摘要:The nascent field of material intelligence (MI) promises revolutionary adaptive and responsive physical functions that are inaccessible to the virtually-restricted digital artificial intelligence (AI). In this perspective paper, we explore the potential of MI for intelligent human-interactive functions; we focus on liquid crystal polymers (LCPs), which are uniquely ideal for both MI and human-interactive applications due to their adaptable stimuli-responsive properties and compliance, respectively. We preface our study by building a framework to categorize MI, underlining the need to modify psychology-based terms due to the disparate mechanisms for biological cognition and material intelligence. Based on our framework, we describe LCP mechanisms and compositing methods for actuation, material memory and learning and forgetting behavior, outlining the journey of an LCP from polymer to MI. We conclude our perspective with an overview of the potential applications for LCPs with MI, accompanied by our recommendations for researchers in the pursuit of futuristic applications; ultimately, we believe the field of MI will generate scientific and social impact that surpasses that of AI.
摘要:Liquid crystal elastomer soft actuators, with their unique liquid crystal anisotropy and rubber soft elastic properties, have shown sensitive response to multiple stimuli and the ability to perform complex large deformation, which has become a research hotspot in the field of scientific research. Among them, liquid crystal elastomer soft pneumatic actuators have attracted much attention due to their simple actuation mode and mild actuation-conditions. Recently, researchers have studied the actuation mode, response speed, and recovery speed of liquid crystal elastomer soft pneumatic actuators, and broadened their mechanical and optical applications. In this review, the latest research trends of liquid crystal elastomer soft pneumatic actuators are reviewed, their abnormal mechanical behavior is introduced, and the potential application prospects of this technology in the fields of mechanics and optics are discussed prospectively, which provides a new perspective and enlightenment for the research and development of related fields.
摘要:Liquid crystal polymers (LCPs) possess distinctive chemical structures and physical properties, which endow them with significant potential in applications such as soft robotics and artificial muscles. In recent years, light regulation technology has emerged as a focal point in this research domain, due to its non-contact nature, precise control, and low energy consumption. Polarization, an essential physical attribute of light, introduces a novel dimension of regulation for photoresponsive systems. Modulating the polarization properties of light can significantly diversify the editing and operational methods of photoresponsive LCP actuators, thereby expanding their application scope. A plethora of studies have already demonstrated the control of shape changes in LCP devices or optical elements using polarized light. Building upon this foundation, this article provides a comprehensive summary of the working principles of polarized light-controlled LCP actuators. It also highlights several representative applications of polarized light-controlled liquid crystal actuators, based on the characteristics of different photoresponsive structures. Additionally, the article reviews the current challenges faced by such actuators and offers a perspective on future development. Future research endeavors should focus on enhancing the stability, photothermal conversion efficiency, and response speed of these actuators to propel their application advancement.
摘要:Liquid crystal elastomer is a type of soft smart materials composed of liquid crystal mesogens and polymer networks. Under external stimuli such as heat, light, or electric field, liquid crystal elastomers can undergo large reversible deformation, showing great potential in applications of soft robotics, artificial muscles, self-sensing systems, and biomedical devices. In recent years, with the development of various manufacturing technologies, researchers have extensively explored the processing methods and structure design of liquid crystal elastomers. This paper first introduces three conventional preparation strategies for liquid crystal elastomers, discussing their features and limitations. Then, we summarize the recent research advances in the manufacturing technologies of liquid crystal elastomers. We further introduce the strategies to utilize the structure design of liquid crystal elastomers to achieve multiple motion modes and rapid actuation. Finally, we discuss the current challenges and future development of liquid crystal elastomers.
摘要:Chiral liquid crystals is a unique photonic material, which can be generally divided into 1D cholesteric liquid crystals and 3D blue phase liquid crystals. Benefiting from the intrinsic periodically arranged nanostructures, chiral liquid crystals not only has the optical properties that ordinary liquid crystals does not have, such as selective reflection, optical activity and circular dichroism, but also can quickly and sensitively respond to external environmental conditions, which are widely used in the fields of advanced display, dynamic anti-counterfeiting, information encryption, intelligent fabrics and so on. In recent years, with the vigorous development of 3D printing technology, researchers have developed a variety of printable chiral liquid crystal inks, prepared chiral liquid crystal materials with complex geometric structure, multi-function, and multi-stimulus-response, and further studied the potential application value of 3D printing chiral liquid crystal. In this paper, the self-assembly mechanisms of chiral liquid crystals based on 3D printing technology are systematically reviewed, such as shear-induced orientation self-assembly, anisotropic deswelling self-assembly, critical colloid concentration self-assembly, and various stimulus-responsive chiral liquid crystal materials and chiral liquid crystal functional materials with fluorescent luminescence based on 3D printing technology are mainly introduced. Finally, we summarized the prospects and potential challenges of 3D printing chiral liquid crystal materials.
摘要:Photoresponsive chiral liquid crystal materials, as a type of soft matter with self-assembly and entropy-driven ordering properties, exhibit excellent optical modulation of helical structures and are widely used in optical anti-counterfeiting, optical coding, and laser engineering. By incorporating chiral photoswitches into liquid crystal systems, light-induced chiral conversion can be effectively harnessed to remotely control the self-assembled helical structures of the liquid crystal materials. Currently, azobenzene, molecular motors, and diarylethene are widely utilized as chiral photoswitches in liquid crystal systems. These compounds exhibit weak stimulus and strong response control properties, highlighting their broad application prospects.This paper focuses on the structural design concepts of these three types of chiral photoswitches and summarizes the unique properties exhibited in light-modulated liquid crystal helical structures, including the reversible optical control of parameters such as helical structure pitch size and direction.Finally, the light-responsive flexible liquid crystal materials constructed using these photoswitches demonstrated their ability to achieve changes in color and shape through light manipulation, showcasing potential application in information storage, anti-counterfeiting, soft robotics, and wearable devices, along with an outlook on future developments in this field.
摘要:Luminescent discotic liquid crystals (L-DLCs) are advanced functional materials that exhibit remarkable characteristics in both molecular structure and luminescent properties. This review provides a comprehensive overview of the molecular design, performance modulation, and applications of L-DLCs. First, the basic concept, typical molecular structure, and liquid crystalline phases of these materials are introduced. The review then discusses in detail the excellent performance of L-DLCs in both fluorescence and phosphorescence mechanisms, with molecular design strategies enabling light emission across different wavelength ranges. Next, the applications of L-DLCs in organic electronic devices are highlighted. Finally, the current state and future trends in this field are summarized, with a focus on molecular structure optimization, improvements in fabrication processes, and the development of device integration strategies, aiming to enhance the overall performance of L-DLCs and accelerate their practical applications in organic electronic devices.
摘要:Circularly polarized luminescence (CPL) reveals the unique excited-state characteristics of chiral luminescent systems, offering broad interdisciplinary applications. However, current chiral luminescent materials typically suffer from inadequate polarized luminescence performance. Chiral liquid crystals possess a distinctive periodic helical structure that can selectively reflect left- or right-handed circularly polarized light. By combining these with luminescent functional materials, one can achieve CPL systems with high luminescence dissymmetry factors. Consequently, the use of chiral liquid crystals to induce and amplify the circularly polarized luminescence performance of luminescent guests has garnered significant attention. This review discusses the research progress and trends in the realm of CPL liquid crystal systems, systematically summarizing the interactions between chiral liquid crystal matrices and luminescent guests (such as organic dyes, colloidal semiconductor quantum dots, carbon quantum dots, perovskite nanocrystals, and upconversion materials), and elucidating the structural characteristics and performance of these composite systems. Finally, it explores the extensive application prospects of CPL liquid crystal materials in information security, 3D displays, asymmetric synthesis, circular polarization laser, and biosensing,while also contemplating their future directions and potential applications.
摘要:Liquid crystals, as an ordered fluid, provide an excellent physical environment for the orderly self-assembly of functional molecules. Traditional research has mainly focused on the one-dimensional ordered assembly of liquid crystal molecules, such as in Nematic or Smectic phases. This article reviews the latest progress in the complex assembly and phase behavior of polyphilic liquid crystal molecules. By regulating the degree and mode of microscopic phase separation, a series of assembly modes have been achieved, ranging from two-dimensional honeycomb columnar phases to three-dimensional network structures. The article explores the influence of steric effects and phase separation on the formation mechanisms of assembled structures, such as superlattices and Frank-Kasper phases, while also analyzing the role of fundamental mathematical concepts like minimal surfaces and supramolecular chirality in assembly behavior. Additionally, it systematically discusses the phase transition paths in two-dimensional tiling of liquid crystals, the control mechanisms of three-dimensional network structures, and the supramolecular chirality behavior arising from symmetry breaking. These studies provide new insights into the understanding of complex supramolecular systems in nature and artificial reticular chemistry.
摘要:With the advancement of material synthesis methods, a wide range of two-dimensional (2D) materials with exceptional properties, such as graphene, boron nitride, MXenes, and black phosphorus, have emerged, making the study of 2D material colloidal liquid crystals and their self-assembly behaviors increasingly important. Alpha-zirconium phosphate (α-ZrP), a typical layered material, has significant applications in fields such as mechanical reinforcement, barrier enhancement, flame retardancy, corrosion resistance, catalysis, environmental protection, energy, and medicine. Due to the ability of α-ZrP crystals to be exfoliated into monolayer nanosheets through various chemical methods, and its advantages of controllable synthesis, low polydispersity, and stable physicochemical properties, α-ZrP has been systematically studied as a physical template for research on 2D material colloidal liquid crystals. This article provides a detailed discussion on the synthesis methods, exfoliation techniques, self-assembly into liquid crystals, and regulatory strategies of α-ZrP. The main factors influencing the liquid crystal phase transitions of α-ZrP include the aspect ratio, polydispersity, temperature, ion concentration, electric field, magnetic field, and spherical particle mixing. Changes in these regulatory conditions lead to diverse phase behaviors and phase structures. This article also explores the potential applications of α-ZrP as a next-generation functional material and highlights the importance of research on its liquid crystal phase transitions as a significant reference for the study of 2D material colloidal liquid crystals and the assembly of 2D materials into macroscopic structures.
关键词:Zirconium Phosphate;Lyotropic liquid crystal;self-assemble;2D material
摘要:Solitons have been widely observed and applied across various fields, including physics, biology, astronomy, and information engineering. In liquid crystal materials, the mechanisms of soliton generation, stability conditions, manipulation methods, and potential applications have long been research hotspots of interest to scientists. This review provides an overview of recent advances in the control of non-topological and topological soliton motion in liquid crystals. It summarizes techniques for controlling the direction and speed of individual soliton using electrical, chemical, and optical methods, introduces the collective motion and self-assembly phenomena of solitons, and discusses the potential applications of soliton motion control in areas such as microparticle transport and beam steering. This work offers insights into further research on the control of soliton motion in liquid crystals and explores the potential applications of liquid crystal solitons in various fields, providing new possibilities for the study of liquid crystal solitons.
关键词:liquid crystals;solitons;motion control;external field manipulation
摘要:Liquid crystal display is now the dominant technology for information displays, which is widely used in small size displays, such as calculators, mobile phones, and digital cameras; medium size displays, such as laptops and desktop monitors; large size displays, such as direct-view TV and projection TV. Although traditional liquid crystals, such as nematic liquid crystals and cholesteric liquid crystals, exhibit fast response to electric field, higher quality displays are pursued along with the improvement of the people's living standards. It requires liquid crystals of faster response to satisfy the dynamic display of high resolution. This paper systematically summarizes the factors affecting the LC response, and emphasizes several kinds of new liquid crystals of fast responsiveness, such as polymer stabilized blue phase liquid crystal, ferroelectric liquid crystal, ferroelectric nematic liquid crystal and electric modulation of order parameters. Finally, we rationally anticipate the promising applications of fast response liquid crystals in displays and photonic devices.