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四川大学高分子科学与工程学院高分子材料工程国家重点实验室,四川 成都,610065
Received:10 June 2009,
Revised:02 January 1900,
Published Online:20 February 2010,
Published:20 February 2010
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张 凯;杜 鑫;李 儒;阎 斌;汪映寒. 表面活性剂对聚合物分散液晶光电性能的影响[J]. 液晶与显示, 2010,25(1): 49-52
ZHANG Kai;DU Xin;LI Ru;YAN Bin;WANG Ying-han. Effect of Surfactant on Electro-Optical Property of Polymer Dispersed Liquid Crystal[J]. 液晶与显示, 2010,25(1): 49-52
为了调控聚合物分散液晶(PDLC)中聚合物基体和液晶微滴的界面作用
降低锚定能
以聚丙烯酸甲酯(PMA)为基体
E7为分散相
并加入了不同含量的硬脂酸(SA)表面活性剂
采用聚合物诱导相分离法制备了PDLC
并对PDLC的光电性能进行了测试。研究发现
PDLC的电光性能随着SA含量的增加而改善
但当SA的含量达到一定值后
液晶微滴出现"岛聚"现象
光电曲线出现一个转折点。实验结果表明
表面活性剂可以调控聚合物和液晶微滴的界面作用
降低锚定能
从而改善PDLC的光电性能。
Polymer dispersed liquid crystal (PDLC) is a kind of new display material. It has a lot of advantages. Anchoring energy
as an important factor of PDLC
has a great influence on electro-optical properties. In this letter
a small amount of stearic acid (SA) was added into PDLC. With the increase of SA
the anchoring energy was reduced
which leads to a reduction in driving voltages and an improvement in the ON state transmittance. However
the ON state transmittance decreased when the concentration of SA exceeded 0.5%. Besides
with the decrease of anchoring energy
the hysteresis increased. It demonstrated that SA do reduced the anchoring energy and improved electro-optical properties of PDLC.
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