Effects of blue light on the circadian system and eye physiology ［J］. Molecular Vision ， 2016 ， 22 ： 61 - 72 .

张平奇，王丹，吕振华，等 . 健康显示的影响因素综述［J］. 液晶与显示， 2020 ， 35 （ 9 ）： 981 - 990 ． doi: 10.37188/YJYXS20203509.0981 http://dx.doi.org/10.37188/YJYXS20203509.0981

ZHANG P Q ， WANG D ， LYU Z H ， et al . Review of determinants of healthy display ［J］. Chinese Journal of Liquid Crystals and Displays ， 2020 ， 35 （ 9 ）： 981 - 990 . （in Chinese） . doi: 10.37188/YJYXS20203509.0981 http://dx.doi.org/10.37188/YJYXS20203509.0981

LEE S I ， MATSUMORI K ， NISHIMURA K ， et al . Melatonin suppression and sleepiness in children exposed to blue-enriched white LED lighting at night ［J］. Physiological Reports ， 2018 ， 6 （ 24 ）： e13942 . doi: 10.14814/phy2.13942 http://dx.doi.org/10.14814/phy2.13942

ZHANG J J ， GUO W H ， XIE B ， et al . Blue light hazard optimization for white light-emitting diode sources with high luminous efficacy of radiation and high color rendering index ［J］. Optics & Laser Technology ， 2017 ， 94 ： 193 - 198 . doi: 10.1016/j.optlastec.2017.03.031 http://dx.doi.org/10.1016/j.optlastec.2017.03.031

ZHU X ， GUO X ， ZHANG J L ， et al . Phosphor-free， color-mixed， and efficient illuminant： multi-chip packaged LEDs for optimizing blue light hazard and non-visual biological effects ［J］. Optics and Lasers in Engineering ， 2020 ， 134 ： 106174 . doi: 10.1016/j.optlaseng.2020.106174 http://dx.doi.org/10.1016/j.optlaseng.2020.106174

SHOU C H ， LUO Z Y ， WANG T ， et al . Investigation of a broadband TiO 2 /SiO 2 optical thin-film filter for hybrid solar power systems ［J］. Applied Energy ， 2012 ， 92 ： 298 - 306 . doi: 10.1016/j.apenergy.2011.09.028 http://dx.doi.org/10.1016/j.apenergy.2011.09.028

庞梦林，周顺，郭峰，等 . 用于观察瞄准镜的截止滤光片设计和制备［J］. 应用光学， 2022 ， 43 （ 2 ）： 221 - 227 ． doi: 10.5768/jao202243.0201006 http://dx.doi.org/10.5768/jao202243.0201006

PANG M L ， ZHOU S ， GUO F ， et al . Design and preparation of cut-off filter for observation scope ［J］. Journal of Applied Optics ， 2022 ， 43 （ 2 ）： 221 - 227 . （in Chinese） . doi: 10.5768/jao202243.0201006 http://dx.doi.org/10.5768/jao202243.0201006

YU H K ， PENG Y S ， YANG Y ， et al . Plasmon-enhanced light-matter interactions and applications ［J］. NPJ Computational Materials ， 2019 ， 5 ： 45 . doi: 10.1038/s41524-019-0184-1 http://dx.doi.org/10.1038/s41524-019-0184-1

LOISEAU A ， ZHANG L ， HU D ， et al . Core-shell gold/silver nanoparticles for localized surface plasmon resonance-based naked-eye toxin biosensing ［J］. ACS Applied Materials & Interfaces ， 2019 ， 11 （ 50 ）： 46462 - 46471 . doi: 10.1021/acsami.9b14980 http://dx.doi.org/10.1021/acsami.9b14980

ŠPRINGER T ， ERMINI M L ， ŠPAČKOVÁ B ， et al . Enhancing sensitivity of surface plasmon resonance biosensors by functionalized gold nanoparticles： size matters ［J］. Analytical Chemistry ， 2014 ， 86 （ 20 ）： 10350 - 10356 . doi: 10.1021/ac502637u http://dx.doi.org/10.1021/ac502637u

AMENDOLA V ， PILOT R ， FRASCONI M ， et al . Surface plasmon resonance in gold nanoparticles： a review ［J］. Journal of Physics： Condensed Matter ， 2017 ， 29 （ 20 ）： 203002 . doi: 10.1088/1361-648x/aa60f3 http://dx.doi.org/10.1088/1361-648x/aa60f3

CHAI Y ， HASNAIN J ， BAHL K ， et al . Direct observation of nanoparticle-surfactant assembly and jamming at the water-oil interface ［J］. Science Advances ， 2020 ， 6 （ 48 ）： eabb8675 . doi: 10.1126/sciadv.abb8675 http://dx.doi.org/10.1126/sciadv.abb8675

TAHGHIGHI M ， MANNELLI I ， JANNER D ， et al . Tailoring plasmonic response by Langmuir-Blodgett gold nanoparticle templating for the fabrication of SERS substrates ［J］. Applied Surface Science ， 2018 ， 447 ： 416 - 422 . doi: 10.1016/j.apsusc.2018.03.237 http://dx.doi.org/10.1016/j.apsusc.2018.03.237

BASTúS N G ， MERKOçI F ， PIELLA J ， et al . Synthesis of highly monodisperse citrate-stabilized silver nanoparticles of up to 200 nm： kinetic control and catalytic properties ［J］. Chemistry of Materials ， 2014 ， 26 （ 9 ）： 2836 - 2846 . doi: 10.1021/cm500316k http://dx.doi.org/10.1021/cm500316k

WEI H R ， LENG W N ， SONG J ， et al . Real-time monitoring of ligand exchange kinetics on gold nanoparticle surfaces enabled by hot spot-normalized surface-enhanced raman scattering ［J］. Environmental Science & Technology ， 2019 ， 53 （ 2 ）： 575 - 585 . doi: 10.1021/acs.est.8b03144 http://dx.doi.org/10.1021/acs.est.8b03144

YANG G ， HALLINAN D T . Self-assembly of large-scale crack-free gold nanoparticle films using a'drain-to-deposit' strategy ［J］. Nanotechnology ， 2016 ， 27 （ 22 ）： 225604 . doi: 10.1088/0957-4484/27/22/225604 http://dx.doi.org/10.1088/0957-4484/27/22/225604

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