摘要:To obtain liquid crystal elastomer with shape-programmable ability and improve its application potential in soft actuators and soft robots, this work reports a light driven soft actuator based on liquid metal (LM)-liquid crystal elastomer (LCE). The soft actuator is fabricated by 4D printing technology, which endows the actuator robust shape-programmable capability.LM was dispersed in ethanol by sonication, then LM micro-particles were mixed into the liquid crystal solution to obtain uniform LM-LCE ink. Using 4D printing technique, the soft actuator with specific deformation was eventually obtained by further programming the orientation of ink. The alternating orthogonal and conical array LM-LCE soft actuators were created via 4D printing. The actuator has good photothermal performance, when exposed to 808 nm infrared laser, its surface temperature can reach above 120 °C in about 10 s. According to the superior photothermal performance, the alternating orthogonal structure actuator is capable of producing bending deformation quickly, while the conical array structure actuator can produce a convex deformation with the spiral center as the vertex.Based on 4D printing technology, the LM-LCE light-driven soft actuator has robust shape-programmable capability, demonstrating better adaptability and adjustability in dynamic and complex environments, and is anticipated to be extensively used in the fields of medical treatment, military, and soft robot.
摘要:Liquid crystal elastomers (LCEs) have potential applications in medical micro-robotics, controllable surface microstructures, and microfluidics due to their programmable shape morphing and up to 400% strain. To achieve high-resolution molecular orientations and high-precision LCE microstructures, advanced alignment and micro/nano-fabrication techniques are required. Here, we presented current alignment techniques and micro/nano-fabrication techniques for LCE micro-structures, summarized their applications in micro-actuators, artificial muscle fibers, and controllable surfaces, and envisaged their future development in medical micro-robotics.
摘要:Liquid crystal elastomers are materials that combine the anisotropic properties of liquid crystals and the mechanical properties of polymers, enabling programmable shape changes. Consequently, they have potential applications in various arenas such as flexible electronics, optical devices, and biomedicine. The advanced functional attributes of liquid crystal elastomers primarily derive from the methodologies used in the treatment methods and the fabrication of geometric structures during the preparation process. The different ways to combine the orientation strategies with the structures can endow the materials with complex deformation modes and functions. In recent years, it has been discovered that integrating mechanical metamaterials with liquid crystal elastomers can actualize functionalities and properties that are unattainable with conventional material design, such as biaxial actuation, thermally induced expansion, and omnidirectional motion, which can be applied in arenas including biomedical engineering, electronic-free sensing, and precise vibration management. This paper provides a comprehensive review of the design methods that employ metamaterial concepts for the concurrent structural and orientational construction of liquid crystal elastomers, and their applications, with an introduction on the applications of 3D printing technology in the fabrication of artificial ordered structures and the impact on material performances.
摘要:Making full use of the self-assembly and stimulus-response properties of liquid crystals (LCs) to achieve flexible construction, dynamic manipulation and multi-functional applications of smectic LC hierachical superstructures has great significance for stimulating more cutting-edge innovative devices and pushing the practical application of LC superstructures. This research focuses on preparation and self-assembly of smectic LC superstructures, modulation of defect structures by multiple external stimuli, and dynamic regulation laws. First, the shape and size modulation of smectic LC topological superstructures by photopatterning and spin-coating parameters were explored. Then, the microlensing function of the focal conic domain arrays was verified. Through optimization of composite material and proposing the polymer-stabilized strategy, dynamic regulation of the square focal cone domain array under electric field at 35 ℃ (i.e., nematic phase) was demonstrated. Finally, this paper also studied multi-dimensional control of smectic LC topological superstructures by introducing chirality, light field and thermal field. This study combines multiple external field stimuli, such as photoalignment, film thickness, polymer network, electric field, chirality, and light field to achieve multi-dimensional control of the hierachical superstructure of smectic LCs.
摘要:In order to broaden the application of bluephase liquid crystal (BPLC) and build a multifunctional BPLC system platform, this paper introduces TPE-PPE, a liquid crystal with aggregation-inducedemission(AIE)characteristics, into the BPLC system, and carries out a study on the fluorescence performance of the composite system. On the one hand, the effects of chiral dopant content on the phase transition behavior and photonic band gap (PBG) displacement of the BPLC are systematically investigated and summarized. On the other hand, the influence of BPLC on the fluorescence performance of AIE molecules is explored, and relevant fluorescence enhancement effects are proposed. The experimental results show that the temperature domain ranges of blue phase Ⅱ with different chiral dopants systems are basically the same, and the PBG shows blue shift with decreasing temperature. The temperature range of blue phase Ⅰ is closely related to the chirality, and when only blue phase Ⅰ exists in the system, its PBG shows red shift with the decrease of temperature. The BPLC system has a certain fluorescence enhancement effect on AIE molecules, and the fluorescence intensity of the system is obviously enhanced with the red shift of the PBG of blue phase Ⅰ. It is concluded that the TPE-PPE molecules are involved in the self-assembly of the BPLC system to a certain extent.The enhanced fluorescence intensity of the TPE-PPE molecules is due to the restricted movement of the TPE-PPE molecules in the double-twisted cylinders.With the disappearance of the blue phase Ⅱ and the red shift of the PBG of the blue phase Ⅰ, more TPE-PPE molecules are involved in the self-assembly of the double-twisted cylinders, and the fluorescence emission of the system is enhanced.
关键词:aggregation-induced emission;polymer-stabilized blue phase liquid crystal;photonic crystal
摘要:Pattern formation of electroconvection in liquid crystals is a peculiar and intriguing phenomenon, and it also poses an important problem in the study of optical diffraction. This work aims to explore pattern formation and related diffraction characteristics in dielectrically negative anisotropic nematic liquid crystals. Four different electroconvection patterns are observed experimentally, namely, soft square, oblique rolls, skewed varicose, and irregular patterns.The threshold voltages required for pattern generation at different temperatures are investigated. The effect of electric field on the periodicity of patterns and the inclination angle of the relative director are studied, and the corresponding diffraction characteristics of the patterns are analyzed. The experimental results show that electroconvection patterns can be altered by adjusting the electric field and temperature. The threshold voltage required for pattern generation decreases with the increase of temperature and increases with the growth of frequency. The periodicity of soft square patterns initially decreases and then increases with the increase of frequency, while the periodicity of oblique rolls decreases with the increase of frequency. When , the oblique rolls exhibit an approximately deviation from the initial director. This controllable electroconvection pattern provides a feasible solution for the realization of tunable optical diffraction devices based on nematic liquid crystals.
摘要:The Optically Driving Liquid Crystal Display (ODLCD) is a novel type of liquid crystal display that utilizes the arrangement of target optical axes to inscribe linear polarization information into the optical orientation layer, which in turn, guides the technology of liquid crystal micro-area orientation. ODLCDs not only boast the significant advantage of low power consumption but also enable information erasure and rewriting through the use of polarized light. However, the current drawback of ODLCDs lies in their prolonged writing time, restricting their practical applications.To address this issue and reduce the writing time of ODLCDs, we conducted experiments by incorporating liquid crystal monomer RM257 and silver nanowires into the liquid crystal matrix, followed by photo-crosslinking under an applied electric field. The impact of different concentrations (mass fraction) of RM257 and silver nanowires on the writing time of ODLCDs was investigated. The experimental results reveal that both RM257 and silver nanowires (AgNWs) exert a significant influence on the writing time of ODLCDs. Specifically, at an RM257 concentration of 12% and AgNWs concentration of 1%, ODLCDs exhibit a lower writing time.This study contributes to the enhancement of the writing time performance of ODLCDs, providing valuable insights for its practical applications.
摘要:This article designs a liquid crystal flexible display film with excellent mechanical properties and unique anti-counterfeiting functions. Firstly, a liquid crystal display device with dual channel display function is designed based on optical orientation technology, which achieves independent display of two channels through light field control.Secondly, using the thickness of the LCD box as the control group, the optimal thickness is determined to enable two independent patterns to form the main and auxiliary display effects, thereby hiding anti-counterfeiting information. Finally, the mechanical tensile properties of liquid crystal display films are improved by doping silver nanowires (AgNWs) into liquid crystal polymer composites. The experimental results show that when the thickness of the liquid crystal flexible display film is 60 μm, the liquid crystal film presents a satisfactory pattern display effect. Meanwhile, compared with the liquid crystal display film without AgNWs doping, the modulus parameter of the liquid crystal flexible film doped with AgNWs is increased by more than 30%, and it has a larger stress-bearing capacity and strain range. This study has positive significance for achieving a liquid crystal anti-counterfeiting trademark with rich information and strong stability.
关键词:Liquid crystal flexible display film;Anti-counterfeiting trademark;silver nanowire;Physical and mechanical properties
摘要:In this work, the oblique helicoidal cholesteric (ChOH) device with high reflectivity and full color displaying was obtained by means of photo-electric cooperative regulation. By introducing a left-handed chiral photoswitch (switch 1) into liquid crystal (LC) system, also based on the principle of chiral cancellation of the opposite handedness chiral additive, a chiral agent R811 was used to balance the difference in helical twisted power value before and after Z/E photoisomerization of switch 1, so that the system could reflect circularly polarized light with opposite handedness and the same red-green-blue colors by applying the same electric field intensity before and after light irradiations. On this basis, a double-layer LC cell was constructed, and the cell was subjected to photo-electric stimulation to induce the helical inversion of the upper layer, so that left- and right-handedness ChOH structure could be formed in the double-layer structure. As a result, the reflectance of the system was increased by around 60% in the device structure with full reflection effect. This study provides a new idea for the preparation of full-color electronic paper devices with high reflectivity, and also provides a useful exploration for the application of photoswitch materials in LC devices.
摘要:The natural photonic crystal patterns provide unique functions for the survival of organisms, such as chameleons adapting their skin pattern colors to the environment for camouflage protection, and cephalopods (squid, cuttlefish, octopus, etc.) producing a wide range of structural colors and photonic patterns to facilitate information exchange between species. Inspired by the special functions of natural photonic patterns, cholesteric liquid crystals (CLCs) patterns have been developed and demonstrated potential applications in data storage, sensors, flexible intelligent devices, and other fields. This article reviews the external stimulus responsiveness, functional evolution, and applications of CLC patterns. Firstly, the external stimulus responsiveness of CLC patterns are summarized, including light, electricity, heat, mechanical force, and solvent. Secondly, various applications of CLC patterns are introduced, such as storage devices with encryption and decryption functions, information security and anti-counterfeiting devices, flexible wearable sensors, and circularly polarized light emitting systems. Finally, the prospects and challenges of CLC patterns are introduced. This review provides a foundation for constructing new functional materials based on CLC patterns.
摘要:Gas sensors based on liquid crystals constitute an emerging research field. Due to the chemical diversity, reversible molecular arrangement, and inherent self-assembly capabilities of liquid crystals, they can satisfy the characteristics of high sensitivity, rapid response, low energy consumption, and selectivity in sensors. As related research advances, methods for liquid crystal gas sensing continue to be refined. This paper reviews recent years' liquid crystal-based gas sensing technology and discusses the existing methods for gas detection using liquid crystals, mainly including nematic liquid crystal gas detection methods and cholesteric liquid crystal gas sensing methods. Nematic liquid crystal gas sensing includes functionalized substrate liquid crystal film sensing, geometrically tailored liquid crystal sensing, and liquid crystal droplet sensing methods. Cholesteric liquid crystal gas sensing mainly includes gas sensing with polymer cholesteric liquid crystal films,liquid crystal droplet sensing,gas detection based on optical fibers, and cellulose gas sensing. Finally, the application and development of liquid crystal gas sensing are discussed.
摘要:Liquid crystal displays almost cover all application display fields, and in non-display fields, they also demonstrate the characteristics of high precision and multi-parameter regulation. Currently, liquid crystal devices still need to further improve their response speed for high-speed control applications. For this reason, overvoltage drive technology has entered the field of vision of researchers. This article mainly reviews the overdrive technology applied in the field of liquid crystal display and control. Firstly, a brief introduction is given to the principles and main applications of overdrive technology, as well as the optimization of device response and other performance improvements when applying overdrive technology in different types of liquid crystal displays. In addition, this article also introduces the application of overdrive technology of liquid crystal devices in non-display field, such as spatial light modulators and liquid crystal lenses. Finally, the article summarizes the technical issues faced by overdrive technology in liquid crystal displays, outlines the main existing solutions, and briefly looks into the technical bottlenecks that need to be overcome and future development directions.
摘要:Lyotropic Chromonic Liquid Crystals (LCLCs) are a type of lyotropic liquid crystals formed by self-assembly of soluble aromatic compounds. Due to their rich physical anisotropy, biocompatibility, and controllability, LCLCs have important research value in applications such as biosensing, bacterial manipulation, etc. This article reviews the research on performance control of LCLCs, briefly introduces their characteristics, and focuses on the effects of control methods such as director alignment and doping on LCLCs. Finally, feasible control methods and possible future development routes are discussed and summarized.
关键词:Lyotropic Liquid Crystals;Chromonic;external field regulation;doping