Synthesis and Properties of Fluorotolane Liquid Crystal Compounds

ZHANG Fang-miao; HAN Yao-hua; SHANG Hong-yong; ZHANG Jing-mei; QIAN Xiu-li

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Synthesis and Properties of Fluorotolane Liquid Crystal Compounds

Material Physics & Chemistry | 更新时间：2020-08-12

- Synthesis and Properties of Fluorotolane Liquid Crystal Compounds
- Chinese Journal of Liquid Crystals and Displays Vol. 25, Issue 4, Pages: 510-514(2010)
- 作者机构：
  
  石家庄诚志永华显示材料有限公司, 河北石家庄 050091,E-mail:zhangfangmiao1@126.com
- 作者简介：
- 基金信息：
- DOI：
  CLC： O753+.2
- Received：18 January 2010，
  
  Revised：11 April 2010，
  
  Published Online：20 August 2010，
  
  Published：20 August 2010
- 稿件说明：
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张芳苗, 韩耀华, 尚洪勇, 张晶梅, 钤秀丽. 含氟联苯乙炔类液晶的合成[J]. 液晶与显示, 2010,25(4): 510-514

ZHANG Fang-miao, HAN Yao-hua, SHANG Hong-yong, ZHANG Jing-mei, QIAN Xiu-li. Synthesis and Properties of Fluorotolane Liquid Crystal Compounds[J]. 液晶与显示, 2010,25(4): 510-514
张芳苗, 韩耀华, 尚洪勇, 张晶梅, 钤秀丽. 含氟联苯乙炔类液晶的合成[J]. 液晶与显示, 2010,25(4): 510-514 DOI：

ZHANG Fang-miao, HAN Yao-hua, SHANG Hong-yong, ZHANG Jing-mei, QIAN Xiu-li. Synthesis and Properties of Fluorotolane Liquid Crystal Compounds[J]. 液晶与显示, 2010,25(4): 510-514 DOI：

摘要

丁基溴苯和间氟苯硼酸经Suzuki偶联生成4'丁基-3-氟联苯

4'丁基-3-氟联苯在低温下碘代生成3-氟-4-碘-4'-丁基联苯

3-氟-4-碘-4'-丁基联苯与5种取代苯乙炔发生Sonogashira反应生成5种含氟联苯炔类单体液晶。进行了产品结构的标定以及参数的测定

确定了化合物具有较大的光学各向异性(

)和较宽的向列相范围。

Abstract

A compound 4'-butyl -3- fluoro -biphenyl was synthesized conjugated with Suzuki from Butyl-bromobenzene and fluorobenzene boronic acid

which generated 3 - fluoro -4- iodine -4 '- butyl - biphenyl under low temperature. Then 3 - fluoro -4 - iodine -4 '- butyl- biphenyl reacted with five types of substituted benzene acetylene

generating five fluorinated biphenyl alkyne monomer liquid crystals via Sonogashira reaction. The structures and parameters of the products were determined. It was found that these compounds has higher optical anisotropy (

) and wider range of nematic phase.

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Keywords

references

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Related Institution

石家庄诚志永华显示材料有限公司

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Shanghai Tianwen Chemical Corporation

School of Materials Science and Engineering, University of Science and Technology Beijing

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