Ion transport electrolyte by self-assembly of liquid crystal materials

Zong-cheng MIAO; Ya-qin CHU; Wen-qing ZHU

doi:10.37188/CJLCD.2022-0013

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Ion transport electrolyte by self-assembly of liquid crystal materials

Material Physics | 更新时间：2022-06-14

- Ion transport electrolyte by self-assembly of liquid crystal materials
- Chinese Journal of Liquid Crystals and Displays Vol. 37, Issue 4, Pages: 437-443(2022)
- 作者机构：
  
  1.西北工业大学光电与智能研究院，陕西西安 710072
  2.安徽工程大学化学与环境工程学院，安徽芜湖 241000
- 作者简介：
- 基金信息：
  
  he National Natural Science Foundation of China(52173263);the Natural Science Foundation of Anhui Province, China(2108085J11);the Fundamental Research Funds for the Central Universities, Northwestern Polytechnical University(D5000210825)
- DOI：10.37188/CJLCD.2022-0013
  CLC： O753⁺.2;TQ317.4;TK02
- Received：13 January 2022，
  
  Revised：22 February 2022，
  
  Published：05 April 2022
- 稿件说明：
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Zong-cheng MIAO, Ya-qin CHU, Wen-qing ZHU. Ion transport electrolyte by self-assembly of liquid crystal materials[J]. Chinese journal of liquid crystals and displays, 2022, 37(4): 437-443.
DOI：

Zong-cheng MIAO, Ya-qin CHU, Wen-qing ZHU. Ion transport electrolyte by self-assembly of liquid crystal materials[J]. Chinese journal of liquid crystals and displays, 2022, 37(4): 437-443. DOI： 10.37188/CJLCD.2022-0013.

摘要

液晶态兼具了固态和液态的优点，作为电解质材料可以兼顾安全性、离子传输率、加工性能、电化学稳定性和界面相容性等特点，受到了越来越多的关注和研究。热致液晶材料可以通过自组装构筑完整的一维、二维或三维离子传输通道，它是电解质研究中广泛关注的领域，特别是近晶相液晶态电解质构筑的稳定二维锂离子传输通道受到了广泛关注，相较于其他液晶态电解质如柱状相、双连续立方相或离子型液晶，在离子传输率方面具有明显优势。本文主要综述了热致液晶材料作为离子电池电解质的起源、发展及其所具备的结构特点，并详细介绍了近年来液晶态电解质的国内外研究进展和应用现状。

Abstract

Liquid crystal has the advantages of both solid and liquid. As a battery electrolyte material， it has attracted more and more attention and research for safety， ion transfer rate， processability， electrochemical stability and interface compatibility. Thermotropic liquid crystal materials can construct complete one-dimensional， two-dimensional or three-dimensional ion transport channels through self-assembly， which is a field of widespread concern in electrolyte research. In particular， the stable two-dimensional ion transport channels constructed by smectic liquid crystalline electrolytes have received extensive attention. Compared with other liquid crystalline electrolytes such as columnar phase， bicontinuous cubic phase or ionic liquid crystals， smectic phase has obvious advantages in ion transfer rate. In this paper， the origin， development and structural characteristics of thermotropic liquid crystal materials as ion battery electrolytes are reviewed， and the research progress and application status at home and abroad in recent years are introduced in details.

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